83 research outputs found
Dual kinetic balance approach to basis set expansions for the Dirac equation
A new approach to finite basis sets for the Dirac equation is developed. It
solves the problem of spurious states and, as a result, improves the
convergence properties of basis set calculations. The efficiency of the method
is demonstrated for finite basis sets constructed from B splines by calculating
the one-loop self-energy correction for a hydrogenlike ion.Comment: 14 pages, 1 tabl
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Effectiveness of a quality improvement collaborative in reducing time to surgery for patients requiring emergency cholecystectomy.
Background:Acute gallstone disease is a high-volume emergency general surgery presentation with wide variations in the quality of care provided across the UK. This controlled cohort evaluation assessed whether participation in a quality improvement collaborative approach reduced time to surgery for patients with acute gallstone disease to fewer than 8 days from presentation, in line with national guidance. Methods:Patients admitted to hospital with acute biliary conditions in England and Wales between 1 April 2014 and 31 December 2017 were identified from Hospital Episode Statistics data. Time series of quarterly activity were produced for the Cholecystectomy Quality Improvement Collaborative (Chole-QuIC) and all other acute National Health Service hospitals (control group). A negative binomial regression model was used to compare the proportion of patients having surgery within 8 days in the baseline and intervention periods. Results:Of 13 sites invited to join Chole-QuIC, 12 participated throughout the collaborative, which ran from October 2016 to January 2018. Of 7944 admissions, 1160 patients had a cholecystectomy within 8 days of admission, a significant improvement (P < 0·050) from baseline performance. This represented a relative change of 1·56 (95 per cent c.i. 1·38 to 1·75), compared with 1·08 for the control group. At the individual site level, eight of the 12 Chole-QuIC sites showed a significant improvement (P < 0·050), with four sites increasing their 8-day surgery rate to over 20 per cent of all emergency admissions, well above the mean of 15·3 per cent for control hospitals. Conclusion:A surgeon-led quality improvement collaborative approach improved care for patients requiring emergency cholecystectomy
Electric dipole moment of the electron in YbF molecule
Ab initio calculation of the hyperfine, P-odd, and P,T-odd constants for the
YbF molecule was performed with the help of the recently developed technique,
which allows to take into account correlations and polarization in the
outercore region. The ground state electronic wave function of the YbF molecule
is found with the help of the Relativistic Effective Core Potential method
followed by the restoration of molecular four-component spinors in the core
region of ytterbium in the framework of a non-variational procedure. Core
polarization effects are included with the help of the atomic Many Body
Perturbation Theory for Yb atom. For the isotropic hyperfine constant A,
accuracy of our calculation is about 3% as compared to the experimental datum.
The dipole constant Ad (which is much smaller in magnitude), though better than
in all previous calculations, is still underestimated by almost 23%. Being
corrected within a semiempirical approach for a perturbation of 4f-shell in the
core of Yb due to the bond making, this error is reduced to 8%. Our value for
the effective electric field on the unpaired electron is 4.9 a.u.=2.5E+10 V/cm.Comment: 7 pages, REVTE
Experimental ionization of atomic hydrogen with few-cycle pulses
We present the first experimental data on strong-field ionization of atomic
hydrogen by few-cycle laser pulses. We obtain quantitative agreement at the 10%
level between the data and an {\it ab initio} simulation over a wide range of
laser intensities and electron energies
A useful form of the recurrence relation between relativistic atomic matrix elements of radial powers
Recently obtained recurrence formulae for relativistic hydrogenic radial
matrix elements are cast in a simpler and perhaps more useful form. This is
achieved with the help of a new relation between the and the
terms ( is a Dirac matrix and are constants) in the
atomic matrix elements.Comment: 7 pages, no figure
Calculation of T_ odd effects in $"" sup 205_TIF including electron correlation
A method and codes for two-step correlation calculation of heavy-atom
molecules have been developed, employing the generalized relativistic effective
core potential and relativistic coupled cluster (RCC) methods at the first
step, followed by nonvariational one-center restoration of proper
four-component spinors in the heavy cores. Electron correlation is included for
the first time in an ab initio calculation of the interaction of the permanent
P,T-odd proton electric dipole moment with the internal electromagnetic field
in a molecule. The calculation is performed for the ground state of TlF at the
experimental equilibrium, R_e=2.0844 A, and at R=2.1 A, with spin-orbit and
correlation effects included by RCC. Calculated results with single cluster
amplitudes only are in good agreement (3% and 1%) with recent
Dirac-Hartree-Fock (DHF) values of the magnetic parameter M; the larger
differences occurring between present and DHF volume parameter (X) values, as
well as between the two DHF calculations, are explained. Inclusion of electron
correlation by GRECP/RCC with single and double excitations has a major effect
on the P,T-odd parameters, decreasing M by 17% and X by 22%.Comment: 5 pages, REVTeX4 style Accepted for publication in Phys.Rev.Letter
Measurement of the electron's electric dipole moment using YbF molecules: methods and data analysis
We recently reported a new measurement of the electron's electric dipole
moment using YbF molecules [Nature 473, 493 (2011)]. Here, we give a more
detailed description of the methods used to make this measurement, along with a
fuller analysis of the data. We show how our methods isolate the electric
dipole moment from imperfections in the experiment that might mimic it. We
describe the systematic errors that we discovered, and the small corrections
that we made to account for these. By making a set of additional measurements
with greatly exaggerated experimental imperfections, we find upper bounds on
possible uncorrected systematic errors which we use to determine the systematic
uncertainty in the measurement. We also calculate the size of some systematic
effects that have been important in previous electric dipole moment
measurements, such as the motional magnetic field effect and the geometric
phase, and show them to be negligibly small in the present experiment. Our
result is consistent with an electric dipole moment of zero, so we provide
upper bounds to its size at various confidence levels. Finally, we review the
prospects for future improvements in the precision of the experiment.Comment: 35 pages, 15 figure
Recurrence relation for relativistic atomic matrix elements
Recurrence formulae for arbitrary hydrogenic radial matrix elements are
obtained in the Dirac form of relativistic quantum mechanics. Our approach is
inspired on the relativistic extension of the second hypervirial method that
has been succesfully employed to deduce an analogous relationship in non
relativistic quantum mechanics. We obtain first the relativistic extension of
the second hypervirial and then the relativistic recurrence relation.
Furthermore, we use such relation to deduce relativistic versions of the
Pasternack-Sternheimer rule and of the virial theorem.Comment: 10 pages, no figure
Measurement of laser intensities approaching 10 15 W/cm 2 with an accuracy of 1%
Accurate knowledge of the intensity of focused ultrashort laser pulses is crucial to the correct interpretation of experimental results in strong-field physics. We have developed a technique to measure laser intensities approaching 1015W/cm2 with an accu
Measurement of the electron electric dipole moment using YbF molecules
The most sensitive measurements of the electron electric dipole moment d_e
have previously been made using heavy atoms. Heavy polar molecules offer a
greater sensitivity to d_e because the interaction energy to be measured is
typically 10^3 times larger than in a heavy atom. We report the first
measurement of this kind, for which we have used the molecule YbF. Together,
the large interaction energy and the strong tensor polarizability of the
molecule make our experiment essentially free of the systematic errors that
currently limit d_e measurements in atoms. Our first result d_e = (- 0.2 \pm
3.2) x 10^-26 e.cm is less sensitive than the best atom measurement, but is
limited only by counting statistics and demonstrates the power of the method.Comment: 4 pages, 4 figures. v2. Minor corrections and clarifications made in
response to referee comment
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