Treatment of hazardous waste landfill leachate using Fenton oxidation process

The efficiency of Fenton’s oxidation was assessed in this study for hazardous waste landfill leachate treatment. The two major reagents, which are generally employed in Fenton’s process are H2O2 as oxidizing agent and Fe2+ as catalyst. Batch experiments were conducted to determine the effect of experimental conditions viz., reaction time, molar ratio, and Fenton reagent dosages, which are significant parameters that influence the degradation efficiencies of Fenton process were examined. It was found that under the favorable experimental conditions, maximum COD removal was 56.49%. The optimum experimental conditions were pH=3, H2O2/Fe2+ molar ratio = 3 and reaction time = 150 minutes. The optimal amount of hydrogen peroxide and iron were 0.12 mol/L and 0.04 mol/L respectively. High dosages of H2O2 and iron resulted in scavenging effects on OH• radicals and lowered degradation efficiency of organic compounds in the hazardous waste landfill leachate

Mineralization of Hazardous Waste Landfill Leachate using Photo-Fenton Process

This study was conducted to evaluate the COD removal efficiency of Photo-Fenton oxidation process. The reagents used in the Photo-Fenton process are catalyst Fe2+ and H2O2 as oxidizing agent. A 16W UV lamp was used to carry out the experiments. All the experiments were performed in batch mode to investigate the influence of operating conditions viz., Fenton reagents dosage, molar ratio and reaction time. The maximum COD removal observed was 68% under optimum operating conditions. The operating conditions H2O2/Fe2+ molar ratio = 3 and reaction time = 90 minutes were found to optimum. The dosages of Fenton reagents i.e. hydrogen peroxide and Fe2+ were optimum at 0.09 mol/L and 0.03 mol/L respectively

Treatment of hazardous waste landfill leachate using Fenton oxidation process

The efficiency of Fenton’s oxidation was assessed in this study for hazardous waste landfill leachate treatment. The two major reagents, which are generally employed in Fenton’s process are H2O2 as oxidizing agent and Fe2+ as catalyst. Batch experiments were conducted to determine the effect of experimental conditions viz., reaction time, molar ratio, and Fenton reagent dosages, which are significant parameters that influence the degradation efficiencies of Fenton process were examined. It was found that under the favorable experimental conditions, maximum COD removal was 56.49%. The optimum experimental conditions were pH=3, H2O2/Fe2+ molar ratio = 3 and reaction time = 150 minutes. The optimal amount of hydrogen peroxide and iron were 0.12 mol/L and 0.04 mol/L respectively. High dosages of H2O2 and iron resulted in scavenging effects on OH• radicals and lowered degradation efficiency of organic compounds in the hazardous waste landfill leachate

Produced Water Treatment with Conventional Adsorbents and MOF as an Alternative: A Review

A large volume of produced water (PW) has been produced as a result of extensive industrialization and rising energy demands. PW comprises organic and inorganic pollutants, such as oil, heavy metals, aliphatic hydrocarbons, and radioactive materials. The increase in PW volume globally may result in irreversible environmental damage due to the pollutants’ complex nature. Several conventional treatment methods, including physical, chemical, and biological methods, are available for produced water treatment that can reduce the environmental damages. Studies have shown that adsorption is a useful technique for PW treatment and may be more effective than conventional techniques. However, the application of adsorption when treating PW is not well recorded. In the current review, the removal efficiencies of adsorbents in PW treatment are critically analyzed. An overview is provided on the merits and demerits of the adsorption techniques, focusing on overall water composition, regulatory discharge limits, and the hazardous effects of the pollutants. Moreover, this review highlights a potential alternative to conventional technologies, namely, porous adsorbent materials known as metal–organic frameworks (MOFs), demonstrating their significance and efficiency in removing contaminants. This study suggests ways to overcome the existing limitations of conventional adsorbents, which include low surface area and issues with reuse and regeneration. Moreover, it is concluded that there is a need to develop highly porous, efficient, eco-friendly, cost-effective, mechanically stable, and sustainable MOF hybrids for produced water treatment