1,856 research outputs found
Lonely adatoms in space
There is a close relation between the problems of second layer nucleation in
epitaxial crystal growth and chemical surface reactions, such as hydrogen
recombination, on interstellar dust grains. In both cases standard rate
equation analysis has been found to fail because the process takes place in a
confined geometry. Using scaling arguments developed in the context of second
layer nucleation, I present a simple derivation of the hydrogen recombination
rate for small and large grains. I clarify the reasons for the failure of rate
equations for small grains, and point out a logarithmic correction to the
reaction rate when the reaction is limited by the desorption of hydrogen atoms
(the second order reaction regime)
The process of irreversible nucleation in multilayer growth. II. Exact results in one and two dimensions
We study irreversible dimer nucleation on top of terraces during epitaxial
growth in one and two dimensions, for all values of the step-edge barrier. The
problem is solved exactly by transforming it into a first passage problem for a
random walker in a higher-dimensional space. The spatial distribution of
nucleation events is shown to differ markedly from the mean-field estimate
except in the limit of very weak step-edge barriers. The nucleation rate is
computed exactly, including numerical prefactors.Comment: 22 pages, 10 figures. To appear in Phys. Rev.
Breakdown of metastable step-flow growth on vicinal surfaces induced by nucleation
We consider the growth of a vicinal crystal surface in the presence of a
step-edge barrier. For any value of the barrier strength, measured by the
length l_es, nucleation of islands on terraces is always able to destroy
asymptotically step-flow growth. The breakdown of the metastable step-flow
occurs through the formation of a mound of critical width proportional to
L_c=1/sqrt(l_es), the length associated to the linear instability of a
high-symmetry surface. The time required for the destabilization grows
exponentially with L_c. Thermal detachment from steps or islands, or a steeper
slope increase the instability time but do not modify the above picture, nor
change L_c significantly. Standard continuum theories cannot be used to
evaluate the activation energy of the critical mound and the instability time.
The dynamics of a mound can be described as a one dimensional random walk for
its height k: attaining the critical height (i.e. the critical size) means that
the probability to grow (k->k+1) becomes larger than the probability for the
mound to shrink (k->k-1). Thermal detachment induces correlations in the random
walk, otherwise absent.Comment: 10 pages. Minor changes. Accepted for publication in Phys. Rev.
Coarsening in surface growth models without slope selection
We study conserved models of crystal growth in one dimension [] which are linearly unstable and develop a mound
structure whose typical size L increases in time (). If the local
slope () increases indefinitely, depends on the exponent
characterizing the large behaviour of the surface current (): for and for
.Comment: 7 pages, 2 EPS figures. To be published in J. Phys. A (Letter to the
Editor
Nonmonotonic roughness evolution in unstable growth
The roughness of vapor-deposited thin films can display a nonmonotonic
dependence on film thickness, if the smoothening of the small-scale features of
the substrate dominates over growth-induced roughening in the early stage of
evolution. We present a detailed analysis of this phenomenon in the framework
of the continuum theory of unstable homoepitaxy. Using the spherical
approximation of phase ordering kinetics, the effect of nonlinearities and
noise can be treated explicitly. The substrate roughness is characterized by
the dimensionless parameter , where denotes the
roughness amplitude, is the small scale cutoff wavenumber of the
roughness spectrum, and is the lattice constant. Depending on , the
diffusion length and the Ehrlich-Schwoebel length , five regimes
are identified in which the position of the roughness minimum is determined by
different physical mechanisms. The analytic estimates are compared by numerical
simulations of the full nonlinear evolution equation.Comment: 16 pages, 6 figures, to appear on Phys. Rev.
Shor's quantum factoring algorithm on a photonic chip
Shor's quantum factoring algorithm finds the prime factors of a large number
exponentially faster than any other known method a task that lies at the heart
of modern information security, particularly on the internet. This algorithm
requires a quantum computer a device which harnesses the `massive parallelism'
afforded by quantum superposition and entanglement of quantum bits (or qubits).
We report the demonstration of a compiled version of Shor's algorithm on an
integrated waveguide silica-on-silicon chip that guides four single-photon
qubits through the computation to factor 15.Comment: 2 pages, 1 figur
The process of irreversible nucleation in multilayer growth. I. Failure of the mean-field approach
The formation of stable dimers on top of terraces during epitaxial growth is
investigated in detail. In this paper we focus on mean-field theory, the
standard approach to study nucleation. Such theory is shown to be unsuitable
for the present problem, because it is equivalent to considering adatoms as
independent diffusing particles. This leads to an overestimate of the correct
nucleation rate by a factor N, which has a direct physical meaning: in average,
a visited lattice site is visited N times by a diffusing adatom. The dependence
of N on the size of the terrace and on the strength of step-edge barriers is
derived from well known results for random walks. The spatial distribution of
nucleation events is shown to be different from the mean-field prediction, for
the same physical reason. In the following paper we develop an exact treatment
of the problem.Comment: 19 pages, 3 figures. To appear in Phys. Rev.
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