6 research outputs found
Population redistribution in optically trapped polar molecules
We investigate the rovibrational population redistribution of polar molecules
in the electronic ground state induced by spontaneous emission and blackbody
radiation. As a model system we use optically trapped LiCs molecules formed by
photoassociation in an ultracold two-species gas. The population dynamics of
vibrational and rotational states is modeled using an ab-initio electric dipole
moment function and experimental potential energy curves. Comparison with the
evolution of the v"=3 electronic ground state yields good qualitative
agreement. The analysis provides important input to assess applications of
ultracold LiCs molecules in quantum simulation and ultracold chemistry.Comment: 6 pages, 5 figures, EPJD Topical issue on Cold Quantum Matter -
Achievements and Prospect
High-precision determination of transition amplitudes of principal transitions in Cs from van der Waals coefficient C_6
A method for determination of atomic dipole matrix elements of principal
transitions from the value of dispersion coefficient C_6 of molecular
potentials correlating to two ground-state atoms is proposed. The method is
illustrated on atomic Cs using C_6 deduced from high-resolution Feshbach
spectroscopy. The following reduced matrix elements are determined < 6S_{1/2}
|| D || 6P_{1/2} > =4.5028(60) |e| a0 and
=6.3373(84) |e| a0 (a0= 0.529177 \times 10^{-8} cm.) These matrix elements are
consistent with the results of the most accurate direct lifetime measurements
and have a similar uncertainty. It is argued that the uncertainty can be
considerably reduced as the coefficient C_6 is constrained further.Comment: 4 pages; 3 fig
Three-body non-additive forces between spin-polarized alkali atoms
Three-body non-additive forces in systems of three spin-polarized alkali
atoms (Li, Na, K, Rb and Cs) are investigated using high-level ab initio
calculations. The non-additive forces are found to be large, especially near
the equilateral equilibrium geometries. For Li, they increase the three-atom
potential well depth by a factor of 4 and reduce the equilibrium interatomic
distance by 0.9 A. The non-additive forces originate principally from chemical
bonding arising from sp mixing effects.Comment: 4 pages, 3 figures (in 5 files