Fabrication of Spherical CaO-SrO-ZnO-SiO2 Particles by Sol-Gel Processing

This study was concerned with the fabrication of ceramic CaO-SrO-ZnO-SiO2 spherical particles, which are novel candidates for the glass phase in glass polyalkenoate cements (GPCs). GPCs made from these glasses have potential as bone cements because, unlike conventional GPCs, they do not contain aluminum ions, which inhibit the calcification of hydroxyapatite in the body. The glass phase of GPCs require a controllable glass morphology and particle size distribution. Sol-gel processing can potentially be used to fabricate homogenous ceramic particles with controlled morphology. However, a thorough study on preparation conditions of spherical CaO-SrO-ZnO-SiO2 particles by sol-gel processing has, to date, not been reported. In this study, gels were prepared by hydrolysis and polycondensation of tetraethoxysilane (TEOS) in an aqueous solution containing polyethylene glycol and nitrates of calcium, strontium and zinc. It was possible to control the morphology and size of the gels by varying the H2O/TEOS molar ratio and the metal ion content in the starting compositions. An aliquot of 3-5 μm homogenous spherical particles were obtained at a H2O/TEOS molar ratio of 42.6 when the starting composition molar ratios were Sr(NO 3):Ca(NO3)2:Zn(NO3) 2:Si(OC2H5)4 = x:0.12:(0.40 - x):0.48 (0 ≤ x ≤ 0.8). Starting composition limitations are caused by the low solubility of strontium ions in the minimal amount of water used and the acceleration of hydrolysis as well as polycondensation at higher water content. © 2009 Springer Science+Business Media, LLC

Characteristics of Glass Ionomer Cements Composed of Glass Powders in CaO-SrO-ZnO-SiO2 System Prepared by Two Different Synthetic Routes

Glass ionomer cements (GICs) are composed of an acid degradable glass, polyacrylic acid and water. Sol-gel processing to prepare the glass phase has certain advantages, such as the ability to employ lower synthesis temperatures than melt quenching and glasses that are reported to have higher purity. A previous study reported the effects of glass synthesis route on GIC fabrication. However, in that study, the sol-gel derived glass exhibited a reduced concentration of cations. This study investigates increasing the cation content of a sol-gel derived glass, 12CaO·4SrO·36ZnO·48SiO2 (molar ratio) by heating before aging to reduce dissolution of cations. This glass was prepared by both sol-gel and melt-quenched routes. GICs were subsequently prepared using both glasses. The resultant cement based on the sol-gel derived glass had a shorter working time than the cement based on the melt-quenched one. Contrary to this, setting time was considerably longer for the cement based on the sol-gel derived glass than for the cement based on the melt-quenched one. The cements based on the sol-gel derived glass were stronger in both compression and biaxial flexure than the cements prepared from the melt-quenched glass. The differences in setting and mechanical properties were associated with both cation content in the glass phase and the different surface area of the resultant cements. © 2013 Springer Science+Business Media New York

Aircraft computations using multigrid and an unstructured parallel library

This paper examines the application of unstructured multigrid, using a sequence of independent tetrahedral grids. The test cases examined are for inviscid flow over an aircraft and an M6 wing. The sensitivity of the method to grid sequence and cycling strategy are investigated. \ud \ud All of the calculations were performed on a parallel computer. This was achieved by using the OPlus library which, by the straightforward insertion of subroutine calls, facilitates parallelisation of the resulting code. A single source OPlus application code can be compiled to executed on either a parallel or sequential machine. This greatly increases the usability of the parallel machine, and the maintainability of the code

Safety Data: Costs, Quality and Strategies for Improvement- Executive Summary

FHWA-RD-96-027The objectives of this project were to examine the costs and quality of safety data and to identify improvement strategies. The project's scope was narrowed to three key sources: the crash report, roadway inventories, and medical records. The primary focus was on crash reporting. Within the medical source, the focus was upon data regarding driver condition prior to crash, and injury severity, since these are of high interest to the highway community. Since the same piece of data will have a different quality for different users and uses, it was necessary to identify the variety of users and uses of highway safety data. This executive summary presents an overview of the research results. The complete results are available in the research report (FHWA-RD-96-191) and the final report (FHWA-RD-96-192)

A unified in vitro evaluation for apatite-forming ability of bioactive glasses and their variants

The aim of this study was to propose and validate a new unified method for testing dissolution rates of bioactive glasses and their variants, and the formation of calcium phosphate layer formation on their surface, which is an indicator of bioactivity. At present, comparison in the literature is difficult as many groups use different testing protocols. An ISO standard covers the use of simulated body fluid on standard shape materials but it does not take into account that bioactive glasses can have very different specific surface areas, as for glass powders. Validation of the proposed modified test was through round robin testing and comparison to the ISO standard where appropriate. The proposed test uses fixed mass per solution volume ratio and agitated solution. The round robin study showed differences in hydroxyapatite nucleation on glasses of different composition and between glasses of the same composition but different particle size. The results were reproducible between research facilities. Researchers should use this method when testing new glasses, or their variants, to enable comparison between the literature in the future