Shocked quartz in the SEM: Distinction between amorphous and healed PDFs

Combined SEM techniques show that different CL signatures of PDFs are related to fresh and healed microstructures of PDFs and host quartz. This is confirmed by TEM results. A combination of SEM techniques can give the same type of information as TE

Crystal preferred orientation in peridotite ultramylonites deformed by grain size sensitive creep, étang de Lers, Pyrenees, France

In naturally deformed upper mantle rocks a strong olivine crystallographic preferred orientation (CPO) occurs in rocks with grain sizes larger than about 15 mm. Finer grained peridotites tend to have weak to random olivine CPO. The different types of olivine CPO are usually interpreted in relation to the dominant deformation mechanisms: with a strong CPO indicating dislocation creep and a random CPO indicating grain size sensitive (GSS) mechanisms involving grain boundary sliding and diffusion creep. Here we report the occurrence of a weak but systematic olivine CPO in ultra-fine-grained (0.5e10 mm) ultramylonites from the Étang de Lers lherzolite, Pyrenees, France. The microstructures, with elongated grains and mixed distribution of phases in the ultramylonites indicate deformation by dominant GSS creep. In theory, an olivine CPO may develop in rocks deformed by GSS creep during dislocation accommodated boundary sliding or phase boundary controlled diffusion creep in pyroxene-rich rocks. Alternatively, the CPO may be a relict texture preserved because the elongated grain shapes limit rotation during grain boundary sliding. Our observations confirm theoretical and experimental studies, which predict that systematic CPO and an associated seismic anisotropy can occur in naturally deformed upper mantle rocks during deformation by grain boundary sliding and diffusion creep

Influence of deformation conditions on the development of heterogeneous recrystallization microstructures in experimentally deformed Carrara marble

Recrystallized grains are potentially useful as indicators of palaeostress in naturally deformed rocks, providing that well-calibrated relationships (palaeopiezometers) exist between the recrystallized grain size and stress. Rocks can exhibit microstructures that are heterogeneous, that is, containing recrystallized as well as deformed grains, and showing subgrains within grains that differ in size and character from the grain core to the mantle. Previous studies on palaeopiezometers only rarely took into account such heterogeneous microstructure. We used electron backscattered diffraction (EBSD) to accurately quantify the heterogeneous microstructures in experimentally deformed Carrara marble (flow stress 15-85 MPa, temperature 700-990 8C and natural strain 0.15-0.90). The sizes of bulges, recrystallized grains and deformed grains have been measured. We found that the overall character of the microstructures varies as a function of deformation conditions. In heterogeneous samples showing core-mantle microstructures, the sizes of the bulges and recrystallized grains are independent of strain and show an inverse dependency on stress. The recrystallized grains have been found to nucleate at grain boundary bulges. Our study illustrates that very different microstructures may develop in relation to the complexity of the recrystallization mechanisms. We therefore suggest that piezometers should be calibrated and applied for a single type of overall microstructure

Quartz microstructures in the Younger Dryas boundary layer~ 12.9 ka

In 2007, Firestone et al. proposed that an extraterrestrial impact occurred at the end of the Allerød interstadial, destabilizing the North American ice sheet and initiating the colder Younger Dryas (YD) stadial. Up to now, the evidence for this proposed impact has been heavily debated (Pinter et al., 2011) and no one has been able to provide convincing evidence in favour of the hypothesis. Two years later, Mahaney et al. (2009) claimed that they had frequently found planar deformation features (PDFs) in quartz from a possible YD boundary layer in Venezuela. However, the data presented consisted of an SEM image of the surface of a quartz grain only, and in following work Mahaney et al. (2010) stated that they had found no irrefutable evidence of PDFs. Instead, they showed grains with oriented cracks along their edges, which they claimed to be related to the ‘mass impact and extreme heat’ from incoming ejecta material. However, oriented cracks are not accepted evidence for an impact (French, Koeberl, 2010)

The Younger Dryas impact hypothesis: A critical review

The Younger Dryas impact hypothesis suggests that multiple extraterrestrial airbursts or impacts resulted in the Younger Dryas cooling, extensive wildfires, megafaunal extinctions and changes in human population. After the hypothesis was first published in 2007, it gained much criticism, as the evidence presented was either not indicative of an extraterrestrial impact or not reproducible by other groups. Only three years after the hypothesis had been presented, a requiem paper was published. Despite this, the controversy continues. New evidence, both in favour and against the hypothesis, continues to be published. In this review we briefly summarize the earlier debate and critically analyse the most recent reported evidence, including magnetic microspherules, nanodiamonds, and iridium, shocked quartz, scoria-like objects and lechatelierite. The subsequent events proposed to be triggered by the impact event, as well as the nature of the event itself, are also briefly discussed. In addition we address the timing of the Younger Dryas impact, a topic which, despite its importance, has not gained much attention thus far. We show that there are three challenges related to the timing of the event: accurate age control for some of the sites that are reported to provide evidence for the impact, linking these sites to the onset of the Younger Dryas and, most importantly, an apparent age discrepancy of up to two centuries between different sites associated with the proposed impact event. We would like to stress that if the markers at different locations have been deposited at different points in time, they cannot be related to the same event. Although convincing evidence for the hypothesis that multiple synchronous impacts resulted in massive environmental changes at ∼12,900 yrs ago remains debatable, we conclude that some evidence used to support the Younger Dryas impact hypothesis cannot fully be explained at this point in time

Identification of magnetic Fe-Ti oxides in marine sediments by electron backscatter diffraction in scanning electron microscopy

In paleomagnetic and environmental magnetic studies the magnetomineralogical identification is usually based on a set of rock magnetic parameters, complemented by crystallographic and chemical information retrieved from X-ray diffraction (XRD), (electron) microscopy or energy dispersive spectroscopy (EDS) of selected samples. While very useful, each of these supplementary techniques has its limitations when applied to natural sample material which are related to low particle concentrations (down to the ppm range in marine sediments) and very fine grain sizes (down to the nm scale). Therefore, meaningful application of such techniques depends on sample quality. Electron backscatter diffraction (EBSD) of individual grains in scanning electron microscopy (SEM) enables mineralogical identification of grains down to ∼0.2 micrometer and is particularly powerful when combined with EDS. In this study, we show the merits of EBSD for rock magnetic investigations by analyzing titanomagnetites and hemoilmenites of various compositions and submicron lamella of titanomagnetite-hemoilmenite intergrowths. Such particles often occur in natural marine sediments where EDS often has a semi-quantitative character and compositionally similar intergrowths may be difficult to distinguish. With the mineralogical information provided by EBSD unambiguous identification of spinel-type and trigonal oxides is obtained. Optimal EBSD patterns are gathered from smooth, polished surfaces, but here we show that interpretable EBSD patterns can be obtained directly from the surface of unconsolidated, so called 'non-embedded' particles from marine sediments. This information enhances the interpretative value of rock magnetic parameters. © 2007 The Authors Journal compilation © 2007 RAS

Identification of magnetic Fe-Ti-oxides in marine sediments by electron backscatter diffraction in scanning electron microscopy

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