Spin reorientation behavior in YMn1-xMxO3 (M = Ti, Fe, Ga; x = 0, 0.1)

The structural and magnetic properties of polycrystalline YMn1-xMxO3 (M = Ti, Fe, Ga; x = 0, 0.1) have been studied by neutron powder diffraction and magnetic measurements to probe the effect of Mn site doping on the frustration behavior and magnetic structure of these compounds. The compounds are isostructural and crystallize with hexagonal structure in P63cm space group. We find that doping with these three ions, Ti4+ (d0), Fe3+ (d5) and Ga3+ (d10), influences both the TN and magnetic structure, unlike other Mn-site dopants reported previously. The magnetic structure of YMnO3 is described by considering a linear combination of irreducible representations {\Gamma}3 and {\Gamma}4 below TN ~ 75K and with decrease in temperature the ratio of {\Gamma}3 and {\Gamma}4 changes. The mixing ratio of these two irreducible representations remains constant on lowering of temperature in the Ga doped compounds. The magnetic structure is modified on doping with nonmagnetic ion Ti4+ (d0). It is described by the basis vectors of the irreducible representation {\Gamma}2 with moment 2.3{\mu}B at 6 K. On doping with Fe3+ (d5) the magnetic structure immediately below TN is explained by considering the {\Gamma}3 irreducible representation. On further lowering of temperature, a spin reorientation at ~ 35 K is observed. Below this temperature, the magnetic structure of YMn0.9Fe0.1O3 is explained by considering {\Gamma}3 representation with 51% mixing of {\Gamma}4. The ordered moments are found to be reduced from the expected value for a Mn3+ ion in all these compounds indicating the frustrated nature of these compounds. However, the frustration parameter, f is significantly reduced in the case of Ti doped compound with {\Gamma}2 representation

Antiferromagnetic Coupling between Surface and Bulk Magnetization and Anomalous Magnetic Transport in Electro-deposited Co Film

We report an interesting magnetic behavior of a Co film (thickness ~ 350 {\AA}) grown on Si/Ti/Cu buffer layer by electro-deposition (ED) technique. Using depth sensitive X-ray reflectivity and polarized neutron reflectivity (PNR) we observed two layer structures for the Co film grown by ED with a surface layer (thickness ~ 100 {\AA}) of reduced density (~ 68% of bulk) compared to rest of the Co film (thickness ~ 250 {\AA}). The two layer structure is consistent with the histogram profile obtained from atomic force microscope (AFM) of the film. Interestingly, using PNR, we found that the magnetization in the surface Co layer is inversely (antiferomagnetically) coupled (negative magnetization for surface Co layer) with the rest of the Co layer for the ED grown film. While we compare PNR result for a Co film of similar layered structure grown by sputtering, the film showed a uniform magnetization as expected. We also show that the depth dependent unusual magnetic behavior of ED grown Co film may be responsible for anomalous anisotropic magnetoresistance observed in low field in this film as compared to the Co film grown by sputtering. Combining X-ray scattering, AFM, superconducting quantum interface device magnetometry (SQUID), PNR and magneto-transport measurements we attempted to correlate and compare the structural, magnetic and morphological properties with magneto-transport of Co films grown by ED and sputtering. The study indicates that the interesting surface magnetic property and magneto-transport property of the ED film is caused by its unique surface morphology

Magnetic and dielectric behavior in YMn1-xFexO3 (x less than or equal to 0.5)

The role of doping Fe on the structural, magnetic and dielectric properties of frustrated antiferromagnet YMn1-xFexO3 (x less than or equal to 0.5) has been investigated. The neutron diffraction analysis shows that the structure of these polycrystalline samples changes from hexagonal phase (space group P63cm) to orthorhombic phase (space group Pnma) for x > 0.2. The frustration parameter decreases with Fe substitution. All the compounds are antiferromagnetic and the magnetic structure is described as a mixture of {\Gamma}3 and {\Gamma}4 irreducible representation (IR) in the hexagonal phase and the ratio of these two IRs is found to vary with Fe doping (x less than or equal to 0.2). A continuous spin reorientation as a function of temperature is observed in these samples. The magnetic ground state in the orthorhombic phase of the higher doped samples (x greater than or equal to 0.3) is explained by taking {\Gamma}1 (GxCyAz) representation of Pnma setting. In YMnO3 suppression of dielectric constant {\epsilon} is observed below Tn indicative of magnetoelectric coupling. This anomalous behavior reduces in Fe doped samples. The dielectric constant is found to be correlated with the magnetic moment (M) obtained from neutron diffraction experiments and follows a M^2 behavior close to Tn in agreement with Landau theory.Comment: To appear in Journal of Apllied Physic

Superconductivity-driven magnetization modulation in YBa2Cu3O7-{\delta} /SrTiO3/La0.67Sr0.33MnO3 heterostructures

Using spin polarized neutron reflectivity experiments, we demonstrate an unusual proximity behaviour when the superconductor (SC) and the ferromagnet (FM) are coupled through an insulator (I) in YBa2Cu3O7-{\delta} (SC)/SrTiO3 (I)/La0.67Sr0.33MnO3 (FM) heterostructures. We have observed an unexpected magnetic modulation at the interface region of the FM below the superconducting transition temperature. The magnetization of the FM layer at the I/FM interface was drastically reduced as compared to the magnetization in the rest of the FM layer. This result indicates that the Cooper pairs tunnel across the insulator and interact with the local magnetization at the interface region (extending ~ 30 {\AA}) of the FM causing modification of the magnetization at the interface. This unexpected magnetic behavior cannot be explained on the basis of the existing theoretical models. However, the length scale associated here clearly suggests the long range proximity effect as a result of tunneling of Cooper pairs.Comment: 6 figure

Griffiths like Robust Ferromagnetism in Co3-xMnxTeO6; (x = 0.5, 1, 2)

We report near room temperature ferromagnetic as well as low temperature antiferromagnetic correlations in Mn doped Cobalt Tellurate (CMTO) solid solutions using thorough magnetization studies. For all the composition the solid solutions show not only short range robust FM order at 185 K but also show long range enhanced AFM order less than or equal to 45 K. Scaling of inverse magnetic susceptibility data provide clear indication of Griffiths like FM phase extended over large thermal region and its robustness against magnetic field. Variations in both the phases as a function of Mn concentration also support our observation of anomalous behavior in the average bond distances and charge states (JAP 116: 074904 (2014)). Further an attempt towards the structural insight into the observed complex magnetic behavior by using network like structural analysis has been drawn. These observations make this an interesting magnetic system from fundamental and application perspective

Annealing driven positive and negative exchange bias in Fe-Cu-Pt heterostructures at room temperature

We report annealing induced exchange bias in Fe-Cu-Pt based heterostructures with Cu as an intermediate layer (Fe/Cu/Pt heterostructure) and capping layer (Fe/Pt/Cu heterostructure). Exchange bias observed at room temperature (300 K) is found to be dependent on the annealing temperature. We obtained positive exchange bias of 120 Oe on annealing both the heterostructures at 400 oC, while on annealing these heterostructures at 500 and 600 oC a negative exchange bias of ~ -100 Oe was found. X-ray reflectivity and polarized neutron reflectivity measurements provided evolution of depth dependent structure and magnetic properties of the heterostructures on annealing at different temperatures and revealed coexistence of soft and hard (alloy) magnetic phases across the thickness of the films. Rapid and long range interdiffusion at interfaces on annealing the systems at a temperature above 400 oC resulted into formation of a ternary alloy phase. These results can be understood within the context of a very unusual interface exchange interaction at the interface of hard/soft magnetic phases, which are dependent on the annealing temperature.Comment: 10 figure

Phase separated behavior in Yttrium doped CaMnO3

The effect of electron doping on the structural, transport, and magnetic properties of Mn (IV) - rich Ca1-xYxMnO3 (x < 0.2) samples have been investigated using neutron diffraction, neutron depolarization, magnetization and resistivity techniques. The temperature dependence of resistivity follows the small polaron model and the activation energy exhibits a minimum for x=0.1 sample. A phase separated magnetic ground state consisting of ferromagnetic domains (~7microns) embedded in G-type antiferromagnetic matrix is observed in the sample, x = 0.1. The transition to the long range magnetically ordered state in this sample is preceded by a Griffiths phase. On lowering temperature below 300K a structural transition from orthorhombic structure (Pnma) to a monoclinic structure (P21/m) is observed in the case of x=0.2 sample. The ferromagnetic behavior in this case is suppressed and the antiferromagnetic ordering is described by coexisting C-type and G-type magnetic structures corresponding to the monoclinic and orthorhombic phases, respectively.

A spin ladder compound doubles its superconducting TC under a gentle uniaxial pressure

Discovery of new high TC superconductors, with TC > 23 K, continues to be challenging. We have doubled the existing TC of single crystal Sr3Ca11Cu24O41, a spin ladder cuprate, from 12K to 24K, using a gentle uniaxial pressure ~ 0.06 GPa. In contrast, earlier works used a nearly 100 times larger hydrostatic pressure 5 GPa, only to reach a maximum TC ~ 12K. Our work exposes large and nearly equal, but opposing contributions to changes in TC, arising from compressions along and perpendicular to ladder planes, in hydrostatic pressure experiments. In our resistivity measurements, uniaxial pressure applied along ladder planes increase TC, while that perpendicular to ladder planes decrease TC. Our findings i) offers a new hope for further increase in TC in spin ladder compounds and ii) calls for a large shift in phase boundaries of the currently accepted pressure-temperature phase diagram.Comment: 5 figures and 24 page

Antisymmetric magnetoresistance and helical magnetic structure in compensated Gd/Co multilayer

Using spin dependent specular and off-specular polarized neutron reflectivity (PNR), we report the observation of a twisted helical magnetic structure with planar 2{\pi} domain wall (DW) and highly correlated magnetic domains in a Gd/Co multilayer. Specular PNR with polarization analysis reveals the formation of planar 2{\pi}DWs below a compensation temperature (TComp), resulting to positive exchange bias in this system. Off-specular PNR with spin polarization showed development of magnetic inhomogenities (increase in magnetic roughness) for central part (thickness ~ 25-30 {\AA}) of each Gd layer, where magnetization is aligned perpendicular (in-plane) to an applied field. These magnetic roughness are vertically correlated and results into Bragg sheet in spin flip channel of Off-specular PNR data, which is contributing towards an antisymmetric magnetoresistance at TComp in the system. The growth and tunability of highly correlated magnetic inhomogeneities (roughness) and domain structure around TComp in combination of twisted helical magnetic structure with planar 2{\pi}DWs will be key for application in all-spin-based technology.Comment: 4 figure

Superconductivity-induced Magnetic Modulation in a Ferromagnet Through an Insulator in LaCaMnO3\SrTiO3\YBa2Cu3O7-{\delta} Hybrid Heterostructures

Coexistence of ferromagnetic and superconducting orders and their interplay in ferromagnet-superconductor heterostructures is a topic of intense research. While it is well known that proximity of a ferromagnet suppresses superconducting order in the superconductor, there exist few studies indicating the proximity of a superconductor suppressing ferromagnetic order in a ferromagnet. Here we demonstrate a rare observation of the suppression of ferromagnetic order in a LaCaMnO3 layer separated from a YBa2Cu3O7-{\delta} layer by a thin insulator (SrTiO3). Polarized neutron reflectivity measurements on LaCaMnO3\SrTiO3\YBa2Cu3O7-{\delta} trilayer deposited on [001] SrTiO3 single crystal substrates shows the emergence of a thin magnetic dead layer in LaCaMnO3 adjacent to the insulating layer below its superconducting transition temperature of YBa2Cu3O7-{\delta}. Further, the magnetic dead layer grows in thickness when the insulating layer is made thinner. This indicates a possible tunneling of the superconducting order-parameter through the insulating SrTiO3 inducing modulation of magnetization in LaCaMnO3.Comment: 29 page