124 research outputs found

    Incoherent Interplane Conductivity of kappa-(BEDT-TTF)2Cu[N(CN)2]Br

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    The interplane optical spectrum of the organic superconductor kappa-(BEDT-TTF)2Cu[N(CN)2]Br was investigated in the frequency range from 40 to 40,000 cm-1. The optical conductivity was obtained by Kramers-Kronig analysis of the reflectance. The absence of a Drude peak at low frequency is consistent with incoherent conductivity but in apparent contradiction to the metallic temperature dependence of the DC resistivity. We set an upper limit to the interplane transfer integral of tb = 0.1 meV. A model of defect-assisted interplane transport can account for this discrepancy. We also assign the phonon lines in the conductivity to the asymmetric modes of the ET molecule.Comment: 7 pages with embedded figures, submitted to PR

    Psicopatologia descritiva: aspectos históricos e conceituais

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    OH-PLIF visualisation of radical farming supersonic combustion flows

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    Experimental investigations employing Planar Laser-induced fluorescence visualisation of the qualitative distribution of the OH radical (OH-PLIF), coupled with surface pressure measurements, have been made of flow in a generic, nominally two-dimensional inlet-injection radical farming supersonic combustion scramjet engine model. The test flows were provided by a hypersonic shock tunnel, and covered total enthalpies corresponding to the flight Mach number range 8.7-11.8 and approximately 150 kPa dynamic pressure. The surface pressure measurements displayed radical farming behaviour, that is a series of adjacent high and low pressure regions corresponding to successive shock/expansion structures, with no significant combustion-induced pressure rise until the second structure. OH-PLIF imaging between the first two structures provides the first direct experimental evidence of significant OH radical concentrations upstream of the ignition point in this mode of scramjet operation and shows that combustion reactions were occurring in highly localised regions in a complex turbulent and poorly micromixed fuel/air mixing layer confined to the fuel injection side of the combustor

    What happens when you add salt: Predicting impacts of secondary salinisation on shallow aquatic ecosystems by using an alternative-states model

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    Alternative-states theory commonly applied, for aquatic systems, to shallow lakes that may be dominated alternately by macrophytes and phytoplankton, under clear-water and enriched conditions, respectively, has been used in this study as a basis to define different states that may occur with changes in wetland salinity. Many wetlands of the south-west of Western Australia are threatened by rapidly increasing levels of salinity as well as greater water depths and permanency of water regime. We identified contrasting aquatic vegetation states that were closely associated with different salinities. Salinisation results in the loss of freshwater species of submerged macrophytes and the dominance of a small number of more salt-tolerant species. With increasing salinity, these systems may undergo further change to microbial mat-dominated systems composed mostly of cyanobacteria and halophilic bacteria. The effect of other environmental influences in mediating switches of vegetation was also examined. Colour and turbidity may play important roles at low to intermediate salinities [concentration of total dissolved solids (TDS) 10 000 mg L–1 TDS). The role of nutrients remains largely unquantified in saline systems. We propose that alternative-states theory provides the basis of a conceptual framework for predicting impacts on wetlands affected by secondary salinisation. The ability to recognise and predict a change in state with changes in salinity adds a further tool to decision-making processes. A change in state represents a fundamental change in ecosystem function and may be difficult to reverse. This information is also important for the development of restoration strategies. Further work is required to better understand the influence of temporal variation in salinity on vegetation states and probable hysteresis effects
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