Temperature dependences of oscillation parameters in ferroelectric liquid crystals

Oscillation processes have been revealed in the course of reversible polarization study in ferroelectric liquid crystals. The oscillation frequency of polarization vector has been found to be from 1 to 30 kHz. The oscillation parameters were studied as functions of temperature. Temperature dependences of the oscillation amplitude and damping decrement have been measured

New chiral E- and Z-isomers of the 1R,4R-2-arylidene-p-menthane-3-ones in induced cholesteric and ferroelectric liquid crystals

A novel pair of the E- and Z-isomeric 1R,4R-2-(4-heptyloxyphenyl)-benzylidene-p-menthan-3-ones has been prepared and the influence of distinctions in their molecular geometry on macroscopic properties of liquid crystal systems with the induced supra-molecular helical structure has been studied. The significantly lower helical twisting power of the chiral Z-isomer in comparison with that of E- one has been confirmed in the case of induced cholesteric systems based on 4-pentyl-4-cyanobiphenyl. The phase behavior and ferroelectric characteristics have been investigated for smectic-C* compositions based on the eutectic mixture of the homological 4-hexyloxyphenyl-4'-hexyloxy- and 4-hexyloxyphenyl-4'-octyloxybenzoates containing the novel isomeric chiral dopants. The spontaneous polarisation of the opposite signs induced by the isomeric chiral components has been revealed for the compositions studied. Distinctions in phase states, absolute values of the spontaneous polarization, smectic tilt angle and rotation viscosity of the systems obtained are discussed

Effect of elastic stresses on free oscillations in ferroelectric liquid crystals

It is shown experimentally that an elastic mechanical stress in a crystal structure is a necessary factor for the appearance of free oscillations of the director of a ferroelectric liquid crystal. Such a mechanical stress arises as a result of internal textural perturbations in the presence of regions with a different orientation of the director or is produced by external pressure applied to one of the cell plates in the appropriate direction. © 1999 American Institute of Physics

Free oscillations in a ferroelectric liquid crystal

A description is given of experimental investigations in which free electromechanical oscillations are obtained for the first time in ferroelectric liquid crystals. © 1997 American Institute of Physics

New (1R,4R)-2-arylidene-p-menthan-3-ones with a bridging ester group in the arylidene fragment. Synthesis and behavior in liquid-crystalline systems

(1R,4R)-2-(4-Hydroxybenzylidene)- and (1R,4R)-2-(4′-hydroxybiphenyl- 4-yl)methylene-p-menthan-3-ones were synthesized by condensation of (-)-menthone with O-tetrahydropyran-2-yl derivatives of 4-hydroxybenzaldehyde and 4′-hydroxy-4-formylbiphenyl, respectively, in a DMSO - base medium followed by the removal of the protective group. The reactions of these hydroxy derivatives with 4-alkylbenzoic, 4-alkyloxybenzoic, trans-4-alkylcyclohexane-4- carboxylic, and 4′-alkylbiphenyl-4-carboxylic acids afforded three series of new chiral esters. Compounds containing the arylidene moiety with three benzene rings were found to exhibit liquid-crystalline properties. The characteristic features of these compounds are discussed based on the results of studies by polarizing microscopy, differential scanning calorimetry, and small-angle X-ray scattering. It was found that the mesomorphic compounds under study can form a smectic A mesophase, twist grain boundary mesophases (TGBA), and blue phases in a wide temperature range. Upon dissolution of certain of chiral compounds in 4′-cyano-4-pentylbiphenyl, a rather high twisting power and the thermal stabilizing effect on mesophases were observed

Resonance phenomena in a ferroelectric liquid crystals

In a surface stabilized ferroelectric liquid crystal cell, optical transmission oscillations have been revealed accompanying mechanical vibrations caused by fast field reversal. Special bookshelf textures, so-called "rainbow", were used in the experiments. Temperature dependences of the oscillation parameters have been studied. The temperature dependence of the oscillation frequency suggests that the some oscillation resonances correspond to modes of the liquid crystals