275 research outputs found
Controlled Organocatalytic Ring-Opening Polymerization of Δ-Thionocaprolactone
For the first time, the controlled ring-opening polymerization (ROP) of Δ-thionocaprolactone (tnCL) is conducted. The organocatalytic ROP of tnCL occurs without carbonyl scrambling, leading to homopoly(Δ-thionocaprolactone) (PtnCL). The ROP by base catalysts alone is proposed to proceed via a nucleophilic mechanism, while the addition of an H-bond donating thiourea (TU) is shown to provide excellent reaction control. The increased reaction control provided by the TU occurs in the virtual absence of binding between tnCL and TU, and a mechanistic account for this observation is discussed. The monomer ring strain is measured and found to be similar to Ύ-valerolactone (VL). Copolymers with VL are synthesized, and the resulting analysis of the copolymer materials properties provides the only known physical characterizations of poly(thio(no)ester-co-ester)s
Loosely bound hyperons in the SU(3) Skyrme model
Hyperon pairs bound in deuteron like states are obtained within the SU(3)
Skyrme model in agreement with general expectations from boson exchange models.
The central binding from the flavor symmetry breaking terms increases with the
strangeness contents of the interacting baryons whereas the kinetic non-linear
-model term fixes the spin and isospin of the bound pair. We give a
complete account of the interactions of octet baryons within the product
approximation to baryon number configurations.Comment: 35 pages REVTEX including 2 figs, with 3 further figs available on
request from [email protected] or from [email protected]
SI-94-TP3S2; STPHY-Th/94-
Semiclassical quantization of SU(3) skyrmions
Semiclassical quantization of the SU(3)-skyrmions is performed by means of
the collective coordinate method. The quantization condition known for the
SU(2)-solitons quantized with SU(3) collective coordinates is generalized for
the SU(3) skyrmions with strangeness content different from zero. Quantization
of the dipole-type configuration with large strangeness content found recently
is considered as an example, the spectrum and the mass splitting of the
quantized states are estimated. The energy and baryon number density of SU(3)
skyrmions are presented in the form emphasizing their symmetry in different
SU(2) subgroups of SU(3), and the lower boundary for the static energy of SU(3)
skyrmions is derived.Comment: 16 pages, 2 figures (available upon request). Submitted to JETP on
May 6, 1997; in print. A preliminary short version of this paper is
hep-th/960916
Flavor symmetry breaking effects on SU(3) Skyrmion
We study the massive SU(3) Skyrmion model to investigate the flavor symmetry
breaking (FSB) effects on the static properties of the strange baryons in the
framework of the rigid rotator quantization scheme combined with the improved
Dirac quantization one. Both the chiral symmetry breaking pion mass and FSB
kinetic terms are shown to improve the ratio of the strange-light to
light-light interaction strengths and that of the strange-strange to
light-light.Comment: 12 pages, latex, no figure
On the quantization of SU(3)-skyrmions
The quantization condition derived previously for SU(2) solitons quantized
with SU(3)-collective coordinates is generalized for SU(3) skyrmions with
strangeness content different from zero. Quantization of the dipole-type
configuration with large strangeness content found recently is considered as an
example.Comment: 7 pages, 2 figures (available by request
BARYON-BARYON INTERACTIONS IN LARGE N_C CHIRAL PERTURBATION THEORY
Interactions of two baryons are considered in large chiral perturbation
theory and compared to the interactions derived from the Skyrme model. Special
attention is given to a torus-like configuration known to be present in the
Skyrme model.Comment: 18 pages, REVTEX, 8 uuencoded PS figures appende
Mass and width of the resonance in nuclei
We calculated the mass and width of the resonance inside nuclei within a
nucleon- model by including the self-energy of the in the
propagator. We found that in the nuclear medium the width of the
is increased by one order of magnitude while its mass changes only by a few
MeV. This broadening of the width of the resonance embedded in nuclei is
consistent with the experimental observations so that the can be
understood as a resonance. Thus, given the freedom between either
isospin 0 or isospin 2 for the , our results give weigth to the isospin-2
assignment.Comment: 14 pages, RevteX type, 2 eps figures. To be published in Phys. Rev. C
(September
Hypernuclei as chiral solitons
The identification of flavored multiskyrmions with the ground states of known
hypernuclei is successful for several of them, e.g. for isodoublet H(Lambda) -
He(Lambda), A=4, isoscalars He(Lambda) (A=5) and Li(Lambda) (A=7). In other
cases agreement is not so good, but the behaviour of the binding energy with
increasing baryon number is in qualitative agreement with data. Charmed or
beauty hypernuclei within this approach are predicted to be bound stronger than
strange hypernuclei. This conclusion is stable against variation of poorly
known heavy flavor decay constants.Comment: 9 pages, 1 Fig. Presented at the International Workshops on Nuclear
and Particle Physics at 50-Gev PS, NP01 (KEK, Japan, December 2001) and NP02
(Kyoto, Japan, September 2002). Some additions and corrections of numerical
results are mad
Mass splittings of nuclear isotopes in chiral soliton approach
The differences of the masses of nuclear isotopes with atomic numbers between
\~10 and ~30 can be described within the chiral soliton approach in
satisfactory agreement with data. Rescaling of the model is necessary for this
purpose - decrease of the Skyrme constant by about 30%, providing the "nuclear
variant" of the model. The asymmetric term in Weizsaecker-Bethe- Bacher mass
formula for nuclei can be obtained as the isospin dependent quantum correction
to the nucleus energy. Some predictions for the binding energies of neutron
rich nuclides are made in this way, from, e.g. Be-16 and B-19 to Ne-31 and
Na-32. Neutron rich nuclides with high values of isospin are unstable relative
to strong interactions. The SK4 (Skyrme) variant of the model, as well as SK6
variant (6-th order term in chiral derivatives in the lagrangian as solitons
stabilizer) are considered, and the rational map approximation is used to
describe multiskyrmions.Comment: 16 pages, 10 tables, 2 figures. Figures are added and few misprints
are removed. Submitted to Phys. Atom. Nucl. (Yad. Fiz.
Dibaryons with Strangeness: their Weak Nonleptonic Decay using SU(3) Symmetry and how to find them in Relativistic Heavy-Ion Collisions
Weak SU(3) symmetry is successfully applied to the weak hadronic decay
amplitudes of octet hyperons. Weak nonmesonic and mesonic decays of various
dibaryons with strangeness, their dominant decay modes, and lifetimes are
calculated. Production estimates for BNL's Relativistic Heavy-Ion Collider are
presented employing wave function coalescence. Signals for detecting strange
dibaryon states in heavy-ion collisions and revealing information about the
unknown hyperon-hyperon interactions are outlined.Comment: 4 pages, 2 figures, uses RevTeX, discussion about the model of the
weak decay and experimental signals extended, references update
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