4,897 research outputs found
The Atomic and Electronic Structure of Liquid N- Methylformamide as Determined from Diffraction Experiments
The structure of liquid N-methylformamide (NMF) has been investigated using
synchrotron radiation at 77 and 95 keV. The use of high energy photons has
several advantages, in this case especially the large accessible momentum
transfer range, the low absorption and the direct comparability with neutron
diffraction. The range of momentum transfer covered is 0.6 \AA Q
24.0 \AA. Neutron diffraction data on the same sample in the same
momentum transfer range have been published previously. In that study two
differently isotope - substituted species were investigated. In order to
compare neutron and photon diffraction data properly Reverse Monte Carlo (RMC-)
simulations have been performed. Some modifications had to be added to the
standard RMC- code introducing different constraints for inter- and
intramolecular distances as these distances partly overlap in liquid NMF. RMC-
simulations having only the neutron data as input were carried out in order to
test the quality of the X-ray data. The photon structure factor calculated from
the RMC- configurations is found to agree well with the present experimental
data, while it deviates considerably from earlier X-ray work using low energy
photons (17 keV). Finally we discuss whether the different interaction
mechanisms of neutrons and photons can be used to directly access the
electronic structure in the liquid. Evidence is presented that the elastic self
scattering part of liquid NMF is changed with respect to the independent atom
approximation. This modification can be accounted for by a simple charged atoms
model.Comment: Accepted for publication in Molecular Physics, LaTex file, 12 pages,
figures not include
Influence of oxygen ordering kinetics on Raman and optical response in YBa_2Cu_3O_{6.4}
Kinetics of the optical and Raman response in YBa_2Cu_3O_{6.4} were studied
during room temperature annealing following heat treatment. The superconducting
T_c, dc resistivity, and low-energy optical conductivity recover slowly,
implying a long relaxation time for the carrier density. Short relaxation times
are observed for the B_{1g} Raman scattering -- magnetic, continuum, and phonon
-- and the charge transfer band. Monte Carlo simulations suggest that these two
relaxation rates are related to two length scales corresponding to local oxygen
ordering (fast) and long chain and twin formation (slow).Comment: REVTeX, 3 pages + 4 PostScript (compressed) figure
Geometrical Optics Formalism to Model Contrast in Dark-Field X-ray Microscopy
Dark-field X-ray microscopy is a new full-field imaging technique that
nondestructively maps the structure and local strain inside deeply embedded
crystalline elements in three dimensions. Placing an objective lens in the
diffracted beam generates a magnified projection image of a local volume. We
provide a general formalism based on geometrical optics for the diffraction
imaging, valid for any crystallographic space group. This allows simulation of
diffraction images based on micro-mechanical models. We present example
simulations with the formalism, demonstrating how it may be used to design new
experiments or interpret existing ones. In particular, we show how
modifications to the experimental design may tailor the reciprocal-space
resolution function to map specific components of the deformation gradient
tensor. The formalism supports multi-length scale experiments, as it enables
DFXM to be interfaced with 3DXRD. The formalism is demonstrated by comparison
to experimental images of the strain field around a straight dislocation
In operando studies of an yttria stabilized zirconia electrolyte supported symmetric solid oxide cell by Dark field X-ray Microscopy at ID06
Development status of a Laue lens project for gamma-ray astronomy
We report the status of the HAXTEL project, devoted to perform a design study
and the development of a Laue lens prototype. After a summary of the major
results of the design study, the approach adopted to develop a Demonstration
Model of a Laue lens is discussed, the set up described, and some results
presented.Comment: 11 pages, 11 figures, 2007 SPIE Conference on Optics for EUV, X-Ray,
and Gamma-Ray Astronomy II
In operando studies of an yttria stabilized zirconia electrolyte supported symmetric solid oxide cell by Dark field X-ray Microscopy at ID06
Using Dark Field X-Ray Microscopy To Study In-Operando Yttria Stabilized Zirconia Electrolyte Supported Solid Oxide Cell
Bivariate genetic modelling of the response to an oral glucose tolerance challenge: A gene x environment interaction approach
AIMS/HYPOTHESIS: Twin and family studies have shown the importance of genetic factors influencing fasting and 2 h glucose and insulin levels. However, the genetics of the physiological response to a glucose load has not been thoroughly investigated. METHODS: We studied 580 monozygotic and 1,937 dizygotic British female twins from the Twins UK Registry. The effects of genetic and environmental factors on fasting and 2 h glucose and insulin levels were estimated using univariate genetic modelling. Bivariate model fitting was used to investigate the glucose and insulin responses to a glucose load, i.e. an OGTT. RESULTS: The genetic effect on fasting and 2 h glucose and insulin levels ranged between 40% and 56% after adjustment for age and BMI. Exposure to a glucose load resulted in the emergence of novel genetic effects on 2 h glucose independent of the fasting level, accounting for about 55% of its heritability. For 2 h insulin, the effect of the same genes that already influenced fasting insulin was amplified by about 30%. CONCLUSIONS/INTERPRETATION: Exposure to a glucose challenge uncovers new genetic variance for glucose and amplifies the effects of genes that already influence the fasting insulin level. Finding the genes acting on 2 h glucose independently of fasting glucose may offer new aetiological insight into the risk of cardiovascular events and death from all causes
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