566 research outputs found

    Nano-indentation properties of tungsten carbide-cobalt composites as a function of tungsten carbide crystal orientation

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    Tungsten carbide-cobalt (WC-Co) composites are a class of advanced materials that have unique properties, such as wear resistance, hardness, strength, fracture-toughness and both high temperature and chemical stability. It is well known that the local indentation properties (i.e., nano- and micro-hardness) of the single crystal WC particles dispersed in such composite materials are highly anisotropic. In this paper, the nanoindentation response of the WC grains of a compact, full-density, sintered WC-10Co composite material has been investigated as a function of the crystal orientation. Our nanoindentation survey has shown that the nanohardness was distributed according to a bimodal function. This function was post-processed using the unique features of the finite mixture modelling theory. The combination of electron backscattered difiraction (EBSD) and statistical analysis has made it possible to identify the orientation of the WC crystal and the distinct association of the inherent nanoindentation properties, even for a small set (67) of nanoindentations. The proposed approach has proved to be faster than the already existing ones and just as reliable, and it has confirmed the previous findings concerning the relationship between crystal orientation and indentation properties, but with a significant reduction of the experimental data

    Supply Chain Strategy in the Luxury Fashion Industry

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    Correlation between the indentation properties and microstructure of dissimilar capacitor discharge welded WC-Co/high-speed steel joints

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    The welding of cemented carbide to tool steel is a challenging task, of scientific and industrial relevance, as it combines the high level of hardness of cemented carbide with the high level of fracture toughness of steel, while reducing the shaping cost and extending the application versatility, as its tribological, toughness, thermal and chemical properties can be optimally harmonised. The already existing joining technologies often impart either insufficient toughness or poor high-temperature strength to a joint to withstand the ever-increasing severe service condition demands. In this paper, a novel capacitor discharge welding (CDW) process is investigated for the case of a butt-joint between a tungsten carbide-cobalt (WC-Co) composite rod and an AISI M35 high-speed steel (HSS) rod. The latter was shaped with a conical-ended projection to promote a high current concentration and heat at the welding zone. CDW functions by combining a direct current (DC) electric current pulse and external uniaxial pressure after a preloading step, in which only uniaxial pressure is applied. The relatively high heating and cooling rates promote a thin layer of a characteristic ultrafine microstructure that combines high strength and toughness. Morphological analysis showed that the CDW process: (a) forms a sound and net shaped joint, (b) preserves the sub-micrometric grain structure of the original WC-Co composite base materials, via a transitional layer, (c) refines the microstructure of the original martensite of the HSS base material, and (d) results in an improved corrosion resistance across a 1-mm thick layer near the weld interface on the steel side. A nano-indentation test survey determined: (e) no hardness deterioration on the HSS side of the weld zone, although (f) a slight decrease in hardness was observed across the transitional layer on the composite side. Furthermore, (g) an indication of toughness of the joint was perceived as the size of the crack induced by processing the residual stress after sample preparation was unaltered

    Determination of the yield radius and yield stress in 2198-T3 aluminum alloy by means of the dual-scale instrumented indentation test

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    A new dual-scale instrumented indentation test (DualS-IIT) methodology is here proposed to determine the yield stress (in a tensile-like sense). The methodology involves measuring the bulk yield radius, as defined by the expansion cavity model (ECM), induced by a Vickers macro-indentation in a medium plane cross-section. The bulk yield radius is measured by means of a subsurface nano-hardness survey along the load direction in correspondence to the transition interface between the hemispherical strain hardened region and the surrounding elastic region. The methodology has been applied to an Al–Li (A2198-T3) alloy and a yield stress of 297 MPa has been measured (in agreement with a tensile test); moreover, anomalous plastic deformation behaviour has appeared under indentation. The combination of macro- and nano-indentation tests in one single experiment, as in the proposed methodology, offers a unique experimental basis to directly correlate the mechanical properties of a material at two different scales, which at present is an open issue in the research on indentation

    Effect of a high forage: Concentrate ratio on milk yield, blood parameters and oxidative status in lactating cows

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    A feeding strategy that requires a forage: concentrate ratio equal to 70: 30, with at least five different herbs in the forage and the use of silages prohibited, has recently been introduced in Italy. Despite the benefits in terms of human health (lower ω6: ω3 ratio, higher conjugated linoleic acid level) of the obtained milk, little information regarding the possible effects on cows' health is available. The aim of this study was to evaluate the effects of such a feeding strategy in dairy cows (90 days in milk at the beginning of the trial) on milk yield and composition, and blood metabolic profile, including the evaluation of oxidative stress. The proposed feeding strategy, compared with a semi-intensive strategy, resulted in an improvement of animal oxidative status (lower levels of reactive oxygen metabolites, higher levels of antioxidant potential and anti-reactive oxygen metabolites) and a significant increase of milk urea only in the first part of the trial. No differences in milk yield and composition were detected throughout the trial
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