3,390 research outputs found
Strontium as a tracer of weathering processes in a silicate catchment polluted by acid atmospheric inputs, Strengbach, France
This paper determines the weathering and atmospheric contributions of Ca in surface water from a small spruce forested silicate catchment (NâE France) receiving acid atmospheric inputs. The bedrock is a granite with K-feldspar and albite as dominant phases. The calcium content in plagioclase is low and the Ca/Na ratio in surface water is high, reflecting other sources of calcium from those expected from the weathering of major mineral phases. The biotite content is low. Only traces of apatite were detected while no calcite was found in spite of a major hydrothermal event having affected the granite. The strontium isotopic ratio 87Sr/86Sr and Sr content was used as a tracer of weathering and was determined in minerals and bulk bedrock, open field precipitation, throughfall, soil solution, spring and stream water. The Sr isotopic ratio of the reacting weathering end-member was predicted by simulating the alteration of the granite minerals by incorporating strontium into the waterârock interaction kinetic code KINDIS. In the early stages of waterârock interaction, K-feldspar and biotite strongly influence the isotopic composition of the weathering solution whereas, the Na-rich plagioclase appears to be the main long-term reactive weathering end-member. Approximately 50% of dissolved Sr in streamwater are atmospherically derived. The 87Sr/86Sr ratios of exchangeable Sr in the fine fraction at 1-m depth from a soil profile indicate that the amount of exchangeable Sr seems essentially controlled by atmospheric inputs. The exception is the deep saprolite where weathering processes could supply the Sr (and Ca). Na-Plagioclase weathering obviously control the chemistry and the isotopic composition of surface waters. The weathering of trace mineral plays a secondary role, the exception is for apatite when plagioclase is absent. Our hydrochemical, mineralogical and isotopic investigations show that a major part of the strong Ca losses detected in catchment hydrochemical budgets that result from the neutralization of acid precipitation has an atmospheric origin. Consequently, in the long term, in such areas, the availability of such an exchangeable base cation might be strongly limited and surface waters consequently acidified
Harvesting Entities from the Web Using Unique Identifiers -- IBEX
In this paper we study the prevalence of unique entity identifiers on the
Web. These are, e.g., ISBNs (for books), GTINs (for commercial products), DOIs
(for documents), email addresses, and others. We show how these identifiers can
be harvested systematically from Web pages, and how they can be associated with
human-readable names for the entities at large scale.
Starting with a simple extraction of identifiers and names from Web pages, we
show how we can use the properties of unique identifiers to filter out noise
and clean up the extraction result on the entire corpus. The end result is a
database of millions of uniquely identified entities of different types, with
an accuracy of 73--96% and a very high coverage compared to existing knowledge
bases. We use this database to compute novel statistics on the presence of
products, people, and other entities on the Web.Comment: 30 pages, 5 figures, 9 tables. Complete technical report for A.
Talaika, J. A. Biega, A. Amarilli, and F. M. Suchanek. IBEX: Harvesting
Entities from the Web Using Unique Identifiers. WebDB workshop, 201
Comb-calibrated solar spectroscopy through a multiplexed single-mode fiber channel
We investigate a new scheme for astronomical spectrograph calibration using
the laser frequency comb at the Solar Vacuum Tower Telescope on Tenerife. Our
concept is based upon a single-mode fiber channel, that simultaneously feeds
the spectrograph with comb light and sunlight. This yields nearly perfect
spatial mode matching between the two sources. In combination with the absolute
calibration provided by the frequency comb, this method enables extremely
robust and accurate spectroscopic measurements. The performance of this scheme
is compared to a sequence of alternating comb and sunlight, and to absorption
lines from Earth's atmosphere. We also show how the method can be used for
radial-velocity detection by measuring the well-explored 5-minute oscillations
averaged over the full solar disk. Our method is currently restricted to solar
spectroscopy, but with further evolving fiber-injection techniques it could
become an option even for faint astronomical targets.Comment: 21 pages, 11 figures. A video abstract for this paper is available on
youtube. For watching the video, please follow
https://www.youtube.com/watch?v=oshdZgrt89I . The video abstract is also
available for streaming and download on the related article website of New
Journal of Physic
Protease inhibitors prevent plasminogen-mediated, but not pemphigus vulgaris-induced, acantholysis in human epidermis
Pemphigus is an autoimmune blistering disease of the skin and mucous membranes. It is caused by autoantibodies directed against desmosomes, which are the principal adhesion structures between epidermal keratinocytes. Binding of autoantibodies leads to the destruction of desmosomes resulting in the loss of cell-cell adhesion (acantholysis) and epidermal blisters. The plasminogen activator system has been implicated as a proteolytic effector in pemphigus. We have tested inhibitors of the plasminogen activator system with regard to their potential to prevent pemphigus-induced cutaneous pathology. In a human split skin culture system, IgG preparations of sera from pemphigus vulgaris patients caused histopathologic changes (acantholysis) similar to those observed in the original pemphigus disease. All inhibitors that were tested (active site inhibitors directed against uPA, tPA, and/or plasmin; antibodies neutralizing the enzymatic activity of uPA or tPA; substances interfering with the binding of uPA to its specific cell surface receptor uPAR) failed to prevent pemphigus vulgaris IgG-mediated acantholysis. Plasminogen-mediated acantholysis, however, was effectively antagonized by the synthetic active site serine protease inhibitor WX-UK1 or by p-aminomethylbenzoic acid. Our data argue against applying anti-plasminogen activator/anti-plasmin strategies in the management of pemphigus
Metastable anions of dinitrobenzene: resonances for electron attachment and kinetic energy release
Attachment of free, low-energy electrons to dinitrobenzene (DNB) in the gas phase leads to DNB as well as several fragment anions. DNB, (DNB-H), (DNB-NO), (DNB-2NO), and (DNB-NO(2)) are found to undergo metastable (unimolecular) dissociation. A rich pattern of resonances in the yield of these metastable reactions versus electron energy is observed; some resonances are highly isomer-specific. Most metastable reactions are accompanied by large average kinetic energy releases (KER) that range from 0.5 to 1.32 eV, typical of complex rearrangement reactions, but (1,3-DNB-H)(-) features a resonance with a KER of only 0.06 eV for loss of NO. (1,3-DNB-NO)(-) offers a rare example of a sequential metastable reaction, namely, loss of NO followed by loss of CO to yield C(5)H(4)O(-) with a large KER of 1.32 eV. The G4(MP2) method is applied to compute adiabatic electron affinities and reaction energies for several of the observed metastable channels. (C) 2010 American Institute of Physics. [doi:10.1063/1.3514931
Transferability of vegetation recovery models based on remote sensing across different fire regimes
P. 441-451Aim
To evaluate the transferability between fire recurrence scenarios of postâfire vegetation cover models calibrated with satellite imagery data at different spatial resolutions within two Mediterranean pine forest sites affected by large wildfires in 2012.
Location
The northwest and east of the Iberian Peninsula.
Methods
In each study site, we defined three fire recurrence scenarios for a reference period of 35 years. We used image texture derived from the surface reflectance channels of WorldViewâ2 and Sentinelâ2 (at a spatial resolution of 2 m Ă 2 m and 20 m Ă 20 m, respectively) as predictors of postâfire vegetation cover in Random Forest regression analysies. Percentage vegetation cover was sampled in two sets of field plots with a size roughly equivalent to the spatial resolution of the imagery. The plots were distributed following a stratified design according to fire recurrence scenarios. Model transferability was assessed within each study site by applying the vegetation cover model developed for a given fire recurrence scenario to predict vegetation cover in other scenarios, iteratively.
Results
For both wildfires, the highest model transferability between fire recurrence scenarios was achieved for those holding the most similar vegetation community composition regarding the balance of species abundance according to their plantâregenerative traits (root mean square error [RMSE] around or lower than 15%). Model transferability performance was highly improved by fineâgrained remoteâsensing data.
Conclusions
Fire recurrence is a major driver of community structure and composition so the framework proposed in this study would allow land managers to reduce efforts in the context of postâfire decisionâmaking to assess vegetation recovery within large burned landscapes with fire regime variability.S
Materials for engine applications above 3000 deg F: An overview
Materials for future generations of aeropropulsion systems will be required to perform at ever-increasing temperatures and have properties superior to the current state of the art. Improved engine efficiency can reduce specific fuel consumption and thus increase range and reduce operating costs. The ultimate payoff gain is expected to come when materials are developed which can perform without cooling at gas temperatures to 2200 C (4000 F). An overview is presented of materials for applications above 1650 C (3000 F), some pertinent physical property data, and the rationale used: (1) to arrive at recommendations of material systems that qualify for further investigation, and (2) to develop a proposed plan of research. From an analysis of available thermochemical data it was included that such materials systems must be composed of oxide ceramics. The required structural integrity will be achieved by developing these materials into fiber-reinforced ceramic composites
A Frequency Comb calibrated Solar Atlas
The solar spectrum is a primary reference for the study of physical processes
in stars and their variation during activity cycles. In Nov 2010 an experiment
with a prototype of a Laser Frequency Comb (LFC) calibration system was
performed with the HARPS spectrograph of the 3.6m ESO telescope at La Silla
during which high signal-to-noise spectra of the Moon were obtained. We exploit
those Echelle spectra to study the optical integrated solar spectrum . The
DAOSPEC program is used to measure solar line positions through gaussian
fitting in an automatic way. We first apply the LFC solar spectrum to
characterize the CCDs of the HARPS spectrograph. The comparison of the LFC and
Th-Ar calibrated spectra reveals S-type distortions on each order along the
whole spectral range with an amplitude of +/-40 m/s. This confirms the pattern
found by Wilken et al. (2010) on a single order and extends the detection of
the distortions to the whole analyzed region revealing that the precise shape
varies with wavelength. A new data reduction is implemented to deal with CCD
pixel inequalities to obtain a wavelength corrected solar spectrum. By using
this spectrum we provide a new LFC calibrated solar atlas with 400 line
positions in the range of 476-530, and 175 lines in the 534-585 nm range. The
new LFC atlas improves the accuracy of individual lines by a significant factor
reaching a mean value of about 10 m/s. The LFC--based solar line wavelengths
are essentially free of major instrumental effects and provide a reference for
absolute solar line positions. We suggest that future LFC observations could be
used to trace small radial velocity changes of the whole solar photospheric
spectrum in connection with the solar cycle and for direct comparison with the
predicted line positions of 3D radiative hydrodynamical models of the solar
photosphere.Comment: Accept on the 15th of October 2013. 9 pages, 10 figures. ON-lINE data
A&A 201
Intrinsic charge transport on the surface of organic semiconductors
The novel technique based on air-gap transistor stamps enabled realization of
the intrinsic (not dominated by static disorder) transport of the
electric-field-induced charge carriers on the surface of rubrene crystals over
a wide temperature range. The signatures of the intrinsic transport are the
anisotropy of the carrier mobility, mu, and the growth of mu with cooling. The
anisotropy of mu vanishes in the activation regime at lower temperatures, where
the charge transport becomes dominated by shallow traps. The deep traps,
deliberately introduced into the crystal by X-ray radiation, increase the
field-effect threshold without affecting the mobility. These traps filled above
the field-effect threshold do not scatter the mobile polaronic carriers.Comment: 10 pages, 4 figure
PHL 5038: a spatially resolved white dwarf + brown dwarf binary
A near-infrared excess is detected at the white dwarf PHLâ5038 in UKIDSS photometry, consistent with the presence of a cool, substellar companion. We have obtained H- and K-grism spectra and images of PHLâ5038 using NIRI on Gemini North. The target is spatially and spectrally resolved into two components: an 8000 K DA white dwarf, and a likely L8 brown dwarf companion, separated by 0.94\arcsec. The spectral type of the secondary was determined using standard spectral indices for late L and T dwarfs. The projected orbital separation of the binary is 55 AU, so it becomes only the second known wide WD+dL binary to be found after GDâ165AB. This object could potentially be used as a benchmark for testing substellar evolutionary models at intermediate to older ages
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