20 research outputs found

    Density of states and order parameter in dirty anisotropic superconductors

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    Journals published by the American Physical Society can be found at http://journals.aps.org/We analyze in detail how the scattering by nonmagnetic impurities affects the shape and amplitude of the order parameter (OF) and the density of states in anisotropic superconductors in the framework of BCS theory. Special attention is paid to the case when the OP is a mixture of d and s waves changing its sign on the Fermi surface. The critical temperature is shown to decay with the increase of the residual resistance according to the power law. At zero temperature impurity scattering gives rise to a peculiar phase transition from a gapless regime to a state with a finite gap in the quasiparticle spectrum

    Behavior and Impact of Zirconium in the Soil–Plant System: Plant Uptake and Phytotoxicity

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    Because of the large number of sites they pollute, toxic metals that contaminate terrestrial ecosystems are increasingly of environmental and sanitary concern (Uzu et al. 2010, 2011; Shahid et al. 2011a, b, 2012a). Among such metals is zirconium (Zr), which has the atomic number 40 and is a transition metal that resembles titanium in physical and chemical properties (Zaccone et al. 2008). Zr is widely used in many chemical industry processes and in nuclear reactors (Sandoval et al. 2011; Kamal et al. 2011), owing to its useful properties like hardness, corrosion-resistance and permeable to neutrons (Mushtaq 2012). Hence, the recent increased use of Zr by industry, and the occurrence of the Chernobyl and Fukashima catastrophe have enhanced environmental levels in soil and waters (Yirchenko and Agapkina 1993; Mosulishvili et al. 1994 ; Kruglov et al. 1996)

    Shell effects in fission and quasi-fission of heavy and superheavy nuclei

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    Results of the experiments aimed at the study of fission and quasi-fission processes in the reactions 12C+204Pb,48Ca+144,154Sm,168Er,208Pb,244Pu,248Cm;58Fe+208Pb,244Pu,248Cm, and64Ni+186W,242Pu are presented in the work. The choice of the above-mentioned reactions was inspired by recent experiments on the production of the isotopes283112,289114 and283116 at Dubna [1],[2] using the same reactions. The58Fe and64Ni projectiles were chosen since the corresponding projectile-target combinations lead to the synthesis of even heavier elements. The experiments were carried out at the U-400 accelerator of the Flerov Laboratory of Nuclear Reactions (JINR, Russia), the XTU Tandem accelerator of the National Laboratory of Legnaro (LNL, Italy) and the Accelerator of the Laboratory of University of Jyvaskyla (JYFL, Finland) using the time-of-flight spectrometer of fission fragments CORSET[3] and the neutron multi-detector DEMON[4],[5]. The role of shell effects and the influence of the entrance channel on the mechanism of the compound nucleus fusion-fission and the competitive process of quasi-fission are discussed

    Dynamical Scaling Implications of Ferrari, Prähofer, and Spohn’s Remarkable Spatial Scaling Results for Facet-Edge Fluctuations

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    Spurred by theoretical predictions from Spohn and coworkers (Phys. Rev. E 69, 035102(R) (2004)), we rederived and extended their result heuristically as well as investigated the scaling properties of the associated Langevin equation in curved geometry with an asymmetric potential. With experimental colleagues we used STM line scans to corroborate their prediction that the fluctuations of the step bounding a facet exhibit scaling properties distinct from those of isolated steps or steps on vicinal surfaces. The correlation functions was shown to go as t 0.15(3) decidedly different from the t 0.26(2) behavior for fluctuations of isolated steps. From the exponents, we were able to categorize the universality, confirming the prediction that the non-linear term of the KPZ equation, long known to play a central role in non-equilibrium phenomena, can also arise from the curvature or potential-asymmetry contribution to the step free energy. We also considered, with modest Monte Carlo simulations, a toy model to show that confinement of a step by another nearby step can modify as predicted the scaling exponents of the step’s fluctuations. This paper is an expansion of a celebratory talk at the 95th Rutgers Statistical Mechanics Conference, May 2006.https://doi.org/10.1007/s10955-014-0981-

    On the potential for CO<sub>2</sub> mineral storage in continental flood basalts – PHREEQC batch- and 1D diffusion–reaction simulations

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    <p>Abstract</p> <p>Continental flood basalts (CFB) are considered as potential CO<sub>2</sub> storage sites because of their high reactivity and abundant divalent metal ions that can potentially trap carbon for geological timescales. Moreover, laterally extensive CFB are found in many place in the world within reasonable distances from major CO<sub>2</sub> point emission sources.</p> <p>Based on the mineral and glass composition of the Columbia River Basalt (CRB) we estimated the potential of CFB to store CO<sub>2</sub> in secondary carbonates. We simulated the system using kinetic dependent dissolution of primary basalt-minerals (pyroxene, feldspar and glass) and the local equilibrium assumption for secondary phases (weathering products). The simulations were divided into closed-system batch simulations at a constant CO<sub>2</sub> pressure of 100 bar with sensitivity studies of temperature and reactive surface area, an evaluation of the reactivity of H<sub>2</sub>O in scCO<sub>2</sub>, and finally 1D reactive diffusion simulations giving reactivity at CO<sub>2</sub> pressures varying from 0 to 100 bar.</p> <p>Although the uncertainty in reactive surface area and corresponding reaction rates are large, we have estimated the potential for CO<sub>2</sub> mineral storage and identified factors that control the maximum extent of carbonation. The simulations showed that formation of carbonates from basalt at 40 C may be limited to the formation of siderite and possibly FeMg carbonates. Calcium was largely consumed by zeolite and oxide instead of forming carbonates. At higher temperatures (60 – 100 C), magnesite is suggested to form together with siderite and ankerite. The maximum potential of CO<sub>2</sub> stored as solid carbonates, if CO<sub>2</sub> is supplied to the reactions unlimited, is shown to depend on the availability of pore space as the hydration and carbonation reactions increase the solid volume and clog the pore space. For systems such as in the scCO<sub>2</sub> phase with limited amount of water, the total carbonation potential is limited by the amount of water present for hydration of basalt.</p
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