LDH Ternary Nanocomposites: g-C₃N₄ Intercalated ZnOMg-Al for Superior Photocatalytic Activity towards Dye Degradation

Photocatalytic dye degradation has received more attention as an affordable and effective way to treat the dye polluted water. In the present chapter, we are going to discuss; (i) the preparation and photophysical characterization of g-C3N4 intercalated ZnO\Mg-Al LDH, a novel ternary nanocomposite, and (ii) its visible light photocatalytic degradation activity against the methylene blue dye. LDHs are 2D materials composed of “brucite-like” cationic layers where an inclusion of trivalent cations presents an overall positive charge to the nanosheets. g-C3N4 is one of the organic semiconductor photocatalyst which active for several types of reactions such as CO2 reduction, water splitting, and degradation because of its stable, non-toxic, and earth-abundant nature. Mainly, the development of numerous 2D g-C3N4 nanosheets has been extensively used in the field of photocatalyst. By the combination heterojunction with 2D/2D interface can effectively improve the photocatalytic activity. The nitrogen-rich g-C3N4 intercalated ZnO\Mg-Al LDH ternary nanocomposite formation could follow the direct dye degradation process and results enhance the visible light absorption. The enhanced photocatalytic activity is mainly due to the improved charge separation rate and high number of photogenerated electrons. The large number of photogenerated electrons and high charge separation efficiency are effectively influence the dye degradation efficiency

Leaf Extract of Dillenia indica as a Source of Selenium Nanoparticles with Larvicidal and Antimicrobial Potential toward Vector Mosquitoes and Pathogenic Microbes

Chikungunya, dengue, Zika, malaria, Japanese encephalitis, filariasis, West Nile, etc. are mosquito transmitted diseases that have killed millions of people worldwide, and millions of people are at risk of these diseases. Control of the mosquitoes, such as Aedes aegypti and Culex quinquefasciatus, is challenging due to their development of resistance to synthetic insecticides. The habitats of the young mosquitoes are also the habitats for foodborne pathogens like Staphylococcus aureus (MTCC96) and Serratia marcescens (MTCC4822). The present study was aimed at synthesizing eco-friendly green nanoparticles using Dillenia indica leaf broth and analyzing its efficacy in controlling the vector mosquitoes A. aegypti and C. quinquefasciatus, as well as the microbial pathogens St. aureus and Se. marcescens. The formation of selenium nanoparticles (SeNps) was confirmed using UV-Vis spectroscopy (absorption peak at 383.00 nm), Fourier transform infrared radiation (FTIR spectrum peaks at 3177, 2114, 1614, 1502, 1340, 1097, 901, 705, and 508 cm−1), X-ray diffraction (diffraction peaks at 23.3 (100), 29.6 (101), 43.5 (012), and 50.05 (201)), and scanning electron microscopy (oval shaped). The size of the nanoparticles and their stability were analyzed using dynamic light scattering (Z-Average value of 248.0 nm) and zeta potential (−13.2 mV). The SeNps disorganized the epithelial layers and have broken the peritrophic membrane. Histopathological changes were also observed in the midgut and caeca regions of the SeNPs treated A. aegypti and C. quinquefasciatus larvae. The SeNps were also active on both the bacterial species showing strong inhibitory zones. The present results will explain the ability of SeNps in controlling the mosquitoes as well as the bacteria and will contribute to the development of multi potent eco-friendly compounds

Synthesis and Characterization of Efficient ZnO/g-C3N4 Nanocomposites Photocatalyst for Photocatalytic Degradation of Methylene Blue

We examine the photocatalytic activity (PCA) of ZnO/graphitic carbon nitride g-C3N4 (g-CN) composite material for methylene blue (MB) degradation under visible-light irradiation (VLI). The polymeric g-CN materials were fabricated by the pyrolysis of urea and thiourea. More importantly, ZnO/g-CN nanostructured composites were fabricated by adding the different mounts (60, 65, 70, and 75 wt.%) of g-CN into ZnO via the simple hydrothermal process. Among fabricated composites, the 75% ZnO/g-CN nanocomposites displayed a superior PCA for MB degradation, which were ~three-fold an enhancement over the pure ZnO nanoparticles. The fabricated materials have been evaluated by X-ray diffraction (XRD), UV-Vis, Fourier transform infrared (FT-IR) spectroscopy, and electron microscopy. More importantly, the photodegradation of MB could get 98% in ZnO/g-CN could be credited to efficient separation of photo-induced charge carriers between ZnO and g-CN. Also, the recycling efficiency of the as-prepared composites was studied for multiple cycles, which shows that the photocatalysts are stable and suitable to carry out photocatalytic degradation in the logistic mode. Additionally, the probable photocatalytic mechanism has also discussed. The synthetic procedure of ZnO/g-CN based materials can be used in numerous fields such as environmental and in energy storage applications

Augmenting the Photocatalytic Performance of Direct Z-Scheme Bi2O3/g-C3N4 Nanocomposite

Huge demands for photocatalytically efficient visible-light-induced catalysts have spurred widespread interest in building adaptable heterojunctions. Here, we used in situ thermal polymerization to synthesise the Z-scheme Bi2O3/g-C3N4 heterojunction. The optical, structural, chemical, compositional and photocatalytic behaviours of the samples were analysed through various analytical techniques and photocatalytic methylene blue (MB) dye degradation reaction. Among the various ratios of Bi2O3/g-C3N4 heterojunction composites, the 1:1 ratio showed improved visible-light-induced catalytic activity, which attained 91.2% degradation efficiency after 120 min of visible-light exposure. The dye degradation efficiency was calculated under various environmental conditions by varying the dye concentration, solution pH and catalyst dosage. A improved Z-scheme photocatalytic mechanism was proposed in light of the results. A potential mechanism was suggested to explain the photocatalytic activity, and trapping experiments supported it. Last but not least, this strategy might be helpful to prepare the heterojunction photocatalyst for the degradation of organic pigments

Augmenting the Photocatalytic Performance of Direct Z-Scheme Bi₂O₃/g-C₃N₄ Nanocomposite

Huge demands for photocatalytically efficient visible-light-induced catalysts have spurred widespread interest in building adaptable heterojunctions. Here, we used in situ thermal polymerization to synthesise the Z-scheme Bi2O3/g-C3N4 heterojunction. The optical, structural, chemical, compositional and photocatalytic behaviours of the samples were analysed through various analytical techniques and photocatalytic methylene blue (MB) dye degradation reaction. Among the various ratios of Bi2O3/g-C3N4 heterojunction composites, the 1:1 ratio showed improved visible-light-induced catalytic activity, which attained 91.2% degradation efficiency after 120 min of visible-light exposure. The dye degradation efficiency was calculated under various environmental conditions by varying the dye concentration, solution pH and catalyst dosage. A improved Z-scheme photocatalytic mechanism was proposed in light of the results. A potential mechanism was suggested to explain the photocatalytic activity, and trapping experiments supported it. Last but not least, this strategy might be helpful to prepare the heterojunction photocatalyst for the degradation of organic pigments