5,854 research outputs found
Monolayer Molybdenum Disulfide Nanoribbons with High Optical Anisotropy
Two-dimensional Molybdenum Disulfide (MoS2) has shown promising prospects for
the next generation electronics and optoelectronics devices. The monolayer MoS2
can be patterned into quasi-one-dimensional anisotropic MoS2 nanoribbons
(MNRs), in which theoretical calculations have predicted novel properties.
However, little work has been carried out in the experimental exploration of
MNRs with a width of less than 20 nm where the geometrical confinement can lead
to interesting phenomenon. Here, we prepared MNRs with width between 5 nm to 15
nm by direct helium ion beam milling. High optical anisotropy of these MNRs is
revealed by the systematic study of optical contrast and Raman spectroscopy.
The Raman modes in MNRs show strong polarization dependence. Besides that the
E' and A'1 peaks are broadened by the phonon-confinement effect, the modes
corresponding to singularities of vibrational density of states are activated
by edges. The peculiar polarization behavior of Raman modes can be explained by
the anisotropy of light absorption in MNRs, which is evidenced by the polarized
optical contrast. The study opens the possibility to explore
quasione-dimensional materials with high optical anisotropy from isotropic 2D
family of transition metal dichalcogenides
Interlayer Interactions in Anisotropic Atomically-thin Rhenium Diselenide
Recently, two-dimensional (2D) materials with strong in-plane anisotropic
properties such as black phosphorus have demonstrated great potential for
developing new devices that can take advantage of its reduced lattice symmetry
with potential applications in electronics, optoelectronics and
thermoelectrics. However, the selection of 2D material with strong in-plane
anisotropy has so far been very limited and only sporadic studies have been
devoted to transition metal dichalcogenides (TMDC) materials with reduced
lattice symmetry, which is yet to convey the full picture of their optical and
phonon properties, and the anisotropy in their interlayer interactions. Here,
we study the anisotropic interlayer interactions in an important TMDC 2D
material with reduced in-plane symmetry - atomically thin rhenium diselenide
(ReSe2) - by investigating its ultralow frequency interlayer phonon vibration
modes, the layer dependent optical bandgap, and the anisotropic
photoluminescence (PL) spectra for the first time. The ultralow frequency
interlayer Raman spectra combined with the first study of polarization-resolved
high frequency Raman spectra in mono- and bi-layer ReSe2 allows deterministic
identification of its layer number and crystal orientation. PL measurements
show anisotropic optical emission intensity with bandgap increasing from 1.26
eV in the bulk to 1.32 eV in monolayer, consistent with the theoretical results
based on first-principle calculations. The study of the layer-number dependence
of the Raman modes and the PL spectra reveals the relatively weak van der Waals
interaction and 2D quantum confinement in atomically-thin ReSe2.Comment: 17 pages, 5 figures, supplementary informatio
The ultra-low-frequency shear modes of 2-4 layer graphenes observed in their scroll structures at edges
The in-plane shear modes between neighbor-layers of 2-4 layer graphenes (LGs)
and the corresponding graphene scrolls rolled up by 2-4LGs were investigated by
Raman scattering. In contrast to that just one shear mode was observed in
3-4LGs, all the shear modes of 3-4LGs were observed in 3-4 layer scrolls (LSs),
whose frequencies agree well with the theoretical predication by both a
force-constant model and a linear chain model. In comparison to the broad width
(about 12cm) for the G band in graphite, all the shear modes exhibit an
intrinsic line width of about 1.0 cm. The local electronic structures
dependent on the local staking configurations enhance the intensity of the
shear modes in corresponding 2-4LSs zones, which makes it possible to observe
all the shear modes. It provides a direct evidence that how the band structures
of FLGs can be sensitive to local staking configurations. This result can be
extended to n layer graphene (n > 4) for the understanding of the basic phonon
properties of multi-layer graphenes. This observation of all-scale shear modes
can be foreseen in other 2D materials with similar scroll structures.Comment: 14 pages, 5 figure
Single Cell Gap Transflective Liquid Crystal Display with Slanted Reflector Above Transmissive Pixels
Single cell gap transflective liquid crystal display which provides that the backlight traverses the reflective pixel portion twice and thereby follows a path similar to that of the ambient light. A slant reflector is built on the path of the back light to reflect the transmitted light to the reflective portion so that the back light and ambient light follow similar paths
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