17 research outputs found
How harmonic is dipole resonance of metal clusters?
We discuss the degree of anharmonicity of dipole plasmon resonances in metal
clusters. We employ the time-dependent variational principle and show that the
relative shift of the second phonon scales as in energy, being
the number of particles. This scaling property coincides with that for nuclear
giant resonances. Contrary to the previous study based on the boson-expansion
method, the deviation from the harmonic limit is found to be almost negligible
for Na clusters, the result being consistent with the recent experimental
observation.Comment: RevTex, 8 page
Cluster ionization via two-plasmon excitation
We calculate the two-photon ionization of clusters for photon energies near
the surface plasmon resonance. The results are expressed in terms of the
ionization rate of a double plasmon excitation, which is calculated
perturbatively. For the conditions of the experiment by Schlipper et al., we
find an ionization rate of the order of 0.05-0.10 fs^(-1). This rate is used to
determine the ionization probability in an external field in terms of the
number of photons absorbed and the duration of the field. The probability also
depends on the damping rate of the surface plasmon. Agreement with experiment
can only be achieved if the plasmon damping is considerably smaller than its
observed width in the room-temperature single-photon absorption spectrum.Comment: 17 pages and 6 PostScript figure