PARTIAL NITRITATION OF SYNTHETIC LANDFILL LEACHATE IN AN ATTACHED IMMOBILIZED REACTOR WITH ACRYL FIBER BIOMASS CARRIER

Joint Research on Environmental Science and Technology for the Eart

STUDIES ON NITROGEN REMOVAL PERFORMANCES FOR SINGLE STAGE NITROGEN REMOVAL USING ANAMMOX AND PARTIAL NITRITATION (SNAP) PROCESS

Joint Research on Environmental Science and Technology for the Eart

DEVELOPMENT OF A NOVEL NITROGEN REMOVAL PROCESS USING ANAMMOX AND PARTIAL NITRITATION AND ITS APPLICABILITY TO LANDFILL LEACHATE

Joint Research on Environmental Science and Technology for the Eart

AN EVIDENCE FOR THE CONTRIBUTION OF ANAMMOX PROCESS IN NITROGEN REMOVAL FROM GROUNDWATER

Joint Research on Environmental Science and Technology for the Eart

NITRITATION-ANAMMOX PILOT SYSTEM FOR NITROGEN REMOVAL FROM EFFLUENT OF UASB REACTOR TREATING SWINE WASTEWATER

Joint Research on Environmental Science and Technology for the Eart

VẬT LIỆU TIO2/THAN HOẠT TÍNH TỪ TRO TRẤU VÀ KHẢ NĂNG HẤP PHỤ XANH METHYLENE

In the present work, TiO2/activated-carbon composite (TiO2/RHAC) was synthesized with an assembly method. Activated carbon was fabircated from rice husks. The water-soluble titanium complex was synthesized from anatase via the peroxide complex. The mixture of activated carbon and water-soluble TiO2 was calcined at 600 °C. The obtained samples were characterized by using XRD, SEM, EDX, and UV-Vis-DR. The results show that the obtained composites exhibit excellent adsorption toward methylene blue (MB). The equilibrium data fit the Langmuir isotherm model well. The maximum monolayer capacity calculated from the Langmuir model is 144.7 mg·g–1. The TiO2/RHAC could be self-cleaned after use by photocatalytic degradation. The adsorption capacity insignificantly decreases after three recycles of adsorption, and TiO2/RHAC is a promising adsorbent for removing dyes from the aqueous environment.Trong nghiên cứu này, TiO2/than hoạt tính từ tro trấu (TiO2/RHAC) đã được tổng hợp bằng phương pháp trộn lẫn than hoạt tính và phức titanium. Than hoạt tính được tổng hợp từ tro trấu và phức titanium hòa tan trong nước tổng hợp từ anatase bằng cách tạo phức peroxide. Hỗn hợp được nung trong môi trường thiếu oxy ở 600 °C. Vật liệu tổng hợp được phân tích bằng nhiễu xạ tia X, kính hiển vi điện tử quét và đẳng nhiệt hấp phụ/giải hấp phụ ni tơ. TiO2/RHAC có khả năng hấp phụ cao đối với xanh methylene. Số liệu đẳng nhiệt cân bằng tuân theo mô hình Langmuir và dung lượng hấp phụ cực đại tính theo mô hình này là 144,7 mg·g–1. Chất bị hấp phụ có thể được loại bỏ bằng cách chiếu sáng bằng đèn chiếu nhờ khả năng xúc tác quang hóa của nó. Sau ba lần tái sinh, dung lượng hấp phụ thay đổi không đáng kể. TiO2/RHAC có tiềm năng làm chất hấp phụ xử lý phẩm màu nói chung

Synthesis of C-N-S-Tridoped TiO2 from Vietnam Ilmenite Ore and Its Visible Light-Driven-Photocatalytic Activity for Tetracyline Degradation

In this study, C-N-S-tridoped TiO2 composite was fabricated from TiO2 prepared from ilmenite ore and thiourea by means of hydrothermal method. The obtained material was characterized by X-ray diffraction, Raman scattering spectroscopy, UV-Vis diffuse reflectance spectroscopy, nitrogen adsorption-desorption isotherms, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). It was found that C-N-S-tridoped TiO2 material has a large specific surface area, showing good photocatalytic activity on the degradation of antibiotic tetracycline in visible light region. The study on the mechanism of tetracycline photodegradation using the liquid chromatography with mass spectrometry was performed. It was found that tetracycline has been degraded over C-N-S-tridoped TiO2 catalyst into many different intermediates which can eventually be converted into CO2 and H2O. The kinetics of photocatalytic decomposition of tetracycline were investigated. In addition, the obtained material could catalyze well the degradation of other antibiotics (ciprofloxacin and chloramphenicol) and dyes (rhodamine-B, methylene blue, and organe red). The catalyst was stable after five recycles with slight loss of catalytic activity, which indicates great potential for practical application of C-N-S-tridoped TiO2 catalyst in treatment of wastewater containing tetracycline in particular or antibiotics in general

Phenol Red Adsorption from Aqueous Solution on the Modified Bentonite

In the present work, the modified bentonites were prepared by the modification of bentonite with cetyltrimethylammonium bromide (CTAB), both cetyltrimethylammonium bromide and hydroxy-Fe cations and both cetyltrimethylammonium bromide and hydroxy-Al cations. X-ray diffraction (XRD), thermal analysis (TG-DTA), infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and nitrogen adsorption/desorption isotherms were utilized to characterize the resultant modified bentonites. The modified bentonites were employed for the removal of phenol red dye from aqueous solution. Phenol red adsorption agreed well with the pseudo-second-order kinetic model. The equilibrium data were analyzed on the basis of various adsorption isotherm models, namely, Langmuir, Freundlich, and Dubinin‒Radushkevich models. The highest monolayer adsorption capacity of phenol red at 30°C derived from the Langmuir equation was 166.7 mg·g−1, 125.0 mg·g−1, and 100.0 mg·g−1 for CTAB‒bentonite, Al‒CTAB‒bentonite, and Fe‒CTAB‒bentonite, respectively. Different thermodynamic parameters were calculated, and it was concluded that the adsorption was spontaneous (∆G°  0), with increased entropy (∆S° > 0) in all the investigated temperature ranges

Electrochemical Determination of Diclofenac by Using ZIF-67/g-C3N4 Modified Electrode

A facial differential pulse voltammetric procedure using a glassy carbon electrode modified with zeolite imidazolate framework-67/graphitic carbon nitride (ZIF-67/g-C3N4) for the diclofenac (DCF) determination is demonstrated. ZIF-67/g-C3N4 with different mass ratios of the components was synthesized in a self-assembly process. The obtained materials were characterized by using X-ray diffraction, scanning electron microscopy (SEM), EDX-mapping, and nitrogen adsorption/desorption isotherms. The peak current varies linearly with the DCF concentration in the range of 0.2–2.2 μmol·L−1 and has a detection limit of 0.071 μmol·L−1. The modified electrode exhibits acceptable repeatability, reproducibility, and selectivity towards DCF. The proposed electrode allows determining DCF in human urine without pretreatment, and the results are comparable with those determined with HPLC

Simultaneous determination of chloramphenicol and tinidazole by electrochemical analysis using MnO2/electrochemically reduced graphene oxide modified electrode

Manganese (IV) oxide/electrochemically reduced graphene oxide (MnO2/ErGO) composite was synthesized in an oxidation-reduction process followed by electrochemical reduction. The obtained materials were characterized with X-ray diffraction (XRD), electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM) with energy-dispersive X-ray mapping (EDX mapping). The electrochemical reduction of a manganese dioxide/GO film pre-cast on a glassy carbon electrode to rGO was performed by using the chronoamperometric method for preparing the MnO2/ErGO modified electrode. The obtained modified electrode was employed to simultaneously determine chloramphenicol (CAP) and tinidazole (TNZ) with linear sweep adsorptive cathodic stripping voltammetry (LS-AdCSV). The effect of experimental parameters, e.g., potential and time of accumulation, pH of the buffered solutions, and the potential sweep rate on the response, was examined. Under the optimal conditions, the modified electrode shows a wide linear response for the concentration of CAP and TNZ in the range of 0.1–20 μM with a detection limit of 0.58 and 0.33 μM. The practicability of the developed sensor was explored by detecting CAP and TNZ individually or simultaneously in honey, eye drops, and tablet samples with satisfactory results