The Alloying Strategy to Tailor the Mechanical Properties of θ-Al₁₃Fe₄ Phase in Al-Mg-Fe Alloy by First-Principles Calculations

As an important strengthening phase in Al-Mg-Fe alloy, the elastic and ductile–brittle characteristics of Al13Fe4 intermetallics hold prime significance in ascertaining the mechanical properties and potential application of Al-Mg-Fe alloys. In this study, multialloying of Co, Cu, Cr, Mn, and Ni has been adopted for tuning the mechanical characteristics of the Al13Fe4 phase; their effects on mechanical features and electronic structure of the Al13Fe4 phase have been scrutinized systematically by first-principles calculations employing the density functional theory. The replacement of Fe with M (M = Co, Cu, Cr, Mn, and Ni) is energetically advantageous at 0 K, as evidenced by the negative cohesive energy and mixing enthalpy of all Al13(Fe,M)4 phases. Cu and Ni, on the contrary, have a detrimental impact on Al13Fe4′s modulus and hardness due to the evolution of chemical bonding strength. Co, Cr, and Mn are thus, interesting candidate elements. In the light of B/G and Poisson’s ratio (σ) criteria, Al13Fe4, Al13(Fe,Cu)4, and Al13(Fe,Ni)4 have superior ductility; however, Al13(Fe,Co), Al13(Fe,Mn), and Al13(Fe,Cr)4 tend to be brittle materials. Calculation-based findings show that Co, Cr, and Mn are appropriate alloying elements for enhancing fracture toughness, whereas Mn reduces Al13Fe4′s elastic anisotropy. The electronic structure assessment found that the mechanical properties of the intermetallics are predominantly influenced by the Al-M bonds when the alloying element M replaced Fe

The Alloying Strategy to Tailor the Mechanical Properties of θ-Al13Fe4 Phase in Al-Mg-Fe Alloy by First-Principles Calculations

As an important strengthening phase in Al-Mg-Fe alloy, the elastic and ductile–brittle characteristics of Al13Fe4 intermetallics hold prime significance in ascertaining the mechanical properties and potential application of Al-Mg-Fe alloys. In this study, multialloying of Co, Cu, Cr, Mn, and Ni has been adopted for tuning the mechanical characteristics of the Al13Fe4 phase; their effects on mechanical features and electronic structure of the Al13Fe4 phase have been scrutinized systematically by first-principles calculations employing the density functional theory. The replacement of Fe with M (M = Co, Cu, Cr, Mn, and Ni) is energetically advantageous at 0 K, as evidenced by the negative cohesive energy and mixing enthalpy of all Al13(Fe,M)4 phases. Cu and Ni, on the contrary, have a detrimental impact on Al13Fe4′s modulus and hardness due to the evolution of chemical bonding strength. Co, Cr, and Mn are thus, interesting candidate elements. In the light of B/G and Poisson’s ratio (σ) criteria, Al13Fe4, Al13(Fe,Cu)4, and Al13(Fe,Ni)4 have superior ductility; however, Al13(Fe,Co), Al13(Fe,Mn), and Al13(Fe,Cr)4 tend to be brittle materials. Calculation-based findings show that Co, Cr, and Mn are appropriate alloying elements for enhancing fracture toughness, whereas Mn reduces Al13Fe4′s elastic anisotropy. The electronic structure assessment found that the mechanical properties of the intermetallics are predominantly influenced by the Al-M bonds when the alloying element M replaced Fe

Suitability Evaluation for Land Reclamation of Nonmetallic Mines in Xinjiang, China

The ecological environment is fragile in Xinjiang, so it is necessary to carry out land reclamation for mines to restore its ecology. The premise of mines land reclamation is to determine the direction of land reclamation, which requires the suitability evaluation for land reclamation. In this paper, the evaluation index system and suitability evaluation model for land reclamation of nonmetallic mines in Xinjiang Uygur Autonomous Region were established. This model was established by using factor analysis, cluster analysis, and discriminant analysis and tested by back-substitution. First, using 149 units of 21 nonmetallic mines as research samples, the samples were divided into 4 categories by a combination of factor and cluster analysis. Then, the samples were trained using a discriminant analysis method to establish the corresponding land reclamation suitability evaluation model. This model was verified by back-substitution with an accuracy of 98.7%, and only 2 of 149 samples were misclassified. Finally, the evaluation model was applied to the Dabancheng Toga Solo limestone mine in Urumqi. Evaluation analysis of 15 land reclamation units of this mine showed satisfactory results. The evaluation model developed here could serve as a powerful complement to the evaluation of land reclamation suitability in Xinjiang

Water Distribution in Reconstructed Soil of Nonmetal Mines and the Ecological Effect in Xinjiang, China

Because of the arid climate and fragile ecological environment in Xinjiang, China, land reclamation should be carried out after mining. The core of land reclamation is the water content of the surface covering soil. In this paper, the law of water distribution in reclamation reconstructed soil of nonmetal mines in Xinjiang was studied. In order to obtain the law of water distribution in reconstructed soil, we set up an observation system of the neutron probe and tensiometer. The neutron probe was used to monitor the soil water content. The tensiometers were used to obtain the matrix potential of soil for verifying the water distribution in reconstructed soil. Volumetric water content and matrix potential of reconstructed soil during 1-year period of management and irrigation were obtained by long-term monitoring. After one year’s field in situ test, 2424 sets of neutron probe data and 1368 sets of tensiometer data were obtained. By studying the above parameters, we summarized the law of water distribution in reconstructed soil of variable thickness and degree of compaction with nonmetallic waste rock filling. The results showed that covering soil was helpful to retain water content. Whether the soil was compacted or uncompacted, the soil water content at the depth of 10 cm was less than that at other depth of reconstructed soil because it was greatly affected by meteorological factors. The water content of reconstructed soil at 30 cm depth was greater than that at other depths. Under the influence of factors such as the thickness and compaction of the soil, the response time of soil water content and matrix potential to each irrigation infiltration was different. According to the characteristics of reclamation-vegetation such as alfalfa growth in Xinjiang, the thickness of surface reconstructed soil should be not less than 50 cm. Over time, soil that was compacted once was better for the vegetation. The research results could provide a reference for the land reclamation of nonmetallic mines in Xinjiang, China

Study on Compaction Effect and Process of Reclaimed Soil of Nonmetallic Mines in Xinjiang, China

Reclaimed soil is the key substrate for land reclamation and ecological restoration in the mine areas. The change of the density of reclaimed soil of the nonmetallic mines in Xinjiang during the land reclamation process was studied in this paper. Firstly, the in situ test method of static load was used to simulate the compaction of reclaimed soil with different thickness of overlying soil by different compaction times of mines reclamation machinery, and field in situ test compaction data were obtained. Then, the numerical simulation method was used to simulate the variation process of displacement and porosity at different depths for different thickness of the reclaimed soil under different compaction conditions. The numerical simulation and the in situ test results verified each other to acquire the compaction process and results of reclaimed soil under different compaction. The results showed that the numerical simulation results were consistent with the in situ test. The reclaimed soil thickness and compaction times were crucial factors affecting the compaction effect of the soil. The difference between the three times compaction and the uncompacted soil was obvious, and the effect of single compaction was weakened with the increase of compaction times. Under the same compaction action, the thicker the soil was, the less obvious the compaction effect would be. In the process of reclamation, the compaction effect of the surface part (at the depth of 10 cm) was visible, and the amount of compression and springback was larger. The research results can provide a reference to the land reclamation of nonmetallic mines in Xinjiang, China

Investigation of Changes to Triaxial Shear Strength Parameters and Microstructure of Yili Loess with Drying–Wetting Cycles

This research examined the drying–wetting cycles induced changes in undrained triaxial shear strength parameters and microstructural changes of Yili loess. The drying–wetting cycles were selected as 0, 1, 3, 5, 10, 20 and 30. Then, we collected Yili loess samples and performed unconsolidated-undrained (U-U) triaxial shearing tests to ascertain the variation in shear strength parameters with drying–wetting cycles. Additionally, we investigated the microstructural changes of Yili loess samples under drying–wetting cycles simultaneously via nuclear magnetic resonance (NMR) and scanning electron electroscopy (SEM). Finally, we established a grey correlation model between shear strength and microstructural parameters. Under U-U conditions, the prime finding was that the loess’s shear strength parameters changed overall after drying–wetting cycles; in particular, the internal friction angle φ dropped significantly while the cohesion c changed only slightly during cycles. For all the cycles, the first cycle gave the highest change. Soil morphology deterioration was evident at the initial stage of cycles. During the entire drying–wetting cyclic process, pore size distribution showed progressive variance from two-peak to a single-peak pattern, while both porosity and the fractal dimension of pores increased gradually towards stability. Soil particle morphology became slowly simple and reached the equilibrium state after 20 drying–wetting cycles. Under cyclic drying–wetting stress, the shear strength parameter changes were significantly correlated to microstructural modifications. This investigation was related to loess in the westerly region. The findings were expected to provide new insight into establishment of the connection between microstructure and macro stress–strain state of loess. To some extent, it provided a theoretical basis for the prevention and control of loess engineering geological disasters in Yili, Xinjiang and other areas with similar climate and soil types

Prevalence and Risk Factors of Metabolic-Associated Fatty Liver Disease among 73,566 Individuals in Beijing, China

The prevalence of metabolic-associated fatty liver disease (MAFLD) is rarely reported in Beijing. The goal of this study was to estimate the prevalence and risk factors of MAFLD among Beijing adults aged ≥25 years old. A cross-sectional, community-based survey with multistage stratified cluster sampling was used. Demographic, transient elastography (TE), biochemical and blood examination information was collected in all the subjects in this study. The prevalence of MAFLD was 32.40% (23,832/73,566). Risk factors independently associated with MAFLD included male gender (OR = 1.47, 95%CI, 1.43–1.52), urban residence (OR = 1.06, 95% CI, 1.02–1.10), older age (30–39 years: OR = 1.29; 40–49 years: OR = 1.43; 50–59 years: OR = 1.09; ≥60 years: OR = 1.52) and lower education (middle school: OR = 2.03; high school: OR = 1.89; undergraduate: OR = 1.69). MAFLD was more common in females than in males after 50 years of age. Lean/normal weight MAFLD patients account for approximately 3.04% (724/23,832) of MAFLD. Compared to non-MAFLD subjects, the lean/normal MAFLD patients had a higher prevalence of hypertension and diabetes, and had a higher degree of hepatic steatosis and liver function enzymology parameters (all p < 0.001). MAFLD was highly prevalent among the general population aged ≥25 years old in Beijing. MAFLD was closely associated with male gender, older age, lower education and urban residence. Even lean/normal-weight people were under risk of MAFLD

The Trend of Permeability of Loess in Yili, China, under Freeze–Thaw Cycles and Its Microscopic Mechanism

Loess landslides induced by the freeze–thaw effect frequently occur in Yili, China. Freeze–thaw cycles cause indelible changes in the soil microstructure, affecting its permeability. This study investigated the impacts of freeze–thaw cycles on the permeability of Yili loess using permeability tests on undisturbed (virgin, in situ) and remolded loess samples taken before and after freeze–thaw cycles. Scanning electron microscopy and nuclear magnetic resonance techniques were utilized to investigate the microscopic mechanism of the freeze–thaw process on the loess. Grey relation analysis (GRA) was employed to analyze the correlation between macroscopic permeability and microscopic parameters (maxi. radius, eccentricity, fractal dimension, directional probability entropy, and porosity). The results revealed that the permeability and all the microstructure parameters have roughly shown the same trend: “fluctuation–towards equilibrium–stability”. Firstly, the permeability coefficients of original and remolded loess experienced three and two peaked–trends, respectively, before 30 freeze–thaw cycles. The trends eventually stabilized within 30–60 freeze–thaw cycles. Increased number of freeze–thaw cycles disintegrated large particles in undisturbed loess into medium–sized particles, and particle shapes became more uncomplicated. Medium–sized particles in the remolded loess agglomerated to larger particles with more complex shapes. Furthermore, the overall porosity of the originally undisturbed loess decreased, and large and medium–sized pores transformed into small pores and micropores. In contrast, the overall porosity of remolded loess increased. Finally, the results revealed that permeability coefficients of the undisturbed and remolded loess became closely related with eccentricity and porosity, respectively. This study provides a reference for preventing and governing the loess landslides induced by the freeze–thaw cycles and permeability reduction in construction on loess in seasonally frozen areas in Yili