Simulating solute transport in an aggregated soil with the dual-porosity model: measured and optimized parameter values

The capability of the first-order, dual-porosity model, which explicitly accounts for non-ideal transport caused by the presence of ‘immobile’ water, to predict the non-ideal transport of non-sorbing solute in a constructed aggregated soil has been investigated. Miscible-displacement experiments performed with a well-characterized aggregated soil and a non-reactive tracer (pentafluorobenzoate) served as the source of the data. Values for the input parameters associated with physical non-equilibrium were determined independently and compared with values obtained by curve fitting of the experimental measurements. The calculated and optimized values compared well, suggesting that the non-equilibrium parameters represent actual physical phenomen

Experimental Studies of Resin Systems for Ablative Thermal Protection System

The present work was initiated to finalise resin for the development of thermal protection system (TPS) for the external surface of a polymeric composite rocket motor case made up of Carbon roving and Epoxy resin. The temperature on the outer surface of the composite case increases due to kinetic heating caused by aerodynamic drag and vehicle velocity. These rocket motor casings are functionally required only in the ascent phase of missile trajectory till motor action time and stage separation. Due to which the experienced heat flux is relatively less, and the temperature on the external composite case is in order of 250 °C - 300 °C depending on missile configuration and trajectory, unlike extreme thermal conditions on ablative nozzle liners exposed to rocket motor exhaust. The maximum allowable temperature in the present study for the Carbon-Epoxy case is 100 °C due to degradation in mechanical properties. The thermal protection system on the external surface will function as a heat-insulating layer based on the working mechanism of ablation. The resin of the thermal protection layer has a substantial impact on the manufacturing process and curing aspects, especially compatibility with the pre-cured carbon epoxy case layer. The generation of test results for thermal stability, cure characteristics and Tg for Epoxy resin has also been included in present studies as an additional objective that provides significant inputs for process development. The test results for Epoxy resin is also used as a basis for the finalisation of resin for the thermal protection layer for processing aspects apart from its basic thermal stability characteristics. The ablative thermal protection working mechanism is based on the ablation phenomenon. In the case of ablation, resin plays a vital role due to pyrolysis and other thermal characteristics. In the present experimental studies, the Phenolic resin and Silicone resin are considered as candidate resin materials for ablative thermal protection system based on available literature and in house experience. The main objective of the present studies is to evaluate thermal stability, char yield after final decomposition through DSC and TGA techniques for both resins as these are fundamental characteristics needed for the present specific application. The test results for specific grades (formulation) of phenolic and Silicone resins are generated and compared. In the present work, the experimental studies to evaluate glass transition temperature (Tg), thermal stability, and cure characteristics for Epoxy resin is also carried through DSC. The test results of specific grade Epoxy resin provides a basis to assess thermal margins for resins selected for ablative thermal protection system and inputs for process development and design requirements. The scope of the present studies is aimed to finalise the resin system for external thermal protection of composite rocket motor case based on thermal characteristics test results and other compatibility aspects with the structural layer

Intra-annual rainfall variability control on interannual variability of catchment water balance: A stochastic analysis

We evaluate the extent to which within-year rainfall variability controls interannual variability of catchment water balance. To this end, we analytically derive the probability density function of the annual Budyko evaporation index, B (i.e., the ratio of annual actual evapotranspiration to annual precipitation), by accounting for the stochastic nature of intra-annual rainfall fluctuation and neglecting all other sources of variability. We apply our analytical model to 424 catchments located in different climatic regions across the conterminous United States to perform this assessment. In general, we found that the model is capable of explaining mean B but is less accurate in predicting its coefficient of variation. Nonetheless, in a significant number of catchments the model can provide adequate predictions of the probability density function of B. Clear geographic patterns can be distinguished in the residuals between observed and predicted statistics of B. Interannual variability is thus not always associated with random intra-annual rainfall fluctuations. In some regions, other controls, such as seasonality and vegetation adaptations, are possibly more important. A sensitivity analysis of model parameters helped characterize the dominant controls on the distribution of B in terms of three dimensionless ratios that include climatic and soil characteristics. This study represents the first step in a diagnostic, data-driven analysis of the climatic controls on the interannual variability of catchment water balance.Water ManagementCivil Engineering and Geoscience