Strontium isotope systematics of mixing groundwater and oil-field brine at Goose Lake in northeastern Montana, USA

Groundwater, surface water, and soil in the Goose Lake oil field in northeastern Montana have been affected by Cl- rich oil-field brines during long-term petroleum production. Ongoing multidisciplinary geochemical and geophysical studies have identified the degree and local extent of interaction between brine and groundwater. Fourteen samples representing groundwater, surface water, and brine were collected for Sr isotope analyses to evaluate the usefulness of 87Sr/86Sr in detecting small amounts of brine. Differences in Sr concentrations and 87Sr/86Sr are optimal at this site for the experiment. Strontium concentrations range from 0.13 to 36.9 mg/L, and corresponding 87Sr/86Sr values range from 0.71097 to 0.70828. The local brine has 168 mg/L Sr and a 87Sr/86Sr value of 0.70802. Mixing relationships are evident in the data set and illustrate the sensitivity of Sr in detecting small amounts of brine in groundwater. The location of data points on a Sr isotope-concentration plot is readily explained by an evaporation-mixing model. The model is supported by the variation in concentrations of most of the other solutes

Oxygen isotopes and trace elements in the Tiva Canyon Tuff, Yucca Mountain and vicinity, Nye County, Nevada

Yucca Mountain is being studied as a potential site for an underground repository for high-level radioactive waste. Because Yucca Mountain is located in a resource-rich geologic setting, one aspect of the site characterization studies is an evaluation of the resource potential at Yucca Mountain. The Tiva Canyon Tuff (TCT) is a widespread felsic ash-flow sheet that is well exposed in the Yucca Mountain area. Samples of the upper part of the TCT were selected to evaluate the potential for economic mineral deposits within the Miocene volcanic section. These samples of the upper cliff and caprock subunits have been analyzed for oxygen isotopes and a large suite of elements. Oxygen isotope compositions ({delta}{sup 18}O) of the TCT are typical of felsic igneous rocks but range from 6.9 to 11.8 permil, indicating some post-depositional alteration. There is no evidence of the low {delta}{sup 18}O values (less than 6 permil) that are typical of epithermal precious-metal deposits in the region. The variation in oxygen isotope ratios is probably the result of deuteric alteration during late-stage crystallization of silica and low-temperature hydration of glassy horizons; these processes are also recorded by the chemical compositions of the rocks. However, most elemental contents in the TCT reflect igneous processes, and the effects of alteration are observed only in some of the more mobile elements. These studies indicate that the TCT at Yucca Mountain has not been affected by large-scale meteoric-water hydrothermal circulation. The chemical compositions of the TCT, especially the low concentrations of most trace elements including typical pathfinder elements, show no evidence for epithermal metal deposits. Together, these data indicate that the potential for economic mineralization in this part of the volcanic section at Yucca Mountain is small

Strontium Isotopic Composition of Paleozoic Carbonate Rocks in the Nevada Test Site Vicinity, Clark, Lincoln, and Nye Counties, Nevada and Inyo County, California.

Ground water moving through permeable Paleozoic carbonate rocks represents the most likely pathway for migration of radioactive contaminants from nuclear weapons testing at the Nevada Test Site, Nye County, Nevada. The strontium isotopic composition (87Sr/86Sr) of ground water offers a useful means of testing hydrochemical models of regional flow involving advection and reaction. However, reaction models require knowledge of 87Sr/86Sr data for carbonate rock in the Nevada Test Site vicinity, which is scarce. To fill this data gap, samples of core or cuttings were selected from 22 boreholes at depth intervals from which water samples had been obtained previously around the Nevada Test Site at Yucca Flat, Frenchman Flat, Rainier Mesa, and Mercury Valley. Dilute acid leachates of these samples were analyzed for a suite of major- and trace-element concentrations (MgO, CaO, SiO2, Al2O3, MnO, Rb, Sr, Th, and U) as well as for 87Sr/86Sr. Also presented are unpublished analyses of 114 Paleozoic carbonate samples from outcrops, road cuts, or underground sites in the Funeral Mountains, Bare Mountain, Striped Hills, Specter Range, Spring Mountains, and ranges east of the Nevada Test Site measured in the early 1990's. These data originally were collected to evaluate the potential for economic mineral deposition at the potential high-level radioactive waste repository site at Yucca Mountain and adjacent areas (Peterman and others, 1994). Samples were analyzed for a suite of trace elements (Rb, Sr, Zr, Ba, La, and Ce) in bulk-rock powders, and 87Sr/86Sr in partial digestions of carbonate rock using dilute acid or total digestions of silicate-rich rocks. Pre-Tertiary core samples from two boreholes in the central or western part of the Nevada Test Site also were analyzed. Data are presented in tables and summarized in graphs; however, no attempt is made to interpret results with respect to ground-water flow paths in this report. Present-day 87Sr/86Sr values are compared to values for Paleozoic seawater present at the time of deposition. Many of the samples have 87Sr/86Sr compositions that remain relatively unmodified from expected seawater values. However, rocks underlying the northern Nevada Test Site as well as rocks exposed at Bare Mountain commonly have elevated 87Sr/86Sr values derived from post-depositional addition of radiogenic Sr most likely from fluids circulating through rubidium-rich Paleozoic strata or Precambrian basement rocks

Geochemical homogeneity of tuffs at the potential repository level, Yucca Mountain, Nevada

In a potential high-level radioactive waste repository at Yucca Mountain, Nevada, radioactive waste and canisters, drip shields protecting the waste from seepage and from rock falls, the backfill and invert material of crushed rock, the host rock, and water and gases contained within pores and fractures in the host rock together would form a complex system commonly referred to as the near-field geochemical environment. Materials introduced into the rock mass with the waste that are designed to prolong containment collectively are referred to as the Engineered Barrier System, and the host rock and its contained water and gases compose the natural system. The interaction of these component parts under highly perturbed conditions including temperatures well above natural ambient temperatures will need to be understood to assess the performance of the potential repository for long-term containment of nuclear waste. The geochemistry and mineralogy of the rock mass hosting the emplacement drifts must be known in order to assess the role of the natural system in the near-field environment. Emplacement drifts in a potential repository at Yucca Mountain would be constructed in the phenocryst-poor member of the Topopah Spring Tuff which is composed of both lithophysal and nonlithophysal zones. The chemical composition of the phenocryst-poor member has been characterized by numerous chemical analyses of outcrop samples and of core samples obtained by surface-based drilling. Those analyses have shown that the phenocryst-poor member of the Topopah Spring Tuff is remarkably uniform in composition both vertically and laterally. To verify this geochemical uniformity and to provide rock analyses of samples obtained directly from the potential repository block, major and trace elements were analyzed in core samples obtained from drill holes in the cross drift, which was driven to provide direct access to the rock mass where emplacement drifts would be constructed

Geochemistry of outcrop samples from the Raven Canyon and Paintbrush Canyon reference sections, Yucca Mountain, Nevada

The Yucca Mountain area in southern Nevada is being evaluated for its suitability as a potential site for the construction of an underground, high-level nuclear waste repository. With support from the Department of Energy, the US Geological Survey is conducting detailed petrographic, geochemical, and isotopic analyses of samples collected from drill cores and from outcrops. The geochemical and isotopic compositions of the volcanic rocks of Yucca Mountain derive from those of their parental magmas, from changes resulting from the eruptive processes and from post-depositional alteration. In this study, geochemical and isotopic data were acquired on samples from reference sections selected in areas where the effects of the post-depositional alteration has been minimal. These data will be used as baseline information for delineating and correlating zonal features in the volcanic rock alteration that may occur in the thermal aureole of the potential repository after it has been loaded with nuclear waste

Age constraints on fluid inclusions in calcite at Yucca Mountain

The {sup 207}Pb/{sup 235}U ages for 14 subsamples of opal or chalcedony layers younger than calcite formed at elevated temperature range between 1.88 {+-} 0.05 and 9.7 {+-} 1.5 Ma with most values older than 6-8 Ma. These data indicate that fluids with elevated temperatures have not been present in the unsaturated zone at Yucca Mountain since about 1.9 Ma and most likely since 6-8 Ma. Discordant U-Pb isotope data for chalcedony subsamples representing the massive silica stage in the formation of the coatings are interpreted using a model of the diffusive loss of U decay products. The model gives an age estimate for the time of chalcedony formation around 10-11 Ma, which overlaps ages of clay minerals formed in tuffs below the water table at Yucca Mountain during the Timber Mountain thermal event

Hydrology, chemical quality, and characterization of salinity in the Navajo aquifer in and near the Greater Aneth Oil Field, San Juan County, Utah /

One folded map in pocket.Shipping list no.: 97-0045-P.Includes bibliographical references (p. 87-90).Mode of access: Internet