41 research outputs found

    On the mechanism of the oxidation of cyclohexanone

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    Luminescence of Dimeric T1(I) Complexes: Metal-Metal Interaction in the Electronically Excited State

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    Dimeric diethyldithiocarbamatethallium(I) [Et 2NCS2Tl]2 shows a red emission at λmax=608 nm which undergoes a huge Stokes shift with regard to the excitation maximum at λ=246 nm. It is suggested that the emission originates from a sp excited state which is characterized by strong metal-metal bonding
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