Transformer Oil Passivation and Impact of Corrosive Sulphur

In recent years a significant volume of research has been undertaken in order to understand the recent failures in oil insulated power apparatus due to deposition of copper sulphide on the conductors and in the insulation paper. Dibenzyl Disulfide (DBDS) has been found to be the leading corrosive sulphur compound in the insulation oil [1]. The process of copper sulphide formation and the deposition in the paper is still being investigated, but a recently proposed method seems to be gaining some confidence [1]. This method suggests a two-step process; initially the DBDS and some oil soluble copper complexes are formed. Secondly the copper complexes are absorbed in the paper insulation, where they then decompose into copper sulphide [2]. The most commonly used mitigating technique for corrosive sulphur contaminated oil is passivation, normally using Irgamet 39 or 1, 2, 3-benzotriazole (BTA). The passivator is diluted into the oil to a concentration of around 100ppm, where it then reacts with the copper conductors to form a complex layer around the copper, preventing it from interacting with DBDS compounds and forming copper sulphide. This research project will investigate the electrical properties of HV transformers which have tested positive for corrosive sulphur, and the evolution of those properties as the asset degrades due to sulphur corrosion. Parallel to this the long term properties of transformers with passivated insulation oil will be analysed in order to understand the passivator stability and whether it is necessary to keep adding the passivator to sustain its performance. Condition monitoring techniques under investigation will include dielectric spectroscopy, frequency response analysis, recovery voltage method (aka interfacial polarisation) amongst others. Partial discharge techniques will not be investigated, as the voltage between the coil plates is low and therefore it will not contribute significantly to the overall insulation breakdown, in corrosive oil related faults [3]. The goal of this research is to establish key electrical properties in both passivated and non-passivated power transformers that demonstrate detectable changes as the equipment degrades due to the insulation oil being corrosive

The Octarepeat Domain of the Prion Protein Binds Cu(II) with Three Distinct Coordination Modes at pH 7.4

The prion protein (PrP) binds Cu2+ in its N-terminal octarepeat domain. This unusual domain is comprised of four or more tandem repeats of the fundamental sequence PHGGGWGQ. Previous work from our laboratories demonstrates that at full copper occupancy, each HGGGW segment binds a single Cu2+. However, several recent studies suggest that low copper occupancy favors different coordination modes, possibly involving imidazoles from histidines in adjacent octapeptide segments. This is investigated here using a combination of X-band EPR, S-band EPR, and ESEEM, along with a library of modified peptides designed to favor different coordination interactions. At pH 7.4, three distinct coordination modes are identified. Each mode is fully characterized to reveal a series of copper-dependent octarepeat domain structures. Multiple His coordination is clearly identified at low copper stoichiometry. In addition, EPR detected copper−copper interactions at full occupancy suggest that the octarepeat domain partially collapses, perhaps stabilizing this specific binding mode and facilitating cooperative copper uptake. This work provides the first complete characterization of all dominant copper coordination modes at pH 7.4

Structural and dynamical properties of liquid Si. An orbital-free molecular dynamics study

Several static and dynamic properties of liquid silicon near melting have been determined from an orbital free {\em ab-initio} molecular dynamics simulation. The calculated static structure is in good agreement with the available X-ray and neutron diffraction data. The dynamical structure shows collective density excitations with an associated dispersion relation which closely follows recent experimental data. It is found that liquid silicon can not sustain the propagation of shear waves which can be related to the power spectrum of the velocity autocorrelation function. Accurate estimates have also been obtained for several transport coefficients. The overall picture is that the dynamic properties have many characteristics of the simple liquid metals although some conspicuous differences have been found.Comment: 12 pages, 11 figure

The ethos of physical activity delivery in mental health: a narrative study of service user experiences.

Our research into the physical activity experiences of people with severe mental illness has led us to take seriously the social and cultural environment in which physical activity is delivered. In this study, through narrative methodology, we examine service user accounts of physical activity to illuminate the characteristics of physical activity groups that are experienced as positive, helpful, or beneficial. We present several qualities and show how effective leadership and coaching is central to these qualities being present. We conclude that it is not so much what activity is delivered, but how it is delivered that is critical for sustained participation and positive outcomes

Density fluctuations and single-particle dynamics in liquid lithium

The single-particle and collective dynamical properties of liquid lithium have been evaluated at several thermodynamic states near the triple point. This is performed within the framework of mode-coupling theory, using a self-consistent scheme which, starting from the known static structure of the liquid, allows the theoretical calculation of several dynamical properties. Special attention is devoted to several aspects of the single-particle dynamics, which are discussed as a function of the thermodynamic state. The results are compared with those of Molecular Dynamics simulations and other theoretical approaches.Comment: 31 pages (in preprint format), 14 figures. Submitted to Phys. Rev.

Estimating the risks of exposure to harmful algal toxins among Scottish harbour seals

This research was supported by funding from the Scottish Government, Marine Scotland, Marine Mammal Scientific Support Research Programme MMSS/002/15 and by NERC National Capability NPG funding, grant No. NE/R015007/1.Harmful algal bloom (HAB) toxins consumed by marine predators through fish prey can be lethal but studies on the resulting population consequences are lacking. Over the past approximately 20 years there have been large regional declines in some harbour seal populations around Scotland. Analyses of excreta (faeces and urine from live and dead seals and faecal samples from seal haulout sites) suggest widespread exposure to toxins through the ingestion of contaminated prey. A risk assessment model, incorporating concentrations of the two major HAB toxins found in seal prey around Scotland (domoic acid (DA), and saxitoxins (STX)), the seasonal persistence of the toxins in the fish and the foraging patterns of harbour seals were used to estimate the proportion of adults and juveniles likely to have ingested doses above various estimated toxicity thresholds. The results were highly dependent on toxin type, persistence, and foraging regime as well as age class, all of which affected the proportion of exposed animals exceeding toxicity thresholds. In this preliminary model STX exposure was unlikely to result in mortalities. Modelled DA exposure resulted in doses above an estimated lethal threshold of 1900 µg/kg body mass affecting up to 3.8% of exposed juveniles and 5.3% of exposed adults. Given the uncertainty in the model parameters and the limitations of the data these conclusions should be treated with caution, but they indicate that DA remains a potential factor involved in the regional declines of harbour seals. Similar risks may be experienced by other top predators, including small cetaceans and seabirds that feed on similar prey in Scottish waters.Peer reviewe

The impact of smart grid technology on dielectrics and electrical insulation

Delivery of the Smart Grid is a topic of considerable interest within the power industry in general, and the IEEE specifically. This paper presents the smart grid landscape as seen by the IEEE Dielectrics and Electrical Insulation Society (DEIS) Technical Committee on Smart Grids. We define the various facets of smart grid technology, and present an examination of the impacts on dielectrics within power assets. Based on the trajectory of current research in the field, we identify the implications for asset owners and operators at both the device level and the systems level. The paper concludes by identifying areas of dielectrics and insulation research required to fully realize the smart grid concept. The work of the DEIS is fundamental to achieving the goals of a more active, self-managing grid