Synthetic Antioxidants as Contaminants of Emerging Concern in Indoor Environments: Knowns and Unknowns

Synthetic antioxidants, including synthetic phenolic antioxidants (SPAs), amine antioxidants (AAs), and organophosphite antioxidants (OPAs), are essential additives for preventing oxidative aging in various industrial and consumer products. Increasing attention has been paid to the environmental contamination caused by these chemicals, but our understanding of synthetic antioxidants is generally limited compared to other emerging contaminants such as plasticizers and flame retardants. Many people spend a significant portion (normally greater than 80%) of their time indoors, meaning that they experience widespread and persistent exposure to indoor contaminants. Thus, this Perspective focuses on the problem of synthetic antioxidants as indoor environmental contaminants. The wide application of antioxidants in commercial products and their demonstrated toxicity make them an important family of indoor contaminants of emerging concern. However, significant knowledge gaps still need to be bridged: novel synthetic antioxidants and their related transformation products need to be identified in indoor environments, different dust sampling strategies should be employed to evaluate human exposure to these contaminants, geographic scope and sampling scope of research on indoor contamination should be broadened, and the partition coefficients of synthetic antioxidants among different media need to be investigated

Design and Fabrication of an All-Solid-State Polymer Supercapacitor with Highly Mechanical Flexibility Based on Polypyrrole Hydrogel

A conducting polymer-based hydrogel (PPy/CPH) with a polypyrrole–poly­(vinyl alcohol) interpenetrating network was prepared by utilization of a chemical cross-linked poly­(vinyl alcohol)–H₂SO₄ hydrogel (CPH) film as flexible substrate followed by vapor-phase polymerization of pyrrole. Then an all-solid-state polymer supercapacitor (ASSPS) was fabricated by sandwiching the CPH film between two pieces of the PPy/CPH film. The ASSPS is mechanically robust and flexible with a tensile strength of 20.83 MPa and a break elongation of 377% which is superior to other flexible conducting polymer hydrogel-based supercapacitors owing to the strong hydrogen bonding interactions among the layers and the high mechanical properties of the PPy/CPH. It exhibits maximum volumetric specific capacitance of 13.06 F/cm³ and energy density of 1160.9 μWh/cm³. The specific capacitance maintains 97.9% and 86.3% of its initial value after 10 000 folding cycles and 10 000 charge–discharge cycles, respectively. The remarkable electrochemical and mechanical performance indicates this novel ASSPS device is promising for flexible electronics

Enhanced Light Scattering of Secondary Organic Aerosols by Multiphase Reactions

Secondary organic aerosol (SOA) plays a pivotal role in visibility and radiative forcing, both of which are intrinsically linked to the refractive index (RI). While previous studies have focused on the RI of SOA from traditional formation processes, the effect of multiphase reactions on the RI has not been considered. Here, we investigate the effects of multiphase processes on the RI and light-extinction of <i>m</i>-xylene-derived SOA, a common type of anthropogenic SOA. We find that multiphase reactions in the presence of liquid water lead to the formation of oligomers from intermediate products such as glyoxal and methylglyoxal, resulting in a large enhancement in the RI and light-scattering of this SOA. These reactions will result in increases in light-scattering efficiency and direct radiative forcing of approximately 20%–90%. These findings improve our understanding of SOA optical properties and have significant implications for evaluating the impacts of SOA on the rapid formation of regional haze, global radiative balance, and climate change