Dual-function coatings to protect absorbent surfaces from fouling

Fouling of surfaces caused by pollution, contamination, humidity and microorganisms is one of the major sources of the degradation of mineral and composite materials. The inhibition of foulant growth is essential for the prevention of different kinds of damage, ranging from aesthetic, mechanical and chemical, to risks concerning human and environmental health. This study proposes a new approach for the development of a transparent preservative material with water-repellent and biocide attributes through the use of a sol-gel method. It was found that Si–O–Si dense networks can effectively grow into the micro-pores of mineral and cellulose-based materials, promoting self-cleaning properties as well as sufficient protection against bio-fouling

Novel Bi-Functional MoS₂/α-Fe₂O₃ Nanocomposites for High Photocatalytic Performance

In this study, 3-dimensional molybdenum disulfide (MoS2) structures, integrated with hematite (α-Fe2O3) nanoparticles, were fabricated under a convenient two-step hydrothermal route. The fabricated photocatalytic nanocomposites consist of well-arranged MoS2 flakes, resembling spherical flower-like morphology, and the nanoparticulate α-Fe2O3 structures decorate the 3D network. By raising the α-Fe2O3 weight ratio, the composites’ specific surface area and morphology were not affected, regardless of the partial cover of the cavities for higher hematite content. Moreover, the crystallinity examination with XRD, Raman, and FTIR techniques revealed that the precursor reagents were fully transformed to well-crystalized MoS2 and Fe2O3 composites of high purity, as no organic or inorganic residues could be detected. The photocatalytic oxidation and reduction performance of these composites was evaluated against the tetracycline pharmaceutical and the industrial pollutant hexavalent chromium, respectively. The improvement in the removal efficiencies demonstrates that the superior photoactivity originates from the high crystallinity and homogeneity of the composite, in combination with the enhanced charge carriers’ separation in the semiconductors’ interface