Weak Magnetic Field Accelerates Chromate Removal by Zero-Valent Iron

Weak magnetic field (WMF) was employed to improve the removal of Cr(VI) by zero-valent iron (ZVI) for the first time. The removal rate of Cr(VI) was elevated by a factor of 1.12-5.89 due to the application of a WMF, and the WMF-induced improvement was more remarkable at higher Cr(VI) concentration and higher pH. Fe2+ was not detected until Cr(VI) was exhausted, and there was a positive correlation between the WMF-induced promotion factor of Cr(VI) removal rate and that of Fe2+ release rate in the absence of Cr(VI) at pH 4.0-5.5. These phenomena imply that ZVI corrosion with Fe2+ release was the limiting step in the process of Cr(VI) removal. The superimposed WMF had negligible influence on the apparent activation energy of Cr(VI) removal by ZVI, indicating that WMF accelerated Cr(VI) removal by ZVI but did not change the mechanism. The passive layer formed with WMF was much more porous than without WMF, thereby facilitating mass transport. Therefore, WMF could accelerate ZVI corrosion and alleviate the detrimental effects of the passive layer, resulting in more rapid removal of Cr(VI) by ZVI. Exploiting the magnetic memory of ZVI, a two-stage process consisting of a small reactor with WMF for ZVI magnetization and a large reactor for removing contaminants by magnetized ZVI can be employed as a new method of ZVI-mediated remediation

Investigation of the Corrosion Behavior of Electroless Ni-P Coating in Flue Gas Condensate

The corrosion behavior of Ni-P coating deposited on 3003 aluminum alloy in flue gas condensate was investigated by electrochemical approaches. The results indicated that nitrite acted as a corrosion inhibitor. The inhibiting effect of nitrite was reduced in solutions containing sulfate or nitrate. Chloride and sulfate accelerated the corrosion of Ni-P coatings greatly. This can provide important information for the researchers to develop special Ni-P coatings with high corrosion resistance in the flue gas condensate

Premagnetization for Enhancing the Reactivity of Multiple Zerovalent Iron Samples toward Various Contaminants

Premagnetization was applied to enhance the removal of various oxidative contaminants (including amaranth (AR27), lead ion (Pb²⁺), cupric ion (Cu²⁺), selenite (Se⁴⁺), silver ion (Ag⁺), and chromate (Cr⁶⁺)) by zerovalent iron (ZVI) from different origins under well-controlled experimental conditions. The rate constants of contaminants by premagnetized ZVI (Mag-ZVI) samples were 1.2–12.2-fold greater than those by pristine ZVI (Pri-ZVI) samples. Generally, there was a linear correlation between the specific reaction rate constants (<i>k</i>_SA) of one particular contaminant removal by various Pri-ZVI or Mag-ZVI samples and those of the other contaminant, which could be successfully employed to predict the <i>k</i>_SA of one contaminant by one ZVI sample if <i>k</i>_SA of the other contaminant by this ZVI sample was available. The specific rate constant of Fe­(II) release at pH 4.0 was proposed in this study to stand for the intrinsic reactivity of a ZVI sample. All Mag-ZVI samples had higher intrinsic reactivity than their counterparts without premagnetization. There were strong correlations between the intrinsic reactivity of various Pri-ZVI/Mag-ZVI samples and the removal rate constants of a specific contaminant by these ZVI samples not only at pH 4.0 when the intrinsic reactivity was determined but also at other pH levels. This correlation could be employed to predict the removal rate constant of this contaminant by a ZVI sample that was not included in the original data set once the intrinsic reactivity of the ZVI sample was known

Enhancing corrosion resistance of ZK60 magnesium alloys via Ca microalloying: The impact of nanoscale precipitates

Enhancing corrosion resistance of Mg-Zn alloys with high strength and low cost was critical for broadening their large-scale practical applications. Here we prepared solutionized, peak- and over-aged ZK60 alloys with and without microalloying Ca (0.26 wt.%) to explore the effects of nanoscale precipitates on their corrosion behavior in detail via experimental analyses and theoretical calculations. The results suggested the peak-aged ZK60 alloy with Ca addition showed improved corrosion resistance in comparison with the alloys without Ca, owing to the contribution of Ca on the refinement of precipitates and increase in their number density. Although the precipitates and Mg matrix formed micro-galvanic couples leading to dissolution, the fine and dense precipitates could generate “in-situ pinning” effect on the corrosion products, forming a spider-web-like structure and improving the corrosion inhibition ability accordingly. The pinning effect was closely related to the size and number density of precipitates. This study provided important insight into the design and development of advanced corrosion resistant Mg alloys

Combined Effect of Weak Magnetic Fields and Anions on Arsenite Sequestration by Zerovalent Iron: Kinetics and Mechanisms

In this study, the effects of major anions (e.g., ClO₄^–, NO₃^–, Cl^–, and SO₄^2–) in water on the reactivity of zerovalent iron (ZVI) toward As­(III) sequestration were evaluated with and without a weak magnetic field (WMF). Without WMF, ClO₄^– and NO₃^– had negligible influence on As­(III) removal by ZVI, but Cl^– and SO₄^2– could improve As­(III) sequestration by ZVI. Moreover, the WMF-enhancing effect on As­(III) removal by ZVI was minor in ultrapure water. A synergetic effect of WMF and individual anion on improving As­(III) removal by ZVI was observed for each of the investigated anion, which became more pronounced as the concentration of anion increased. Based on the extent of enhancing effects, these anions were ranked in the order of SO₄^2– > Cl^– > NO₃^– ≈ ClO₄^– (from most- to least-enhanced). Furthermore, the inhibitory effect of HSiO₃^–, HCO₃^–, and H₂PO₄^– on ZVI corrosion could be alleviated taking advantage of the combined effect of WMF and SO₄^2–. The coupled influence of anions and WMF was associated with the simultaneous movement of anions with paramagnetic Fe²⁺ to keep local electroneutrality in solution. Our findings suggest that the presence of anions is quite essential to maintaining or stimulating the WMF effect

Comparative Characterization and Pathogenicity of a Novel Porcine Epidemic Diarrhea Virus (PEDV) with a Naturally Occurring Truncated ORF3 Gene Coinfected with PEDVs Possessing an Intact ORF3 Gene in Piglets

Coinfection caused by various genotypes of porcine epidemic diarrhea virus (PEDV) is a new disease situation. We previously reported the coexistence of PEDV strains containing different ORF3 genotypes in China. In this study, the PEDV strains 17GXCZ-1ORF3d and 17GXCZ-1ORF3c were isolated and plaque-purified from the same piglet, which had a natural large deletion at the 172–554 bp position of the ORF3 gene or possessed a complete ORF3 gene, respectively. Meanwhile, 17GXCZ-1ORF3d had &gt;99% nt identity with 17GXCZ-1ORF3c in the 5′UTR, ORF1a/1b, S, E, M, N and 3′UTR regions but only demonstrated low nucleotide identities (80.5%) in the ORF3 gene. To elucidate the pathogenicity, 7-day-old piglets were infected. Piglets infected with these two PEDV strains exhibited severe clinical signs and shed the virus at the highest level within 96 hpi. Compared with the piglets inoculated with the 17GXCZ-1ORF3c strain, the piglets inoculated with the 17GXCZ-1ORF3d strain had higher mortality rates (75% vs. 50%), an earlier onset of clinical signs with a significantly higher diarrhea score, lower VH:CD ratios and a higher percentage of PEDV-positive enterocytes. This study is the first to report PEDV coinfections with different ORF3 genotypes, and a PEDV strain with a large deletion in the ORF3 gene might have the advantage of a potential genetic marker, which would be useful during vaccine development