Fluctuation-dissipation relation in a sheared fluid

In a fluid out of equilibrium, the fluctuation dissipation theorem (FDT) is usually violated. Using molecular dynamics simulations, we study in detail the relationship between correlation and response functions in a fluid driven into a stationary non-equilibrium state. Both the high temperature fluid state and the low temperature glassy state are investigated. In the glassy state, the violation of the FDT is quantitatively identical to the one observed previously in an aging system in the absence of external drive. In the fluid state, violations of the FDT appear only when the fluid is driven beyond the linear response regime, and are then similar to those observed in the glassy state. These results are consistent with the picture obtained earlier from theoretical studies of driven mean-field disordered models, confirming the similarity between these models and real glasses.Comment: 4 pages, latex, 3 ps figure

Shearing a Glassy Material: Numerical Tests of Nonequilibrium Mode-Coupling Approaches and Experimental Proposals

The predictions of a nonequilibrium schematic mode-coupling theory developed to describe the nonlinear rheology of soft glassy materials have been numerically challenged in a sheared binary Lennard-Jones mixture. The theory gives an excellent description of the stress/temperature `jamming phase diagram' of the system. In the present paper, we focus on the issue of an effective temperature Teff for the slow modes of the fluid, as defined from a generalized fluctuation-dissipation theorem. As predicted theoretically, many different observables are found to lead to the same value of Teff, suggesting several experimental procedures to measure Teff. New, simple experimental protocols to access Teff from a generalized equipartition theorem are also proposed, and one such experiment is numerically performed. These results give strong support to the thermodynamic interpretation of Teff and make it experimentally accessible in a very direct way.Comment: Version accepted for publication - Physical Review Letter

Crossovers in the dynamics of supercooled liquids probed by an amorphous wall

We study the relaxation dynamics of a binary Lennard-Jones liquid in the presence of an amorphous wall generated from equilibrium particle configurations. In qualitative agreement with the results presented in Nature Phys. {\bf 8}, 164 (2012) for a liquid of harmonic spheres, we find that our binary mixture shows a saturation of the dynamical length scale close to the mode-coupling temperature $T_c$. Furthermore we show that, due to the broken symmetry imposed by the wall, signatures of an additional change in dynamics become apparent at a temperature well above $T_c$. We provide evidence that this modification in the relaxation dynamics occurs at a recently proposed dynamical crossover temperature $T_s > T_c$, which is related to the breakdown of the Stokes-Einstein relation. We find that this dynamical crossover at $T_s$ is also observed for a system of harmonic spheres as well as a WCA liquid, showing that it may be a general feature of glass-forming systems.Comment: 10 pages, 8 figure

A quantitative test of the mode-coupling theory of the ideal glass transition for a binary Lennard-Jones system

Using a molecular dynamics computer simulation we determine the temperature dependence of the partial structure factors for a binary Lennard-Jones system. These structure factors are used as input data to solve numerically the wave-vector dependent mode-coupling equations in the long time limit. Using the so determined solutions, we compare the predictions of mode-coupling theory (MCT) with the results of a previously done molecular dynamics computer simulation [Phys. Rev. E 51, 4626 (1995), ibid. 52, 4134 (1995)]. From this comparison we conclude that MCT gives a fair estimate of the critical coupling constant, a good estimate of the exponent parameter, predicts the wave-vector dependence of the various nonergodicity parameters very well, except for very large wave-vectors, and gives also a very good description of the space dependence of the various critical amplitudes. In an attempt to correct for some of the remaining discrepancies between the theory and the results of the simulation, we investigate two small (ad hoc) modifications of the theory. We find that one modification gives a worse agreement between theory and simulation, whereas the second one leads to an improved agreement.Comment: Figures available from W. Ko

Coupling/decoupling between translational and rotational dynamics in a supercooled molecular liquid

We use molecular dynamics computer simulations to investigate the coupling/decoupling between translational and rotational dynamics in a glass-forming liquid of dumbbells. This is done via a careful analysis of the $\alpha$-relaxation time $\tau_{q^{*}}^{\rm C}$ of the incoherent center-of-mass density correlator at the structure factor peak, the $\alpha$-relaxation time $\tau_{2}$ of the reorientational correlator, and the translational ($D_{t}$) and rotational ($D_{r}$) diffusion constants. We find that the coupling between the relaxation times $\tau_{q^{*}}^{\rm C}$ and $\tau_{2}$ increases with decreasing temperature $T$, whereas the coupling decreases between the diffusivities $D_{t}$ and $D_{r}$. In addition, the $T$-dependence of $D_{t}$ decouples from that of $1/\tau_{2}$, which is consistent with previous experiments and has been interpreted as a signature of the "translation-rotation decoupling." We trace back these apparently contradicting observations to the dynamical heterogeneities in the system. We show that the decreasing coupling in the diffusivities $D_{t}$ and $D_{r}$ is only apparent due to the inadequacy of the concept of the rotational diffusion constant for describing the reorientational dynamics in the supercooled state. We also argue that the coupling between $\tau_{q^{*}}^{\rm C}$ and $\tau_{2}$ and the decoupling between $D_{t}$ and $1/\tau_{2}$, both of which strengthen upon cooling, can be consistently understood in terms of the growing dynamic length scale.Comment: revised manuscript, to appear in Phys. Rev. Let

Slow Dynamics in Glasses

Minimalist theories of complex systems are broadly of two kinds: mean-field and axiomatic. So far all theories of complex properties absent from simple systems and intrinsic to glasses are axiomatic. Stretched Exponential Relaxation (SER) is the prototypical complex temporal property of glasses, discovered by Kohlrausch 150 years ago, and now observed almost universally in microscopically homogeneous, complex non-equilibrium materials, including luminescent electronic (Coulomb) glasses. Critical comparison of alternative axiomatic theories with both numerical simulations and experiments strongly favors dynamical trap models over static percolative or energy landscape models. PACS: 61.20.Lc; 67.40.F

Democratic particle motion for meta-basin transitions in simple glass-formers

We use molecular dynamics computer simulations to investigate the local motion of the particles in a supercooled simple liquid. Using the concept of the distance matrix we find that the alpha-relaxation corresponds to a small number of crossings from one meta-basin to a neighboring one. Each crossing is very rapid and involves the collective motion of O(40) particles that form a relatively compact cluster, whereas string-like motions seem not to be relevant for these transitions. These compact clusters are thus candidates for the cooperatively rearranging regions proposed long times ago by Adam and Gibbs.Comment: 4 pages, 4 Postscript figure

Test of mode coupling theory for a supercooled liquid of diatomic molecules. II. q-dependent orientational correlators

Using molecular dynamics computer simulations we study the dynamics of a molecular liquid by means of a general class of time-dependent correlators S_{ll'}^m(q,t) which explicitly involve translational (TDOF) and orientational degrees of freedom (ODOF). The system is composed of rigid, linear molecules with Lennard- Jones interactions. The q-dependence of the static correlators S_{ll'}^m(q) strongly depend on l, l' and m. The time dependent correlators are calculated for l=l'. A thorough test of the predictions of mode coupling theory (MCT) is performed for S_{ll}^m(q,t) and its self part S_{ll}^{(s)m}(q,t), for l=1,..,6. We find a clear signature for the existence of a single temperature T_c, at which the dynamics changes significantly. The first scaling law of MCT, which involves the critical correlator G(t), holds for l>=2, but no critical law is observed. Since this is true for the same exponent parameter lambda as obtained for the TDOF, we obtain a consistent description of both, the TDOF and ODOF, with the exception of l=1. This different behavior for l \ne 1 and l=1 can also be seen from the corresponding susceptibilities (chi'')_{ll}^m(q,omega) which exhibit a minimum at about the same frequency omega_{min} for all q and all l \ne 1, in contrast to (chi'')_{11}^m(q,omega) for which omega'_{min} approx 10 omega_{min} . The asymptotic regime, for which the first scaling law holds, shrinks with increasing l. The second scaling law of MCT (time-temperature superposition principle) is reasonably fulfilled for l \ne 1 but not for l=1. Furthermore we show that the q- and (l,m)-dependence of the self part approximately factorizes, i.e. S_{ll}^{(s)m}(q,t) \cong C_l^{(s)}(t) F_s(q,t) for all m.Comment: 11 pages of RevTex, 16 figure

Fluctuation dissipation ratio in an aging Lennard-Jones glass

By using extensive Molecular Dynamics simulations, we have determined the violation of the fluctuation-dissipation theorem in a Lennard-Jones liquid quenched to low temperatures. For this we have calculated $X(C)$, the ratio between a one particle time-correlation function $C$ and the associated response function. Our results are best fitted by assuming that $X(C)$ is a discontinuous, piecewise constant function. This is similar to what is found in spin systems with one step replica symmetry breaking. This strengthen the conjecture of a similarity between the phase space structure of structural glasses and such spin systems.Comment: improved data and metho

Growing spatial correlations of particle displacements in a simulated liquid on cooling toward the glass transition

We define a correlation function that quantifies the spatial correlation of single-particle displacements in liquids and amorphous materials. We show for an equilibrium liquid that this function is related to fluctuations in a bulk dynamical variable. We evaluate this function using computer simulations of an equilibrium glass-forming liquid, and show that long range spatial correlations of displacements emerge and grow on cooling toward the mode coupling critical temperature