Monostable Super Antiwettability

Super-antiwettability is an extreme situation of wetting where liquids stay at the tops of rough surfaces, in the so-called Cassie state1. Owing to the dramatic reduction of solid/liquid contact, it has many applications, such as antifouling2,3, droplet manipulation4,5, and self-cleaning6-9. However, super-antiwettability is often destroyed by impalement transitions caused by environmental disturbances10-16 while inverse transitions without energy input have never been observed12,17-21. Here we show through controlled experiments that there is a "monostable" region in the phase space of the receding contact angle and roughness parameters where transitions between (impaled) Wenzel and Cassie states can be reversible. We describe the transition mechanism and establish a simple criterion that predicts the experimentally observed Wenzel-to-Cassie transitions for different liquids placed on micropost-patterned substrates. These results can guide for designing and engineering robust super-antiwetting surfaces.Comment: 12 pages, 4 figure

Control of Surface Wettability via Strain Engineering

Reversible control of surface wettability has wide applications in lab-on-chip systems, tunable optical lenses, and microfluidic tools. Using a graphene sheet as a sample material and molecular dynamic (MD) simulations, we demonstrate that strain engineering can serve as an effective way to control the surface wettability. The contact angles $\theta$ of water droplets on a graphene vary from 72.5$^\circ$ to 106$^\circ$ under biaxial strains ranging from -10% to 10% that are applied on the graphene layer. For an intrinsic hydrophilic surface (at zero strain), the variation of $\theta$ upon the applied strains is more sensitive, i.e., from 0$^\circ$ to 74.8$^\circ$. Overall the cosines of the contact angles exhibit a linear relation with respect to the strains. In light of the inherent dependence of the contact angle on liquid-solid interfacial energy, we develop an analytic model to show the $\cos \theta$ as a linear function of the adsorption energy $E_{ads}$ of a single water molecule over the substrate surface. This model agrees with our MD results very well. Together with the linear dependence of $E_{ads}$ on biaxial strains, we can thus understand the effect of strains on the surface wettability. Thanks to the ease of reversibly applying mechanical strains in micro/nano-electromechanical systems (MEMS/NEMS), we believe that strain engineering can be a promising means to achieve the reversibly control of surface wettability.Comment: Submitted to Physical Review E on September 17, 2012, manuscript ID: EW1084

An Irreducible Function Basis of Isotropic Invariants of A Third Order Three-Dimensional Symmetric Tensor

In this paper, we present an eleven invariant isotropic irreducible function basis of a third order three-dimensional symmetric tensor. This irreducible function basis is a proper subset of the Olive-Auffray minimal isotropic integrity basis of that tensor. The octic invariant and a sextic invariant in the Olive-Auffray integrity basis are dropped out. This result is of significance to the further research of irreducible function bases of higher order tensors

Superlubric Nanogenerators with Superb Performances

Nanogenerators promise self-powered sensors and devices for extensive applications in internet of things, sensor networks, big data, personal healthcare systems, artificial intelligence, et al. However, low electric current densities and short product lifespans have blocked nanogenerators' applications. Here we show that structural superlubricity, a state of nearly zero friction and wear between two contacted solid surfaces, provides a revolutionary solution to the above challenge. We investigate three types of superlubric nanogenerators (SLNGs), namely the capacitor-based, triboelectric, and electret-based SLNGs, and systematically analyze the influences of material and structural parameters to these SLNGs' performances. We demonstrate that SLNGs can achieve not only enduring lifespans, but also superb performances - three orders of magnitude in current densities and output powers higher than those of conventional nanogenerators. Furthermore, SLNGs can be driven by very weak external loads (down to ~1 ${\mu}$N) in very low frequencies (down to ~1 ${\mu}$Hz), and are thus capable to harvest electric energies from an extremely board spectrum of environments and biosystems. Among the three types of SLNGs, the capacitor-based is synthetically most competitive in the senses of performance, fabrication and maintaining. These results can guide designs and accelerate fabrications of SLNGs toward real applications.Comment: 14 pages, 4 figure

Curvature Gradient Driving Droplets in Fast Motion

Earlier works found out spontaneous directional motion of liquid droplets on hydrophilic conical surfaces, however, not hydrophobic case. Here we show that droplets on any surface may take place spontaneous directional motion without considering contact angle property. The driving force is found to be proportional to the curvature gradient of the surface. Fast motion can be lead at surfaces with small curvature radii. The above discovery can help to create more effective transportation technology of droplets, and better understand some observed natural phenomena.Comment: 18 pages, 7 figure

Rotational instability in superlubric joints

Surface and interfacial energies play important roles in a number of instability phenomena in liquids and soft matters, but are rare to play a similar role in solids. Here we report a new type of mechanical instabilities that are controlled by surface and interfacial energies and are valid for a large class of materials, in particular two-dimensional layered materials. When sliding a top flake cleaved from a square microscale graphite mesa by using a probe acted on the flake through a point contact, we observed that the flake moved unrotationally for a certain distance before it suddenly transferred to a rotating-moving state. The theoretical analysis that agrees well with the experimental observation reveals that this mechanical instability is an interesting effect of the structural superlubricity (a state of nearly zero friction). Our further analysis shows that this type of instability holds generally for various sliding joints on different scales, as long as the friction is ultralow. Thus, the uncovered mechanism provides useful knowledge for manipulating and controlling all these sliding joints, and can guide design of future structural superlubricity based devices.Comment: 9 pages, 4 figure

Drop Impact on Two-Tier Monostable Superrepellent Surfaces

Superrepellency is a favorable non-wetting situation featured by a dramatically reduced solid/liquid contact region with extremely low adhesion. However, drop impact often brings out a notable extension of the contact region associated with rather enhanced water affinity, such renders irreversible breakdowns of superhydrophobicity. Here, we report an alternative outcome, a repeated Cassie-Wenzel-Cassie (CWC) wetting state transition in the microscale occurs when a drop impacts a two-tier superhydrophobic surface, which exhibits a striking contrast to the conventional perspective. Influences of material parameters on the impact dynamics are quantified. We demonstrate that self-cleaning and dropwise condensation significantly benefit from this outcome - dirt particles or small droplets in deep textures can be taken away through the transition. The results reported in this study allows us to promote the strategy to design functional superrepellency materials.Comment: 20 pages, 5 figure

Frictional scattering and frictional waveguides: achieving persistent superlubricity at high velocity on the nanoscale

Nanomechanical devices can operate at much higher speeds than their macroscopic analogues, due to low inertia. For example, peak speeds >100m/s have been predicted for carbon nanotube devices. This stimulates our interest in the atomic-scale physics of friction at high velocity. Here we study a model nanosystem consisting of a graphene flake moving freely on a graphite substrate at >100m/s. Using molecular dynamics we discover that ultra-low friction, or superlubricity, is punctuated by high-friction transients as the flake rotates through successive crystallographic alignments with the substrate. We term this phenomenon frictional scattering and show that it is mathematically analogous to Bragg scattering. We also show that frictional scattering can be eliminated by using graphitic nanoribbons as frictional waveguides to constrain the flake rotation, thus achieving persistent superlubricity. Finally, we propose an experimental method to study nanoscale high-velocity friction. These results may guide the design of efficient high-frequency nanomechanical devices

Accurate Measurement of the Cleavage Energy of Graphite

The basal plane cleavage energy (CE) of graphite is a key material parameter for understanding many of the unusual properties of graphite, graphene, and carbon nanotubes. The CE is equal to twice the surface energy and is closely related to the interlayer binding energy and exfoliation energy of graphite. Nonetheless, a wide range of values for these properties have been reported and no consensus has yet emerged as to their magnitude. Here, we report the first direct, accurate experimental measurement of the CE of graphite using a novel method based on the recently discovered self-retraction phenomenon in graphite. The measured value, 0.37 +/- 0.01 J/m2 for the incommensurate state of bicrystal graphite, is nearly invariant with respect to temperature (from 22{\deg}C to 198{\deg}C) and bicrystal twist angle, and insensitive to impurities (from the atmosphere). The cleavage energy for the ideal ABAB graphite stacking, 0.39 +/- 0.02 J/m2, is calculated based upon a combination of the measured CE and a theoretical calculation. These experimental measurements are ideal for use in evaluating the efficacy of competing theoretical approaches

Interlayer shear strength of single crystalline graphite

Reported values (0.2 MPa ~ 7.0 GPa) of the interlayer shear strength (ISS) of graphite are very dispersed. The main challenge to obtain a reliable value of ISS is the lack of precise experimental methods. Here we present a novel experimental approach to measure the ISS, and obtain the value as 0.14 GPa. Our result can serve as an important basis for understanding mechanical behavior of graphite or graphene-based materials.Comment: 11 pages, 5 figure