General Approach To Compute Phosphorescent OLED Efficiency

Phosphorescent organic light-emitting diodes (PhOLEDs) are widely used in the display industry. In PhOLEDs, cyclometalated Ir(III) complexes are the most widespread triplet emitter dopants to attain red, e.g., Ir(piq)3 (piq = 1-phenylisoquinoline), and green, e.g., Ir(ppy)3 (ppy = 2-phenylpyridine), emissions, whereas obtaining operative deep-blue emitters is still one of the major challenges. When designing new emitters, two main characteristics besides colors should be targeted: high photostability and large photoluminescence efficiencies. To date, these are very often optimized experimentally in a trial-and-error manner. Instead, accurate predictive tools would be highly desirable. In this contribution, we present a general approach for computing the photoluminescence lifetimes and efficiencies of Ir(III) complexes by considering all possible competing excited-state deactivation processes and importantly explicitly including the strongly temperature-dependent ones. This approach is based on the combination of state-of-the-art quantum chemical calculations and excited-state decay rate formalism with kinetic modeling, which is shown to be an efficient and reliable approach for a broad palette of Ir(III) complexes, i.e., from yellow/orange to deep-blue emitters

Complexity of Sarcomere Protein Gene Mutations in Restrictive Cardiomyopathy

Restrictive cardiomyopathy (RCM) is characterized by impaired filling of the ventricles in the presence of normal wall thickness and systolic function. Although idiopathic RCM is rare compared to other types of cardiomyopathy, the effects are severe. Until recently, many sarcomere genes previously described to be causative mutations in hypertrophic cardiomyopathy and dilated cardiomyopathy have been reported in RCM. Nowadays, it is accepted that primary RCM is also within the spectrum of sarcomere disease. However, the relationship between the identified mutations in sarcomere genes and clinical manifestation are complex, and the possible pathogenic mechanisms are not fully understood. Besides, many RCM‐related sarcomere mutations were reported to cause variable clinical phenotype. Occasionally, “phenotype transition” may also be seen in an individual who was previously diagnosed with RCM

Many-body physics of spontaneously broken higher-rank symmetry: from fractonic superfluids to dipolar Hubbard model

Fractonic superfluids are exotic phases of matter in which bosons are subject to mobility constraints, resulting in features beyond those of conventional superfluids. These exotic phases arise from the spontaneous breaking of higher-rank symmetry (HRS) in many-body systems with higher-moment conservation, such as dipoles, quadrupoles, and angular moments. The aim of this paper is to introduce exciting developments on the theory of spontaneous symmetry breaking in such systems, which we refer to as ``many-fracton systems''. More specifically, we introduce exciting progress on general aspects of HRS, minimal model construction, realization of symmetry-breaking ground states, order parameter, off-diagonal long-range order (ODLRO), Noether currents with continuity equations, Gross-Pitaevskii equations, quantum fluctuations, Goldstone modes, specific heat, generalized Mermin-Wagner theorem, critical current, Landau criterion, symmetry defects, and Kosterlitz-Thouless (KT)-like physics, hydrodynamics, and dipolar Hubbard model realization. This paper is concluded with several future directions.Comment: Title changed, references updated. A short review on recent progress on higher rank symmetry breaking, fractonic superfluids, dipole (and other higher moments) conservation, and related topic

Anisotropic Rabi model

We define the anisotropic Rabi model as the generalization of the spin-boson Rabi model: The Hamiltonian system breaks the parity symmetry; the rotating and counter-rotating interactions are governed by two different coupling constants; a further parameter introduces a phase factor in the counter-rotating terms. The exact energy spectrum and eigenstates of the generalized model is worked out. The solution is obtained as an elaboration of a recent proposed method for the isotropic limit of the model. In this way, we provide a long sought solution of a cascade of models with immediate relevance in different physical fields, including i) quantum optics: two-level atom in single mode cross electric and magnetic fields; ii) solid state physics: electrons in semiconductors with Rashba and Dresselhaus spin-orbit coupling; iii) mesoscopic physics: Josephson junctions flux-qubit quantum circuits.Comment: 5 pages+ 6 pages supplementary, 7 figures, accepted by Phys. Rev.