Synthesis of unsymmetrical alkyl acetals via addition of primary alcohols to allyl ethers mediated by ruthenium complexes

Ru-catalyzed synthesis of mixed alkyl–alkyl acetals via addition of primary alcohols to allyl ethers has been extended to include long-chain and/or functionalized substrates. The catalytic systems for these reactions were generated from RuCl2(PPh3)3 and [RuCl2(1,5-COD)]x and phosphines [PPh3 or P(p-chlorophenyl)3] or SbPh3 . Of particular importance is the almost quantitative elimination of transacetalization. The addition proceeds through allyl complexes, not via isomerization of allyl ethers––subsequent addition of ROH to vinyl ethers

Terminology of polymers and polymerization processes in dispersed systems (IUPAC Recommendations 2011)

A large group of industrially important polymerization processes is carried out in dispersed systems. These processes differ with respect to their physical nature, mechanism of particle formation, particle morphology, size, charge, types of interparticle interactions, and many other aspects. Polymer dispersions, and polymers derived from polymerization in dispersed systems, are used in diverse areas such as paints, adhesives, microelectronics, medicine, cosmetics, biotechnology, and others. Frequently, the same names are used for different processes and products or different names are used for the same processes and products. The document contains a list of recommended terms and definitions necessary for the unambiguous description of processes, products, parameters, and characteristic features relevant to polymers in dispersed systems

DC-DC boost-flyback converter functioning as input stage for one phase low power grid-connected inverter

The paper treats about main problems of one phase DC-AC microinverters that allow single solar cell to be joined with the grid. One of the issues is to achieve high voltage gain with high efficiency in DC circuit, which is necessary for proper operation of inverter. The operating principles, results of practical implementation and investigations on boost-flyback converter, which meets mentioned demands, are presented. (high step-up DC-DC boost-flyback converter for single phase grid microinverter

Single-source three-phase switched-capacitor-based MLI

This article proposes a novel three-phase inverter based on the concept of switched capacitors (SCs), which uses a single DC source. A three-phase, seven-level line-to-line output voltage waveform is synthesised by the proposed topology, which includes eight switches, two capacitors, and one diode per phase leg. The proposed topology offers advantages in terms of inherent voltage gain, lower voltage stresses on power switches, and a reduced number of switching components. Additionally, the switched capacitors are self-balanced, thereby eliminating the need for a separate balancing circuit. The proposed structure and its operating principle, the self-balancing mechanism of the capacitors, and the control strategy are all thoroughly explained in the article. The proposed topology has also been compared with some recent SC topologies. Lastly, the proposed topology has been shown to be feasible through simulation and experimentation