Investigação das argamassas antigas de revestimento da Redução Jesuítica Guarani, São Miguel Arcanjo, Brasil

A Redução Guaranítica de São Miguel Arcanjo, um dos sete povos missioneiros que se instalaram no noroeste do estado do Rio Grande do Sul, Brasil, por volta de 1687 no atual sítio, e parte de um dos trinta povos formados pela Companhia de Jesus. Dada a sua relevância histórica para o Brasil, este estudo tem como objetivo principal caracterizar analiticamente a constituição físicoquímica das argamassas originais, que ainda pontualmente são encontradas na Ruína, identificar seus principais materiais constituintes, bem como a existência ou não da cal e a forma com que esta se apresenta. Resultados obtidos, por microscopia eletrônica de varredura (MEV-EDS), difração de raios X (DRX), espectroscopia no infravermelho por transformada de Fourier (FTIR), análise granulométrica e análise por termogravimétrica (TG/DTG) indicam que a fonte principal de aglomerante era a cal. Cal, de origem animal ou pétrea, com a presença da cal calcítica em ambos os conjuntos de amostras. Os estudos mostram a presença da variação do carbonato de cálcio em aragonita nas amostras internas e de hidroxiapatita nas externas. Assim, com base neste estudo, busca-se de modo simplificado facilitar o trabalho de investigação de uma obra de restauro, com a criação de uma rotina básica para conhecimento e caracterização da matéria a ser restaurada se necessário para posterior intervenção

Crystal-mush reactivation by magma recharge: Evidence from the Campanian Ignimbrite activity, Campi Flegrei volcanic field, Italy

International audienceProcesses of crystal-mush remobilization by mafic magma recharges are often related to the outpouring of largevolumes of silicic melt during caldera-forming eruptions. This occurred for the Campanian Ignimbrite (CI) erup-tion (Campi Flegrei, Italy), which produced a voluminous trachy-phonolitic ignimbrite in southern-central Italyabout 40 ka ago. We focussed on the proximal-CI deposits at San Martino that are composed of a main sequenceof early-erupted, crystal-poor units and a late-erupted (post-caldera collapse) crystal-rich Upper Pumice FlowUnit (UPFU). Detailed micro-analytical geochemical data were performed on glasses and crystals of pyroclastsfrom these deposits and coupled with Sr-Nd isotopic measurements on glasses. Results show that the CI eruptionwas fed by two distinct melts for the early-erupted units and the late UPFU, respectively. The glasses of the early-erupted units have negative Eu anomalies and show more evolved compositions and higher Nd isotope ratiosthan those of the UPFU, which have positive Eu/Eu*. The magmas of the early units formed the main volume oferuptible meltof the CI reservoir, and are interpretedashaving beenextractedfrom cumulate crystal-mushwith-out a vertical geochemical gradient within the magma reservoir. The data indicate that the generation of thedistinctive UPFU melts involved the injection of a new batch of mafic magma into the base of the CI reservoir.The mafic magma allowed heating and reactivation of the CI crystal-mush by melting of low-Or sanidines(+/−low-An plagioclases), leaving high-An plagioclases and high-Mg# clinopyroxenes as residual phases anda crystal-mush melt, made of 20% of the initial mush interstitial melt (with a composition similar to the early-erupted units) and 80% of sanidine melt. When the mush crystallinity was sufficiently reduced, the maficmagma was able to penetrate into the reactivated crystal-mush, mixing with variable proportions of crystal-mush melt and generating cooler hybrid melts, which underwent further crystallization of high-Or sanidine atvariable degrees (10–25%). Finally, possibly a short time before the eruption, the UPFU magmas were able tomix and mingle with the crystal-poor eruptible melts still persisting in the CI reservoir at the time of UPFU emis-sion. We suggest that the complex mechanisms described for the magma evolution feeding the CI eruption mayoccur whenever a crystal-mush is reactivated by new mafic magma input

Insights into the explosive eruption history of the Campanian volcanoes prior to the Campanian Ignimbrite eruption

The Campanian Volcanic Zone (CVZ) comprises multiple active volcanoes and includes the highly productive Campi Flegrei and Ischia caldera systems. These caldera volcanoes have produced probably the largest eruptions in Europe in the past 200 ka, such as the Monte Epomeo Green Tuff (MEGT; Ischia) at ca. 56 ka and the Campanian Ignimbrite (CI; Campi Flegrei) at ca. 40 ka, which form widespread isochrons across the Mediterranean region. These closely-spaced volcanic centres erupt phonolitic to trachytic glass compositions that are similar, and thus it can be challenging to correlate tephra deposits to specific volcanic sources. Here we present a detailed tephrostratigraphy for pre-CI eruption activity using the units preserved within a sequence at the coastal Acquamorta outcrop, on the western side of the CI caldera rim. Both the MEGT and CI units are present in the section, and they bracket twelve eruption units that were logged and sampled. New major and trace element glass chemistry data have been acquired for these Acquamorta tephra deposits. Three eruption deposits from Ischia and nine from Campi Flegrei are identified, which helps constrain the tempo of volcanic activity of these centres between the large caldera-forming eruptions. The three Ischia tephra deposits between the MEGT and the CI are indistinguishable based on both major and trace element glass chemistry and cannot be correlated to a specific or known eruption in this interval, such as the Schiappone tephra. The compositional variations between the Campi Flegrei eruptions reveal temporal shifts in the composition of the tephra deposits that reflect changes in the magmatic system prior to the CI eruption. These deposits indicate that there were at least nine eruptions at Campi Flegrei within 16 ka of the enormous CI eruption, and suggest that there was no significant period of repose before the caldera generating eruption

Reactivity of the drug methimazole and its iodine adduct with elemental zinc

The reactivity of zinc complexes with N,S-donor molecules may be of relevance to the study of Zn-metalloproteins and -metalloenzymes. In this context, the zinc complex [Zn(MeImSH)2I2] was synthesised by the reaction of zinc powder with the 1 : 1 iodine adduct of the drug methimazole [(MeImSH)·I2]. The molecular structure of the complex, elucidated by X-ray diffraction analysis, showed a tetrahedral zinc(II) centre coordinated by two neutral methimazole units (through the sulfur atoms) and two iodides. From the reaction of MeImSH and Zn powder, the complex [Zn(MeImSH)(MeImS)2] (MeImS = deprotonated form of methimazole) was separated and characterised. An analysis of the crystal packing of the neutral complexes [Zn(MeImSH)2X2] (X = I, Br and Cl) and the ionic complex [Zn(MeImSH)3I]I showed that in all of the complexes the sulfur atom, in addition to binding to the metal centre, contributes to the formation of 1-D chains built via C(4)–HS and N–HX interactions in the neutral complexes, and via C(4)–HS and N–CH3S interactions in the ionic complex [Zn(MeImSH)3I]I. The deprotonation/protonation of the coordinated methimazole units can modulate the coordination environment at the Zn core. From the reaction of complex [Zn(MeImSH)3I]I with a strong non-coordinating organic base, we have shown that, as a consequence of the NH deprotonation of methimazole S-coordinated to zinc(II), the ligand coordination mode changes from S-monodentate to N,S-bridging. Correspondingly, in the complex [Zn(MeImSH)(MeImS)2], the MeImS that displays the N,S-bridging mode at zinc can be N-protonated and thereby changes to the S-monodentate coordination

Life in harsh environments : carabid and spider trait types and functional diversity on a debris-covered glacier and along its foreland

1. Patterns of species richness and species assemblage composition of ground-dwelling arthropods in primary successions along glacier forelands are traditionally described using a taxonomic approach. On the other hand, the functional trait approach could ensure a better characterisation of their colonisation strategies in these types of habitat. 2. The functional trait approach was applied to investigate patterns of functional diversity and life-history traits of ground beetles and spiders on an alpine debris-covered glacier and along its forefield in order to describe their colonisation strategies. 3. Ground beetles and spiders were sampled at different successional stages, representing five stages of deglaciation. 4. The results show that the studied glacier hosts ground beetle and spider assemblages that are mainly characterised by the following traits: walking colonisers, ground hunters and small-sized species. These traits are typical of species living in cold, wet, and gravelly habitats. The diversity of functional traits in spiders increased along the succession, and in both carabids and spiders, life-history traits follow the \u2018addition and persistence model\u2019. Accordingly, there is no turnover but there is an addition of new traits and a variation in their proportion within each species assemblage along the succession. The distribution of ground beetles and spiders along the glacier foreland and on the glacier seems to be driven by dispersal ability and foraging strategy. 5. The proposed functional approach improves knowledge of the adaptive strategies of ground-dwelling arthropods colonising glacier surfaces and recently deglaciated terrains, which represent landforms quickly changing due to global warming

The late MIS 5 Mediterranean tephra markers: A reappraisal from peninsular Italy terrestrial records

We present new tephrostratigraphic records from the late MIS 5 (ca 110e80 ka) terrestrial sediments from southern and central Italy. On the one hand, the central Italy record consists of an outcropping lacustrine sequence from the Sulmona intermountain basin that contains four trachyticephonolitic tephra layers (POP3, POP2a, POP2b, POP1), all of which show a K-alkaline affinity that is typical for the Roman co-magmatic Province. The POP3 and POP1 layers were dated by 40Ar/39Ar method at 106.2 1.3 ka (2s) and 92.4 4.6 ka (2s), respectively. The sequence in southern Italy, on the other hand, is represented by post-Tyrrhenian coastal deposits of the Cilento area, Campania, which contain two trachytic layers (CIL2, CIL1) that show the same K-alkaline affinity. Based on their chemical compositions and radiometric ages, POP3 and POP1 are firmly correlated with the marine tephra layers X-5 (105 2 ka) and C-22 (ca 90 ka), which, in turn, match tephras TM-25 and TM-23-11, respectively, in the lacustrine sequence of Lago Grande di Monticchio (southern Italy). Of note, the POP1 layer also matches the Adriatic Sea tephra PRAD 2517 that was previously correlated with the older X-5 layer. The tephra couplet POP2a and POP2b (ca 103 and 103.5 ka, extrapolated ages) are compatible with the TM- 24b and TM-24-3 tephras in Monticchio, which match both the stratigraphic positions and the chemical compositions. In the Cilento area, as well as the already described X-6 layer (ca 108 ka) (CIL2), we recognise a new stratigraphic superimposed layer (CIL1) that matches the POP3/TM-25/C-27/X-5 Mediterranean marker(s). In summary, the data presented here provide new chemical and 40Ar/39Ar chronological constraints towards a robust late MIS 5 tephrostratigraphy of the central Mediterranean, although at the same time, they also reveal how the tephrostratigraphy itself might be flawed when dealing with tephra markers that are not adequately constrained and characterised.Published31-451V. Storia eruttivaJCR Journa