7 research outputs found

    Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group?

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    Oxidative decomposition of cyanocuprates of the type CuLi(CN)Ar (Ar = [C6H4(CH2NMe2)-2]-, 1a) or type CuLi2(CN)Ar2(1b) shows the unexpected formation of aryl-cyanides in up to 30% yield. © 2002 Elsevier Science Ltd. All rights reserved
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