Polyhedral units and network connectivity in calcium aluminosilicate glasses from high-energy x-ray diffraction

Structure factors for Cax/2AlxSi1-xO2 glasses (x=0,0.25,0.5,0.67) extended to a wave vector of magnitude Q= 40 1/A have been obtained by high-energy x-ray diffraction. For the first time, it is possible to resolve the contributions of Si-O, Al-O and Ca-O coordination polyhedra to the experimental atomic pair distribution functions (PDF). It has been found that both Si and Al are four-fold coordinated and so participate in a continuous tetrahedral network at low values of x. The number of network breaking defects in the form of non-bridging oxygens (NBO's) increases slowly with x until x=0.5 (NBO's ~ 10% at x=0.5). By x=0.67 the network breaking defects become significant as evidenced by the significant drop in the average coordination number of Si. By contrast, Al-O tetrahedra remain free of NBO's and fully integrated in the Al/Si-O network for all values of x. Calcium maintains a rather uniform coordination sphere of approximately 5 oxygen atoms for all values of x. The results suggest that not only Si/Al-O tetrahedra but Ca-O polyhedra, too, play a role in determining the glassy structure

Probability for Primordial Black Holes in Multidimensional Universe with Nonlinear Scalar Curvature Terms

We investigate multi-dimensional universe with nonlinear scalar curvature terms to evaluate the probability of creation of primordial black holes. For this we obtain Euclidean instanton solution in two different topologies: (a) $S^{D-1}$ - topology which does not accommodate primordial black holes and (b) $S^1\times S^{D-2}$-topology which accommodates a pair of black holes. The probability for quantum creation of an inflationary universe with a pair of black holes has been evaluated assuming a gravitational action which is described by a polynomial function of scalar curvature with or without a cosmological constant ($\Lambda$) using the framework of semiclassical approximation of Hartle-Hawking boundary conditions. We discuss here a class of new gravitational instantons solution in the $R^4$-theory which are relevant for cosmological model building.Comment: 18 pages, no figure. accepted in Phys. Rev.