Influence of Zn excess on compositional, structural and vibrational properties of Cu2ZnSn0.5Ge0.5Se4 thin films and their effect on solar cell efficiency

This Accepted Manuscript will be available for reuse under a CC BY-NC-ND licence after 24 months of embargo periodThe effect of Zn content on compositional, structural and vibrational properties of Cu2ZnSn1-xGexSe4 (CZTGSe, x ~ 0.5) thin films is studied. Kesterite layer is deposited by co-evaporation onto 5 × 5 cm2 Mo/SLG substrate followed by a thermal treatment at maximum temperature of 480 °C, obtaining areas with different composition and morphology which are due to the sample position in the co-evaporation system and to the non-uniform temperature distribution across the substrate. Kesterite layers with higher Zn amounts are characterized by lower Cu and Ge contents; however, a uniform Ge distribution through the absorber layer is detected in all cases. The excess Zn concentration leads to the formation of ZnSe secondary phase on the surface and in the bulk of the absorber as determined by Raman spectroscopy. When higher Ge content and no ZnSe are present in the absorber layer, a compact structure is formed with larger grain size of kesterite. This effect could explain the higher Voc of the solar cell. The Zn content does not affect the bandgap energy significantly (Eg near 1.3 eV), although the observed effect of Zn excess in CZTGSe results in a decreased device performance from 6.4 to 4.2%. This investigation reveals the importance of the control of the off-stoichiometric CZTGSe composition during the deposition process to enhance solar cells propertiesThis work was supported by Spanish Ministry of Science, Innovation and Universities Project WINCOST (ENE2016-80788-C5-2-R) and European Project INFINITE CELL (H2020-MSCA-RISE-2017-777968). ARP also acknowledges financial support from Community of Madrid within Youth Employment Program (PEJD-2017-PRE/IND-4062). MG acknowledges the financial support from ACCIÓ-Generalitat de Catalunya within the TECNIOspring Plus fellowship (TECSPR18-1-0048

Polypyrrole and polyaniline nanocomposites with high photothermal conversion efficiency

The simple and scalable synthesis of poly[2-(methacryloyloxy)ethyl phosphorylcholine] (PMPC)-coated conducting polymer (CP) nanocomposites is described. These functional nanocomposites exhibit tunable absorption in the near-infrared region with relatively high photothermal efficiencies. More importantly, their potential for bio-imaging and therapeutic treatment is proven by cellular uptake and cytotoxicity studies

Properties of the rho and sigma Mesons from Unitary Chiral Dynamics

The chiral limit of the rho and sigma masses and widths is discussed. We work within the inverse amplitude method to one loop in SU(2) ChPT and analyze the consequences that all chiral logarithms cancel out in the rho-channel, while they do not cancel for the sigma case, and how they strongly influence the properties of this latter resonance. Our results confirm and explain the different behavior of the sigma and rho poles for NC not far from 3, but we extend the analysis to very large NC, where the behavior of these two resonances is re-analyzed. We note that the rather natural requirement of consistency between resonance saturation and unitarization imposes useful constraints. By looking only at the rho-channel, and within the single resonance approximation, we find that the masses of the first vector and scalar meson nonets, invoked in the single resonance approximation, turn out to be degenerated in the large NC limit. On the contrary we show that, for sufficiently large NC, the scalar meson evolution lies beyond the applicability reach of the one-loop inverse amplitude method and if the scalar channel is also incorporated in the analysis, it may lead, in some cases, to phenomenologically inconsistent results.Comment: 11 pages, 1 figur

On the UV renormalizability of noncommutative field theories

UV/IR mixing is one of the most important features of noncommutative field theories. As a consequence of this coupling of the UV and IR sectors, the configuration of fields at the zero momentum limit in these theories is a very singular configuration. We show that the renormalization conditions set at a particular momentum configuration with a fixed number of zero momenta, renormalizes the Green's functions for any general momenta only when this configuration has same set of zero momenta. Therefore only when renormalization conditions are set at a point where all the external momenta are nonzero, the quantum theory is renormalizable for all values of nonzero momentum. This arises as a result of different scaling behaviors of Green's functions with respect to the UV cutoff ($\Lambda$) for configurations containing different set of zero momenta. We study this in the noncommutative $\phi^4$ theory and analyse similar results for the Gross-Neveu model at one loop level. We next show this general feature using Wilsonian RG of Polchinski in the globally O(N) symmetric scalar theory and prove the renormalizability of the theory to all orders with an infrared cutoff. In the context of spontaneous symmetry breaking (SSB) in noncommutative scalar theory, it is essential to note the different scaling behaviors of Green's functions with respect to $\Lambda$ for different set of zero momenta configurations. We show that in the broken phase of the theory the Ward identities are satisfied to all orders only when one keeps an infrared regulator by shifting to a nonconstant vacuum.Comment: 29 pages, 8 figures, uses JHEP.cls, references adde

Canonical Quantization of Noncommutative Field Theory

A simple method to canonically quantize noncommutative field theories is proposed. As a result, the elementary excitations of a (2n+1)-dimensional scalar field theory are shown to be bilocal objects living in an (n+1)-dimensional space-time. Feynman rules for their scattering are derived canonically. They agree, upon suitable redefinitions, with the rules obtained via star-product methods. The IR/UV connection is interpreted within this framework.Comment: 8 pages, 1 figur

Equilibrium roughening transition in a 1D modified sine-Gordon model

We present a modified version of the one-dimensional sine-Gordon that exhibits a thermodynamic, roughening phase transition, in analogy with the 2D usual sine-Gordon model. The model is suited to study the crystalline growth over an impenetrable substrate and to describe the wetting transition of a liquid that forms layers. We use the transfer integral technique to write down the pseudo-Schr\"odinger equation for the model, which allows to obtain some analytical insight, and to compute numerically the free energy from the exact transfer operator. We compare the results with Monte Carlo simulations of the model, finding a perfect agreement between both procedures. We thus establish that the model shows a phase transition between a low temperature flat phase and a high temperature rough one. The fact that the model is one dimensional and that it has a true phase transition makes it an ideal framework for further studies of roughening phase transitions.Comment: 11 pages, 13 figures. Accepted for publication in Physical Review

Turbulence generation by a shock wave interacting with a random density inhomogeneity field

When a planar shock wave interacts with a random pattern of pre-shock density non-uniformities, it generates an anisotropic turbulent velocity/vorticity field. This turbulence plays an important role at the early stages of the mixing process in the compressed fluid. This situation emerges naturally in shock interaction with weakly inhomogeneous deuterium-wicked foam targets in Inertial Confinement Fusion (ICF) and with density clumps/clouds in astrophysics. We present an exact small-amplitude linear theory describing such interaction. It is based on the exact theory of time and space evolution of the perturbed quantities behind a corrugated shock front for a single-mode pre-shock non-uniformity. Appropriate mode averaging in 2D results in closed analytical expressions for the turbulent kinetic energy, degree of anisotropy of velocity and vorticity fields in the shocked fluid, shock amplification of the density non-uniformity, and sonic energy flux radiated downstream. These explicit formulas are further simplified in the important asymptotic limits of weak/strong shocks and highly compressible fluids. A comparison with the related problem of a shock interacting with a pre-shock isotropic vorticity field is also presented.Comment: This article corresponds to a presentation given at the Second International Conference and Advanced School "Turbulent Mixing and Beyond," held on 27 July - 07 August 2009 at the Abdus Salam International Centre for Theoretical Physics, Trieste, Italy. That Conference Proceeding will be published as a Topical Issue of the Physica Scripta IOP scienc

Temperature dependence of the anomalous effective action of fermions in two and four dimensions

The temperature dependence of the anomalous sector of the effective action of fermions coupled to external gauge and pseudo-scalar fields is computed at leading order in an expansion in the number of Lorentz indices in two and four dimensions. The calculation preserves chiral symmetry and confirms that a temperature dependence is compatible with axial anomaly saturation. The result checks soft-pions theorems at zero temperature as well as recent results in the literature for the pionic decay amplitude into static photons in the chirally symmetric phase. The case of chiral fermions is also considered.Comment: RevTex, 19 pages, no figures. References adde