15 research outputs found
Isotope shift calculations for atoms with one valence electron
This work presents a method for the ab initio calculation of isotope shift in
atoms and ions with one valence electron above closed shells. As a zero
approximation we use relativistic Hartree-Fock and then calculate correlation
corrections. The main motivation for developing the method comes from the need
to analyse whether different isotope abundances in early universe can
contribute to the observed anomalies in quasar absorption spectra. The current
best explanation for these anomalies is the assumption that the fine structure
constant, alpha, was smaller at early epoch. We test the isotope shift method
by comparing the calculated and experimental isotope shift for the alkali and
alkali-like atoms Na, MgII, K, CaII and BaII. The agreement is found to be
good. We then calculate the isotope shift for some astronomically relevant
transitions in SiII and SiIV, MgII, ZnII and GeII.Comment: 11 page
Further evidence for a variable fine-structure constant from Keck/HIRES QSO absorption spectra
[Abridged] We previously presented evidence for a varying fine-structure
constant, alpha, in two independent samples of Keck/HIRES QSO spectra. Here we
present a detailed many-multiplet analysis of a third Keck/HIRES sample
containing 78 absorption systems. We also re-analyse the previous samples,
providing a total of 128 absorption systems over the redshift range
0.2<z_abs<3.7. All three samples separately yield consistent, significant
values of da/a. The analyses of low- and high-z systems rely on different
ions/transitions with very different dependencies on alpha, yet they also give
consistent results. We identify additional random errors in 22 high-z systems
characterized by transitions with a large dynamic range in apparent optical
depth. Increasing the statistical errors on da/a for these systems gives our
fiducial result, a weighted mean da/a=(-0.543+/-0.116)x10^-5, representing
4.7-sigma evidence for a smaller weighted mean alpha in the absorption clouds.
Assuming that da/a=0 at z_abs=0, the data marginally prefer a linear increase
in alpha with time: dota/a=(6.40+/-1.35)x10^-16 yr^-1. The two-point
correlation function for alpha is consistent with zero over 0.2-13 Gpc comoving
scales and the angular distribution of da/a shows no significant dipolar
anisotropy. We therefore have no evidence for spatial variations in da/a. We
extend our previous searches for possible systematic errors, identifying
atmospheric dispersion and isotopic structure effects as potentially the most
significant. However, overall, known systematic errors do not explain the
results. Future many-multiplet analyses of QSO spectra from different
telescopes and spectrographs will provide a now crucial check on our Keck/HIRES
results.Comment: 31 pages, 25 figures (29 EPS files), 8 tables. Accepted by MNRAS.
Colour versions of Figs. 6, 8 & 10 and text version of Table 3 available at
http://www.ast.cam.ac.uk/~mim/pub.htm
LASER COOLED, STORED ION EXPERIMENTS AT NBS AND POSSIBLE APPLICATIONS TO MICROWAVE AND OPTICAL FREQUENCY STANDARDS
Research on stored ion frequency standards at the United States National Bureau of Standards is briefly discussed. We summarize past work and indicate directions of future research