Nanosecond laser texturing for high friction applications

AbstractA nanosecond pulsed Nd:YAG fibre laser with wavelength of 1064nm was used to texture several different steels, including grade 304 stainless steel, grade 316 stainless steel, Cr–Mo–Al ‘nitriding’ steel and low alloy carbon steel, in order to generate surfaces with a high static friction coefficient. Such surfaces have applications, for example, in large engines to reduce the tightening forces required for a joint or to secure precision fittings easily. For the generation of high friction textures, a hexagonal arrangement of laser pulses was used with various pulse overlaps and pulse energies. Friction testing of the samples suggests that the pulse energy should be high (around 0.8mJ) and the laser pulse overlap should be higher than 50% in order to achieve a static friction coefficient of more than 0.5. It was also noted that laser processing increases the surface hardness of samples which appears to correlate with the increase in friction. Energy-Dispersive X-ray spectroscopy (EDX) measurements indicate that this hardness is caused by the formation of hard metal-oxides at the material surface

Misdiagnosis, Mistreatment, and Harm - When Medical Care Ignores Social Forces.

The Case Studies in Social Medicine demonstrate that when physicians use only biologic or individual behavioral interventions to treat diseases that stem from or are exacerbated by social factors, we risk harming the patients we seek to serve

Pilgrim’s Progress: Lessons in Shared Governance

In the Spring of 2006, Southern Illinois University Edwardsville (SIUE) initiated a conversation to define a “Teacher-Scholar” Philosophy appropriate for the campus. In an experience similar to John Bunyan’s protagonist, Christian, in the classic 1678 allegory Pilgrim’s Progress, the SIUE faculty and administrators set off on a 21st century journey of discovery.[2] Our journey, however, was toward shared governance, rather than down the path to salvation. Like Bunyan’s Christian, we traveled metaphorically through the Town of Vanity, the Valley of Humiliation, the Slough of Despond, the Hill of Difficulty, and the Castle of Doubt. Unlike Christian, however, our journey of discovery ended before we crossed the River of Death and entered the Celestial City

Competition and interaction: Party ties to interest groups in a multidimensional policy space

Political parties and interest groups play a vital role in incorporating societal interests into democratic decision‐making. Therefore, explaining the nature and variation in the relationship between them will advance our understanding of democratic governance. Existing research has primarily drawn attention to how exchange of resources shapes these relationships largely neglecting the role of contextual conditions. Our contribution is to examine whether parties’ structured interactions with different categories of interest groups vary systematically with the pattern of party competition at the level of policy dimensions. First, we argue that higher party fragmentation in a policy space makes organisational ties to interest groups more likely, due to fears of voter loss and splinter groups. Second, we expect higher polarisation between parties on a policy dimension to make ties to relevant groups less likely due to increased electoral costs. We find support for both expectations when analysing new data on 116 party units in 13 mature democracies along nine different policy dimensions. Our findings underline the value of considering the strategic context in which parties and interest groups interact to understand their relationship. The study sheds new light on parties and interest groups as intermediaries in democracy and contributes to a new research agenda connecting interest group research with studies of parties’ policy positions and responsiveness.publishedVersio

In situ neutron diffraction study of the high-temperature redox chemistry of Ln3−xSr1+xCrNiO8−δ (Ln = La, Nd) under hydrogen

International audienceThe chemical reduction of the K2NiF4-type oxides, Ln2Sr2CrNiO8−δ (Ln = La, Nd) and Nd2.25Sr1.75CrNiO8−δ, has been investigated in situ under a dynamic hydrogen atmosphere at high temperature using neutron powder diffraction. The high count-rate and high resolution of the D20 diffractometer at ILL, Grenoble allowed real-time data collection and structure refinement by full-pattern Rietveld analysis with a temperature resolution of 1 °C. Excellent agreement was obtained with the results of thermogravimetric analysis of these materials, which are potential fuel-cell electrodes. The neutron study revealed that oxygen is lost only from the equatorial anion site; the reduction of La2Sr2CrNiO8−δ yields a pure Ni(II) phase, La2Sr2CrNiO7.5en route to a mixed Ni(II,I) oxide, La2Sr2CrNiO7.40, whereas hydrogen reduction of Nd2Sr2CrNiO8−δ and Nd2.25Sr1.75CrNiO8−δ proceeds continuously from Ni(III) to an average oxidation state of 1.80 for the nickel ion. The data collected throughout a subsequent heating/cooling cycle in air indicated that the reduced phases intercalate oxygen reversibly into the equatorial vacancies of the K2NiF4-type structure. The retention of I4/mmm symmetry, along with the absence of the formation of any impurities throughout the heating/cooling cycles under reducing and oxidizing atmospheres, demonstrates both the reversibility and the strongly topotactic character of the oxygen deintercalation/intercalation chemical redox process and establishes the excellent structural stability of these layered mixed-metal oxides over a wide range of oxygen partial pressures

Laser surface texturing for high friction contacts

AbstractA pulsed, nanosecond fibre laser with wavelength of 1064nm was used to texture grade 316 stainless steel and ‘low alloy’ carbon steel in order to generate contacts with high static friction coefficients. High friction contacts have applications in reducing the tightening force required in joints or to easily secure precision fittings, particularly for larger components where standard methods are difficult and expensive. Friction tests performed at normal pressures of 100MPa and 50MPa have shown that very high static friction coefficients greater than 1.25, an increase of 346% over untextured samples at 100MPa, can be easily achieved by single pass laser texturing of both contacting surfaces with the use of low pulse separations. The high static friction coefficients, obtained at 100MPa normal pressure with textures with up to 62.5μm pulse separation (processing speed ∼0.67cm2/s), were found to be associated with a significant amount of plastic deformation caused by the high normal pressures. As a result, higher normal pressures were found to result in higher friction coefficients

Interactions between the Coxiella burnetii parasitophorous vacuole and the endoplasmic reticulum involve the host protein ORP1L

Coxiella burnetii is a gram-negative intracellular bacterium that forms a large, lysosome-like parasitophorous vacuole (PV) essential for bacterial replication. Host membrane lipids are critical for the formation and maintenance of this intracellular niche, yet the mechanisms by which Coxiella manipulates host cell lipid metabolism, trafficking and signalling are unknown. Oxysterol-binding protein-related protein 1 long (ORP1L) is a mammalian lipid-binding protein that plays a dual role in cholesterol-dependent endocytic trafficking as well as interactions between endosomes and the endoplasmic reticulum (ER). We found that ORP1L localized to the Coxiella PV within 12 h of infection through a process requiring the Coxiella Dot/Icm Type 4B secretion system, which secretes effector proteins into the host cell cytoplasm where they manipulate trafficking and signalling pathways. The ORP1L N-terminal ankyrin repeats were necessary and sufficient for PV localization, indicating that ORP1L binds a PV membrane protein. Strikingly, ORP1L simultaneously co-localized with the PV and ER, and electron microscopy revealed membrane contact sites between the PV and ER membranes. In ORP1L-depleted cells, PVs were significantly smaller than PVs from control cells. These data suggest that ORP1L is specifically recruited by the bacteria to the Coxiella PV, where it influences PV membrane dynamics and interactions with the ER

Cation composition effects on oxide conductivity in the Zr_2Y_2O_7-Y_3NbO_7 system

Realistic, first-principles-based interatomic potentials have been used in molecular dynamics simulations to study the effect of cation composition on the ionic conductivity in the Zr2Y2O7-Y3NbO7 system and to link the dynamical properties to the degree of lattice disorder. Across the composition range, this system retains a disordered fluorite crystal structure and the vacancy concentration is constant. The observed trends of decreasing conductivity and increasing disorder with increasing Nb5+ content were reproduced in simulations with the cations randomly assigned to positions on the cation sublattice. The trends were traced to the influences of the cation charges and relative sizes and their effect on vacancy ordering by carrying out additional calculations in which, for example, the charges of the cations were equalised. The simulations did not, however, reproduce all the observed properties, particularly for Y3NbO7. Its conductivity was significantly overestimated and prominent diffuse scattering features observed in small area electron diffraction studies were not always reproduced. Consideration of these deficiencies led to a preliminary attempt to characterise the consequence of partially ordering the cations on their lattice, which significantly affects the propensity for vacancy ordering. The extent and consequences of cation ordering seem to be much less pronounced on the Zr2Y2O7 side of the composition range.Comment: 22 pages, 8 figures, submitted to Journal of Physics: Condensed Matte