Engineered photocatalysts for detoxification of waste water

This report describes progress on the development of engineered photocatalysts for the detoxification of water polluted with toxic organic compounds and heavy metals. We examined a range of different oxide supports (titania, alumina, magnesia and manganese dioxide) for tin uroporphyrin and investigated the efficacy of a few different porphyrins. A water-soluble octaacetic-acid-tetraphenylporphyrin and its derivatives have been synthesized and characterized in an attempt to design a porphyrin catalyst with a larger binding pocket. We have also investigated photocatalytic processes on both single crystal and powder forms of semiconducting SiC with an ultimate goal of developing a dual-semiconductor system combining TiO{sub 2} and SiC. Mathematical modeling was also performed to identify parameters that can improve the efficiency of SiC-based photocatalytic systems. Although the conceptual TiO{sub 2}/SiC photodiode shows some promises for photoreduction processes, SiC itself was found to be an inefficient photocatalyst when combined with TiO{sub 2}. Alternative semiconductors with bandgap and band potentials similar to SiC should be tested in the future for further development and a practical utilization of the dual photodiode concept

Engineered photocatalysts for detoxification of waste water

This report describes progress on the development of engineered photocatalysts for the detoxification of water polluted with toxic organic compounds and heavy metals. We examined a range of different oxide supports (titania, alumina, magnesia and manganese dioxide) for tin uroporphyrin and investigated the efficacy of a few different porphyrins. A water-soluble octaacetic-acid-tetraphenylporphyrin and its derivatives have been synthesized and characterized in an attempt to design a porphyrin catalyst with a larger binding pocket. We have also investigated photocatalytic processes on both single crystal and powder forms of semiconducting SiC with an ultimate goal of developing a dual-semiconductor system combining TiO{sub 2} and SiC. Mathematical modeling was also performed to identify parameters that can improve the efficiency of SiC-based photocatalytic systems. Although the conceptual TiO{sub 2}/SiC photodiode shows some promises for photoreduction processes, SiC itself was found to be an inefficient photocatalyst when combined with TiO{sub 2}. Alternative semiconductors with bandgap and band potentials similar to SiC should be tested in the future for further development and a practical utilization of the dual photodiode concept

Destruction of Trace Organics in Otherwise Ultra Pure Water

A number of experiments were conducted to determine the economic viability of applying various ultraviolet (UV) oxidation processes to a waste water stream containing approximately 12 mg/L total organic carbon (TOC), predominately ethylene glycol. In all experiments, a test solution was illuminated with either near-UV or a far-UV light alone or in combination with a variety of photocatalysts and oxidants. Based upon the outcomes of this project, both UV/photocatalysis and UV/ozone processes are capable of treating the water sample to below detection capabilities of TOC. However, the processes are fairly energy intensive; the most efficient case tested required 11 kWh per order of magnitude reduction in TOC per 1000 L. If energy consumption rates of 5-10 kWh/1000 L are deemed reasonable, then further investigation is recommended

Destruction of trace organics in otherwise ultra pure water

A number of experiments were conducted to determine the economic viability of applying various ultraviolet (UV) oxidation processes to a waste water stream containing approximately 12 mg/L total organic carbon (TOC), predominately ethylene glycol. In all experiments, a test solution was illuminated with either near-UV or a far-UV light alone or in combination with a variety of photocatalysts and oxidants. Based upon the outcomes of this project, both UV/photocatalysis and UV/ozone processes are capable of treating the water sample to below detection capabilities of TOC. However, the processes are fairly energy intensive; the most efficient case tested required 11 kWh per order of magnitude reduction in TOC per 1000 L. If energy consumption rates of 5-10 kWh/1000 L are deemed reasonable, then further investigation is recommended

Performance of the solar two central receiver power plant

Solar Two is a utility-led project to promote the commercialization of solar power towers by retrofitting the Solar One pilot plant from a water/steam-based system to a molten salt system. Solar Two is capable of producing 10 MWe net electricity with enough thermal storage capacity to operate the turbine for three hours after sunset. The plant was turned over to its operations and maintenance contractor in February 1998, marking transition from start-up to the test and evaluation phase. Solar Two has collected as much as 230 MWh thermal and generated as much as 72 MWhe gross electricity in one day. The plant has demonstrated dispatchability after dark, during clouds, and during sunshine hours. To date, Solar Two has collected thermal energy at a maximum rate of 39 MWt and generated gross electricity at a maximum rate of 11.1 MWe. Important lessons have been learned in the areas of heat trace, valve selection, materials of construction, and steam generator design. Testing has begun in a number of areas relating to receiver performance, storage tank performance, salt chemistry, overnight thermal conditioning, electricity dispatching, performance monitoring and evaluation, availability tracking, and receiver controls

Enhancement of solar photocatalytic detoxification by adsorption of porphyrins onto TiO sub 2

Titanium dioxide (TiO{sub 2}) is a photocatalyst for solar detoxification of water containing organic contaminants such as solvents, PCB's, dioxins, pesticides, and dyes. Unfortunately, the ultraviolet (UV) energy used by TiO{sub 2} ({lambda}<400 nm) only comprises about 4% of the solar spectrum. One way of enhancing the efficiency of solar detoxification technologies is to utilize a larger portion of the solar spectrum to initiate the Tio{sub 2}- catalyzed detoxification chemistry. Metalloporphyrins strongly absorb visible and near infrared radiation. By utilization of a process called photosensitization, adsorption of these dyes onto TiO{sub 2} can enable a much broader portion of the solar spectrum to be used. Photosensitization relies upon the ability of the dye molecule to absorb more of the solar energy than bare TiO{sub 2} and to interact electronically with the TiO{sub 2} surface in such a way as to initiate TiO{sub 2}-based redox photochemistry using the dye-absorbed energy. 16 refs., 7 figs