Beneficiation of ilmenite from lumar analog

The results reported were obtained on a meteoric eucrite sample called Millbillillie Sample no. 173. Optical microscopy studies of the sample showed it to consist of ilmenite, troilite, and transparent gangue. The transparent gangue consisted of feldspar (anorthite), pyroxenes, olivines, and opaques. Troilite was present in minor quantities. Screen assay analyses of the 30, 100, 200, and 400 US mesh screen fractions showed that minor concentration of titanium occurred in the 200 x 400 and -400 mesh screen fractions. Scanning electron microscopy (SEM) studies of the bulk sample showed the presence of a variety of ilmenite grains, ranging from 50 microns down to less than 1 micron without any evidence of liberation. Electron Diffraction Scans (EDS) confirmed the ratio of Fe to Ti in the ilmenite grains. Dry magnetic separation in a Frantz Isodynamic Separator was found to be effective only at sizes finer than 150 microns (100 US mesh) and more so at 200 mesh (74 microns). In each case, dedusting of the sample to remove -400 mesh (-0.037 microns) fines was required. Liberation size was determined to be 200 mesh and finer. The highest grade concentrate assaying 3.45 percent Ti was produced by magnetic separation of the -200 + 400 mesh screen fraction assaying 0.44 Ti (from a -30 mesh sample) at a current setting of 0.35 AMP. This concentrate contained 21.2 percent of the Ti values in the screen fraction with 2.72 weight percent of feed to test. The results can be projected to a sample stage ground to -200 mesh. Magnetic separation of the 200 + 400 mesh (-0.074 + 0.037 microns) should produce a concentrate accounting for 1.41 weight percent of the feed. This concentrate will analyze 3.45 percent Ti and contain 10.3 percent of the Ti values in the feed. By changing the Frantz Magnetic Separator settings, a lower grade concentrate analyzing 0.98 percent Ti can be produced at an increased recovery of 25.4 percent. The concentrate weight will be 11.7 percent of the feed. It must be emphasized that improved grades and recoveries can be obtained with the -400 mesh fines. However, beneficiation of these extremely fine materials is not possible in a practical process scheme

Barrier island erosion and overwash study -- effect of seawalls. Volume 2

This is the second of a pair of reports documenting the effects of storms on beach systems including the presence of seawalls. With the aim of simulating the effects of overwash on barrier islands with seawalls and characterizing their response, a series of eight experiments was conducted at the Coastal Engineering Laboratory of the University of Florida. The barrier island was simulated by a 400 feet wide horizontal crest and an initially uniform mildly-sloped (1:19) beach. The effects of positioning the seawall at two different locations as well as the effects of various storm surge levels and accompanying overtopping were investigated. Experiments were conducted with both regular and irregular storm waves. With the seawall located at the slope break between the crest and the sloping beach of the barrier island, and the crest of the seawall just submerged in sand, the effects on the sediment transport process were found to be minimal. For the same position of the seawall but with the crest of the seawall raised above the surrounding ground level, overtopping caused washover of sand indicating substantial transport in suspension. Increased levels of overtopping tended to accentuate bed profile changes but supress bar formation (as did irregular waves). Positioning the seawall at the Mean Sea Level shoreline caused significant scour both immediately landward as well as immediately seaward of the seawall. A prominent scour trough developed further seaward. The longshore bar was highly three-dimensional. It appears that seawalls need to be located adequately landward of the shoreline to discharge their function effectively without adverse effect to the beach. In addition, concerns for safety warrant the presence of an adequate buffer-zone between the seawall and the upland property. (61 pp.

Perturbation theory for the effective diffusion constant in a medium of random scatterer

We develop perturbation theory and physically motivated resummations of the perturbation theory for the problem of a tracer particle diffusing in a random media. The random media contains point scatterers of density $\rho$ uniformly distributed through out the material. The tracer is a Langevin particle subjected to the quenched random force generated by the scatterers. Via our perturbative analysis we determine when the random potential can be approximated by a Gaussian random potential. We also develop a self-similar renormalisation group approach based on thinning out the scatterers, this scheme is similar to that used with success for diffusion in Gaussian random potentials and agrees with known exact results. To assess the accuracy of this approximation scheme its predictions are confronted with results obtained by numerical simulation.Comment: 22 pages, 6 figures, IOP (J. Phys. A. style

Symmetry Relations for Trajectories of a Brownian Motor

A Brownian Motor is a nanoscale or molecular device that combines the effects of thermal noise, spatial or temporal asymmetry, and directionless input energy to drive directed motion. Because of the input energy, Brownian motors function away from thermodynamic equilibrium and concepts such as linear response theory, fluctuation dissipation relations, and detailed balance do not apply. The {\em generalized} fluctuation-dissipation relation, however, states that even under strongly thermodynamically non-equilibrium conditions the ratio of the probability of a transition to the probability of the time-reverse of that transition is the exponent of the change in the internal energy of the system due to the transition. Here, we derive an extension of the generalized fluctuation dissipation theorem for a Brownian motor for the ratio between the probability for the motor to take a forward step and the probability to take a backward step

Effective diffusion constant in a two dimensional medium of charged point scatterers

We obtain exact results for the effective diffusion constant of a two dimensional Langevin tracer particle in the force field generated by charged point scatterers with quenched positions. We show that if the point scatterers have a screened Coulomb (Yukawa) potential and are uniformly and independently distributed then the effective diffusion constant obeys the Volgel-Fulcher-Tammann law where it vanishes. Exact results are also obtained for pure Coulomb scatterers frozen in an equilibrium configuration of the same temperature as that of the tracer.Comment: 9 pages IOP LaTex, no figure

Designing Democratic Innovations as Deliberative Systems: The Ambitious Case of NHS Citizen

What does it mean to design democratic innovation from a systems perspective? The demand of the deliberative systems approach that we turn from the single forum towards the broader system has largely been embraced by those interested in designing institutions for citizen participation. Nevertheless, there has been no analysis of the practical implications for democratic innovation. Is it possible to design differentiated but interconnected participatory and deliberative settings? Does this better connect democratic innovations to mass politics? Does it promote greater legitimacy? This article analyses one such attempt to design a deliberative system in the real world: the ambitious NHS Citizen initiative. Our analysis demonstrates, while NHS Citizen pioneered some cutting-edge participatory design, it ultimately failed to resolve (and in some cases exacerbated) well known obstacles to institutionalization, and generated new challenges. To effectively inform democratic renewal and reform, a systems approach must evolve strategies to ameliorate these challenges

A Detailed Investigation of Staged Normal Injection into a Mach 2 Flow

A study of the staged injection of two jets of air behind a rearward facing step into a Mach 2 flow was performed using the SPARK 3-D Navier-Stokes code. Calculated mole fraction distributions were compared with an extensive set of planar mole fraction measurements made with a laser induced iodine fluorescence technique. A statistical measure, the standard deviation, was used to help assess agreement between calculation and experiment. Overall, good agreement was found between calculated and measured values. Generally, agreement was better in the far field of the injectors. The effect of grid resolution was investigated by calculating solutions on grids of 60,000, 200,000, and 450,000 points. Differences in the solutions on the two finer grids were small. However, the mole fraction distributions were distinguishable. The effect of turbulence modeling was investigated by employing three different algebraic models for the jet turbulence: the Baldwin-Lomax model, the Prandtl mixing length model, and the Eggers mixing length model. Overall, the Eggers mixing length model was found to be superior for this case. Finally, the effect of the jet exit conditions was examined. A recently proposed Mach number distribution at the jet exit was found to slightly improve agreement between measurement and calculation

Some considerations on coastal processes relevant to sea level rise

The effects of potential sea level rise on the shoreline and shore environment have been briefly examined by considering the interactions between sea level rise and relevant coastal processes. These interactions have been reviewed beginning with a discussion of the need to reanalyze previous estimates of eustatic sea level rise and compaction effects in water level measurement. This is followed by considerations on sea level effects on coastal and estuarine tidal ranges, storm surge and water level response, and interaction with natural and constructed shoreline features. The desirability to reevaluate the well known Bruun Rule for estimating shoreline recession has been noted. The mechanics of ground and surface water intrusion with reference to sea level rise are then reviewed. This is followed by sedimentary processes in the estuaries including wetland response. Finally comments are included on some probable effects of sea level rise on coastal ecosystems. These interactions are complex and lead to shoreline evolution (under a sea level rise) which is highly site-specific. Models which determine shoreline change on the basis of inundation of terrestrial topography without considering relevant coastal processes are likely to lead to erroneous shoreline scenarios, particularly where the shoreline is composed of erodible sedimentary material. With some exceptions, present day knowledge of shoreline response to hydrodynamic forcing is inadequate for long-term quantitative predictions. A series of interrelated basic and applied research issues must be addressed in the coming decades to determine shoreline response to sea level change with an acceptable degree of confidence. (PDF contains 189 pages.

Influence of base and photoacid generator on deprotection blur in extreme ultraviolet photoresists and some thoughts on shot noise

A contact-hole deprotection blur metric has been used to monitor the deprotection blur of an experimental open platform resist (EH27) as the wt % of base and photoacid generator (PAG) were varied. A six times increase in base wt % is shown to reduce the size of successfully patterned 1:1 line-space features from 52 to 39 nm without changing deprotection blur. Corresponding isolated line edge roughness is reduced from 6.9 to 4.1 nm. A two times increase in PAG wt % is shown to improve 1:1 line-space patterning from 47 to 40 nm without changing deprotection blur or isolated line edge roughness. A discussion of improved patterning performance as related to shot noise and deprotection blur concludes with a speculation that the spatial distribution of PAG molecules has been playing some role, perhaps a dominant one, in determining the uniformity of photogenerated acids in the resists that have been studied. © 2008 American Vacuum Society