Relative Entropy: Free Energy Associated with Equilibrium Fluctuations and Nonequilibrium Deviations

Using a one-dimensional macromolecule in aqueous solution as an illustration, we demonstrate that the relative entropy from information theory, $\sum_k p_k\ln(p_k/p_k^*)$, has a natural role in the energetics of equilibrium and nonequilibrium conformational fluctuations of the single molecule. It is identified as the free energy difference associated with a fluctuating density in equilibrium, and is associated with the distribution deviate from the equilibrium in nonequilibrium relaxation. This result can be generalized to any other isothermal macromolecular systems using the mathematical theories of large deviations and Markov processes, and at the same time provides the well-known mathematical results with an interesting physical interpretations.Comment: 5 page

Comment on "Pulsar Velocities and Neutrino Oscillations"

In a recent Letter, Kusenko and Segre proposed a new mechanism to explain the observed proper motions of pulsars. Their mechanism was based on the asymmetric neutrino emission induced by neutrino oscillations in the protoneutron star magnetic field. In this note I point out that their estimate of the asymmetry in the neutrino emission is incorrect. A proper calculation shows that their mechanism at least requires a magnetic field of 10**16 G in order to produce the observed average pulsar velocity.Comment: 4 pages, RevTe

Optical Control of Topological Quantum Transport in Semiconductors

Intense coherent laser radiation red-detuned from absorption edge can reactively activate sizable Hall type charge and spin transport in n-doped paramagnetic semiconductors as a consequence of k-space Berry curvature transferred from valence band to photon-dressed conduction band. In the presence of disorder, the optically induced Hall conductance can change sign with laser intensity.Comment: to appear in Phys. Rev. Let

Calorimetric Evidence of Strong-Coupling Multiband Superconductivity in Fe(Te0.57Se0.43) Single Crystal

We have investigated the specific heat of optimally-doped iron chalcogenide superconductor Fe(Te0.57Se0.43) with a high-quality single crystal sample. The electronic specific heat Ce of this sample has been successfully separated from the phonon contribution using the specific heat of a non-superconducting sample (Fe0.90Cu0.10)(Te0.57Se0.43) as a reference. The normal state Sommerfeld coefficient gamma_n of the superconducting sample is found to be ~ 26.6 mJ/mol K^2, indicating intermediate electronic correlation. The temperature dependence of Ce in the superconducting state can be best fitted using a double-gap model with 2Delta_s(0)/kBTc = 3.92 and 2Delta_l(0)/kBTc = 5.84. The large gap magnitudes derived from fitting, as well as the large specific heat jump of Delta_Ce(Tc)/gamma_n*Tc ~ 2.11, indicate strong-coupling superconductivity. Furthermore, the magnetic field dependence of specific heat shows strong evidence for multiband superconductivity