23 research outputs found

    Low-dimensional carbon spacers in surface plasmon-coupled emission with femtomolar sensitivity and 1000-fold fluorescence enhancements

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    We present low-dimensional carbon spacer engineering technology in surface plasmon-coupled emission for femtomolar sensitivity and fluorescence enhancements exceeding 1000 fold.</p

    Purcell factor based understanding of enhancements in surface plasmon-coupled emission with DNA architectures

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    Tuning the Purcell factor with DNA architectures to realize &gt;130-fold fluorescence enhancements in surface plasmon-coupled emission.</p

    Spacer layer engineering for ultrasensitive Hg(II) detection on surface plasmon-coupled emission platform

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    AbstractIn this work, we demonstrate for the first time the ultrasensitive detection of Hg2+ ions with femtomolar sensitivity in water samples with the use of the surface plasmon-coupled emission (SPCE) platform. The use of portable network diagnostic tools for water security and integrated water shed management is a topic of recent research interest. In this context, the current study explores Hg2+ monitoring using a rhodamine-6G (Rh6G) derivative bearing a monothiospirolactone mounted onto a SPCE substrate. Thus far, the limit of detection for mercury ions by the conventional fluorescence technique has been 0.15 nm. However, we have achieved 1 fm Hg2+ detection using silver nanoparticle-based spacer layer engineering on an SPCE sensor chip. Using this technology, a field device can be fabricated for rapid, ultrasensitive, multi-analyte detection (of contaminants) in water samples.</jats:p

    Spacer layer engineering for ultrasensitive Hg(II) detection on surface plasmon-coupled emission platform

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    In this work, we demonstrate for the first time the ultrasensitive detection of Hg²⁺ ions with femtomolar sensitivity in water samples with the use of the surface plasmon-coupled emission (SPCE) platform. The use of portable network diagnostic tools for water security and integrated water shed management is a topic of recent research interest. In this context, the current study explores Hg²⁺ monitoring using a rhodamine-6G (Rh6G) derivative bearing a monothiospirolactone mounted onto a SPCE substrate. Thus far, the limit of detection for mercury ions by the conventional fluorescence technique has been 0.15 nm. However, we have achieved 1 fm Hg²⁺ detection using silver nanoparticle-based spacer layer engineering on an SPCE sensor chip. Using this technology, a field device can be fabricated for rapid, ultrasensitive, multi-analyte detection (of contaminants) in water samples.S.S.R., P.K.B., and V.S. acknowledge the support from DBT Ramalingaswamy fellowship (102/ IFD/SAN/776/2015-16), DST Fast Track scheme (no. SR/ FT/CS-51/2010(G)) and UGC-BSR fellowship, Government of India. Guidance from Bhagawan Sri Sathya Sai Baba is also gratefully acknowledged.https://www.degruyter.com/document/doi/10.1515/ntrev-2017-0124/htm
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