290 research outputs found

    Asymptotics for Two-dimensional Atoms

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    We prove that the ground state energy of an atom confined to two dimensions with an infinitely heavy nucleus of charge Z>0Z>0 and NN quantum electrons of charge -1 is E(N,Z)=-{1/2}Z^2\ln Z+(E^{\TF}(\lambda)+{1/2}c^{\rm H})Z^2+o(Z^2) when Z→∞Z\to \infty and N/Z→λN/Z\to \lambda, where E^{\TF}(\lambda) is given by a Thomas-Fermi type variational problem and cH≈−2.2339c^{\rm H}\approx -2.2339 is an explicit constant. We also show that the radius of a two-dimensional neutral atom is unbounded when Z→∞Z\to \infty, which is contrary to the expected behavior of three-dimensional atoms.Comment: Revised version to appear in Ann. Henri Poincar\'

    Amino-functionalized CoFe2O4 magnetic nanoparticles as an efficient heterogeneous catalyst for benzaldehyde cyanosilylation

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    Diaminosilane-functionalized cobalt spinel ferrite (CoFe2O4) magnetic nanoparticles were synthesized and used as an efficient heterogeneous base catalyst for the cyanosilylation reaction benzaldehyde with trimethylsilyl cyanide. The magnetic nanoparticle catalyst was characterized by X-ray powder diffraction (XRD), transmission electron microscope (TEM), thermogravimetric analysis (TGA), fourier transform infrared (FT-IR), nitrogen physisorption measurements. Quantitative conversion (99%) was achieved under mild conditions. Recovery of catalyst was facilely achieved by magnetic decantation. The supported catalyst could be reused without significant degradation in catalytic activity

    Determine the source term of a two-dimensional heat equation

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    Let Ω\Omega be a two-dimensional heat conduction body. We consider the problem of determining the heat source F(x,t)=φ(t)f(x,y)F(x,t)=\varphi(t)f(x,y) with φ\varphi be given inexactly and ff be unknown. The problem is nonlinear and ill-posed. By a specific form of Fourier transforms, we shall show that the heat source is determined uniquely by the minimum boundary condition and the temperature distribution in Ω\Omega at the initial time t=0t=0 and at the final time t=1t=1. Using the methods of Tikhonov's regularization and truncated integration, we construct the regularized solutions. Numerical part is given.Comment: 18 page

    On the effective quasi-bosonic Hamiltonian of the electron gas: collective excitations and plasmon modes

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    We consider an effective quasi-bosonic Hamiltonian of the electron gas which emerges naturally from the random phase approximation and describes the collective excitations of the gas. By a rigorous argument, we explain how the plasmon modes can be interpreted as a special class of approximate eigenstates of this model

    Determination of the body force of a two-dimensional isotropic elastic body

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    Let Ω\Omega represent a two−-dimensional isotropic elastic body. We consider the problem of determining the body force FF whose form ϕ(t)(f1(x),f2(x))\phi(t)(f_1(x),f_2(x)) with ϕ\phi be given inexactly. The problem is nonlinear and ill-posed. Using the Fourier transform, the methods of Tikhonov's regularization and truncated integration, we construct a regularized solution from the data given inexactly and derive the explicitly error estimate. Numerical part is givenComment: 23 page
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