45 research outputs found
Anomalous thermal expansion and strong damping of the thermal conductivity of NdMnO and TbMnO due to 4f crystal-field excitations
We present measurements of the thermal conductivity and the thermal
expansion of NdMnO and TbMnO. In both compounds a splitting of
the multiplet of the ion causes Schottky contributions to
. In TbMnO this contribution arises from a crystal-field splitting,
while in NdMnO it is due to the Nd-Mn exchange coupling. Another
consequence of this coupling is a strongly enhanced canting of the Mn moments.
The thermal conductivity is greatly suppressed in both compounds. The main
scattering process at low temperatures is resonant scattering of phonons
between different energy levels of the multiplets, whereas the complex 3d
magnetism of the Mn ions is of minor importance.Comment: 9 pages including 6 figure
A novel heavy-fermion state in CaCu_3Ru_4O12
We have measured susceptibility, specific heat, resistivity, and thermopower
of CaCuTiRuO and CaCuMnRuO, and
have found that CaCuRuO can be regarded as a heavy-fermion oxide
in d-electron systems. The Kondo temperature is near 200 K, and the
susceptibility (1.4 emu/Cu mol) and the electron specific heat
coefficient (28 mJ/Cu molK) are moderately enhanced. The resistivity is
proportional to at low temperatures, and satisfies the Kadowaki-Woods
relation. The heavy-fermion state comes from the interaction between the
localized moment of Cu 3d and the conduction electron of Ru 4d. An
insulator-metal transition occurs between and 4 in
CaCuTiRuO, which can be regarded as a transition from
magnetic insulator to heavy-fermion metal.Comment: 4 pages, 5 figures, submitted to J. Phys. Soc. Jp