Obtaining lignin nanoparticles by sonication

Lignin, the main natural aromatic polymer was always aroused researchers interest. Currently around 90% of this biomaterial is burned for energy. It has a very complex and complicated structure which depends on the separation method and plant species, what determine difficulties to use as a raw material widely. This research presents a physical method to modify lignin by ultrasonic irradiation in order to obtain nanoparticles. The nanoparticles synthesized were dimensionally and morphologically characterized. At the same time the preoccupations were to determine the structural and compositional changes that occurred after sonication. To achieve this, two types of commercial lignins (wheat straw and Sarkanda grass) were used and the modifications were analyzed by FTIR-spectroscopy, GPC-chromatography, (31)P-NMR-spectroscopy and HSQC0. The results confirm that the compositional and structural changes of nanoparticles obtained are not significantly modified at the intensity applied but depend on the nature of lignin

Do Search for Dibaryonic De - Excitations in Relativistic Nuclear Reactions

Some odd characteristics are observed in the single particle distributions obtained from $He + Li$ interactions at $4.5 AGeV/c$ momenta which are explained as the manifestation of a new mechanism of strangeness production via dibaryonic de-excitations. A signature of the formation of hadronic and baryonic clusters is also reported. The di-pionic signals of the dibaryonic orbital de-excitations are analyzed in the frame of the MIT - bag Model and a Monte Carlo simulation.The role played by the dibaryonic resonances in relativistic nuclear collisions could be a significant one. Key words: Relativistic nuclear interactions negative pions, negative kaons, di-pions , streamer chamber, dibaryons, MIT - bag model PACS codes: 25.75.+r,14.40.Aq,14.20.Pt,12.40.AsComment: 17 pages,LATEX, preprint ICTP -243 1993,figures available by reques

Non-linear evolution of the cosmological background density field as diagnostic of the cosmological reionization

We present constraints on the cosmological and reionization parameters based on the cumulative mass function of the Ly-alpha systems. We find that the analysis of the cumulative mass function of the Ly-alpha systems indicates a reionization redshift z_r=24.2\+-4 (68%CL) in agreement with the value found on the basis of the WMAP anisotropy measurements, setting constraints on the amplitude of the density contrast, sigma_8=0.91+-0.04 (68\CL), similar to those derived from the X-ray cluster temperature function. Our joint analysis of Ly-alpha cumulative mass function and WMAP anisotropy measurements shows that the possible current identification of a running of the slope, dn_s/dlnk \ne 0, at k_p=0.05Mpc^-1 (multipole l of about 700) is mainly an effect of the existing degeneracy in the amplitude-slope plane at this scale, the result being consistent with the absence of running, the other constraints based on WMAP data remaining substantially unchanged. Finally, we evaluate the progress on the determination the considered parameters achievable by using the final temperature anisotropy data from WMAP and from the forthcoming Planck satellite that will significantly improve the sensitivity and reliability of these results. This work has been done in the framework of the Planck LFI activities.Comment: 40 pages, 6 figure

Radiative effects by high-z UV radiation background: Implications for the future CMB polarization measurements

We investigate the role of the radiative effects for the temporal evolution of the reionization fraction by using cosmological Smooth Particle Hydrodynamics (SPH) simulations. We find that the increase of photo-ionization and photo-heating rates due to optical depth effects results in a significantly contribute to the heating of the IGM before and during the reionization. The main effect of the UV radiation spectrum on the temporal evolution of the ionization fraction is given by the value of the reionization redshift and the redshift interval, in which the reionization is completed. We evaluate the effects of the UV radiation background on the CMB angular power spectrum taking into account different temporal evolutions of the ionization fraction. We show that through E-mode CMB polarization power spectrum measurements, the Planck experiment will have the sensitivity to distinguish between different reionization histories even when they imply the same optical depth to electron scattering and degenerated temperature anisotropy power spectra.Comment: 33 pages, 9 figure