1 research outputs found
Magnetization steps in Zn_(1-x)Mn_xO: Four largest exchange constants and single-ion anisotropy
Magnetization steps (MST's) from Mn pairs in several single crystals of
Zn_(1-x)Mn_xO (0.0056<=x<=0.030, and in one powder (x=0.029), were observed.
The largest two exchange constants, J1/kB=-18.2+/-0.5K and J1'/kB=-24.3+/-0.6K,
were obtained from large peaks in the differential susceptibility, dM/dH,
measured in pulsed magnetic fields, H, up to 500 kOe. These two largest J's are
associated with the two inequivalent classes of nearest neighbors (NN's) in the
wurtzite structure. The 29% difference between J1 and J1' is substantially
larger than 13% in CdS:Mn, and 15% in CdSe:Mn. The pulsed-field data also
indicate that, despite the direct contact between the samples and a
superfluid-helium bath, substantial departures from thermal equilibrium
occurred during the 7.4 ms pulse. The third- and fourth-largest J's were
determined from the magnetization M at 20 mK, measured in dc magnetic fields H
up to 90 kOe. Both field orientations H||c and H||[10-10] were studied. (The
[10-10] direction is perpendicular to the c-axis, [0001].) By definition,
neighbors which are not NN's are distant neighbors (DN's). The largest DN
exchange constant (third-largest overall), has the value J/kB=-0.543+/-0.005K,
and is associated with the DN at r=c. Because this is not the closest DN, this
result implies that the J's do not decrease monotonically with the distance r.
The second-largest DN exchange constant (fourth-largest overall), has the value
J/kB=-0.080 K. It is associated with one of the two classes of neighbors that
have a coordination number z=12, but the evidence is insufficient for a
definite unique choice. The dependence of M on the direction of H gives
D/kB=-0.039+/-0.008K, in fair agreement with -0.031 K from earlier EPR work.Comment: 12 pages, 10 figures. Submitted to PR