Optical properties, electron-phonon coupling, and Raman scattering of vanadium ladder compounds

The electronic structure of two V-based ladder compounds, the quarter-filled NaV$_2$O$_5$ in the symmetric phase and the iso-structural half-filled CaV$_2$O$_5$ is investigated by ab initio calculations. Based on the bandstructure we determine the dielectric tensor $\epsilon(\omega)$ of these systems in a wide energy range. The frequencies and eigenvectors of the fully symmetric A$_{g}$ phonon modes and the corresponding electron-phonon and spin-phonon coupling parameters are also calculated from first-principles. We determine the Raman scattering intensities of the A$_g$ phonon modes as a function of polarization and frequency of the exciting light. All results, i.e. shape and magnitude of the dielectric function, phonon frequencies and Raman intensities show very good agreement with available experimental data.Comment: 11 pages, 10 figure

Formation of plasma around a small meteoroid: 1. Kinetic theory

This article is a companion to Dimant and Oppenheim [2017] https://doi.org/10.1002/2017JA023963.This paper calculates the spatial distribution of the plasma responsible for radar head echoes by applying the kinetic theory developed in the companion paper. This results in a set of analytic expressions for the plasma density as a function of distance from the meteoroid. It shows that at distances less than a collisional mean free path from the meteoroid surface, the plasma density drops in proportion to 1/R where R is the distance from the meteoroid center; and, at distances much longer than the mean‐free‐path behind the meteoroid, the density diminishes at a rate proportional to 1/R2. The results of this paper should be used for modeling and analysis of radar head echoes.This work was supported by NSF grant AGS-1244842. (AGS-1244842 - NSF

Folded modes in the infrared spectra of the spin-Peierls phase of CuGeO_3

Polarized far-infrared transmittance spectra of CuGeO_3 single crystals were measured at different temperatures (6K < T < 300K). Two spectral lines, at 284.2 cm-1 in E||c polarization and at 311.7 cm-1 in E||b polarization, appear at the temperature of the spin-Peierls transition and grow in intensity with decreasing temperature. Both of them are, most probably, folded modes of the dimerized lattice. We discuss a possible role of the spin-phonon interaction in the formation of the 311.7 cm-1 feature.Comment: 4 pages, 5 figures, 1 table; Submitted to Phys.Rev.B Second revision. Figures and text were slightly change

Effect of Acute Heat Stress on Some Hematological Parameters, Trace Elements and Meat Quality in Rabbits

The aim of the present study was to investigate the effect of acute heat stress on some hematological parameters, trace elements and meat quality traits in rabbits. Twelve male rabbits at the age of 4 months were allocated into 2 groups: control and experimental. The experimental rabbits were exposed to intermittent solar radiation for 4 hours at 36 °C. The following parameters were determined: white blood cells (WBC) count, red blood cells (RBC) count, hematocrit, neutrophil and lymphocyte percentages, liver and meat content of chromium (Cr) and selenium (Se), pH of meat at 60 min and 24 h post mortem, meat color, myoglobin and water holding capacity (WHC). Exposure to heat increased neutrophil to lymphocyte ratio (P<0.01) and liver content of Cr (P<0.01), while WBC count, RBC count, hematocrit, liver Se, muscle Cr and Se, pH of meat at 24 h, meat color, myoglobin and WHC were not affected by the applied heat load. The experimental rabbits had significantly lower meat pH at 60 min after slaughter relative to the control rabbits (P<0.05). It was suggested that experimental rabbits had sufficient muscle glycogen at the time of slaughter needed to produce the lactic acid that reduced the ultimate pH of post-mortem muscle within the range observed in the control rabbits

Raman, infrared and optical spectra of the spin-Peierls compound NaV_2O_5

We have measured polarized spectra of Raman scattering, infrared and optical transmission of NaV_2O_5 single crystals above the temperature of the spin-Peierls transition Tsp=35 K. Some of the far-infrared (FIR) phonon lines are strongly asymmetric, due to the spin-phonon interaction. In addition to the phonon lines, a broad band was observed in the c(aa)c Raman spectrum and in the E||a FIR transmission spectrum. A possible origin of these bands is discussed. The absorption band at 10000 cm-1 1.25 eV is attributed to vanadium d-d electronic transitions while the absorption edge above 3 eV is supposed to correspond to the onset of charge-transfer transitions.Comment: 7 figures, 8 page

Optical spectra, crystal-field parameters, and magnetic susceptibility of the new multiferroic NdFe3(BO3)4

We report high-resolution optical absorption spectra for NdFe3(BO3)4 trigonal single crystal which is known to exhibit a giant magnetoelectric effect below the temperature of magnetic ordering TN = 33 K. The analysis of the temperature-dependent polarized spectra reveals the energies and, in some cases, symmetries and exchange splittings of Nd3+ 84 Kramers doublets. We perform crystal-field calculations starting from the exchange-charge model, obtain a set of six real crystal-field parameters, and calculate wave functions and magnetic g-factors. In particular, the values g(perpendicular) = 2.385, g(parallel) = 1.376 were found for the Nd3+ ground-state doublet. We obtain Bloc=7.88 T and |JFN|= 0.48 K for the values of the local effective magnetic field at liquid helium temperatures at the Nd3+ site and the Nd - Fe exchange integral, respectively, using the experimentally measured Nd3+ ground-state splitting of 8.8 cm-1. To check reliability of our set of crystal field parameters we model the magnetic susceptibility data from literature. A dimer containing two nearest-neighbor iron ions in the spiral chain is considered to partly account for quasi-one-dimensional properties of iron borates, and then the mean-field approximation is used. The results of calculations with the exchange parameters for Fe3+ ions Jnn = -6.25 K (intra-chain interactions) and Jnnn = -1.92 K (inter-chain interactions) obtained from fitting agree well with the experimental data.Comment: 13 pages, 8 figures, 2 table

Risk factors for the preservation of morphological changes in the gastric mucosa after eradication therapy for Helicobacter pylori infection in children with chronic gastritis

We conducted a clinical, morphofunctional examination and standard treatment of 155 children with chronic gastroduodenitis associated with Helicobacter pylori (HP) infection. It was кevealed that after 6 months lymphoplasmacytic infiltration of the gastric mucosa (GM) preserved in 37% of cases, and unspecified atrophy - in 9%, increased C3 and C4 components of the compliment - in 19% of children, antroduodenal discoordination on the background of postprandial secretin and cholecystokinin level - in 25%, as well as disorders of the intestinal microbiot