Kinetic study of adsorption and photo-decolorization of Reactive Red 198 on TiO2 surface

Recycling and reuse of wastewater after purification will reduce the environmental pollution as well as fulfill the increasing demand of water. Adsorption-based water treatment process is very popular for dye-house wastewater treatment. The present study deals with treatment of wastewater contaminated by reactive dye. TiO2 is used as adsorbent and the spent adsorbent has been regenerated by Advanced Oxidation Process (AOP), without using any other chemicals. TiO2 adsorbs dye molecules and then those dye molecules have been oxidized via a photocatalytic reaction in presence of UV irradiation. Kinetics of dye adsorption and photocatalytic oxidation reaction has been developed in this study. Photocatalyst adsorbent (TiO2) has been reused several times after regeneration. The activity of catalyst decreases after each cycle; due to poisoning cause by intermediate by-products. Kinetic of this catalyst deactivation has been incorporated with L–H model to develop the photocatalytic reaction kinetic model

Waveform distortion in an FM/FM telemetry system

Waveform distortion in FM/FM telemetry syste

Strike Three: Umpires' Demand for Discrimination

We explore umpires' racial/ethnic preferences in the evaluation of Major League Baseball pitchers. Controlling for umpire, pitcher, batter and catcher fixed effects and many other factors, strikes are more likely to be called if the umpire and pitcher match race/ethnicity. This effect only exists where there is little scrutiny of umpires' behavior -- in ballparks without computerized systems monitoring umpires' calls, at poorly attended games, and when the called pitch cannot determine the outcome of the at-bat. If a pitcher shares the home-plate umpire's race/ethnicity, he gives up fewer runs per game and improves his team's chance of winning. The results suggest that standard measures of salary discrimination that adjust for measured productivity may generally be flawed. We derive the magnitude of the bias generally and apply it to several examples.

Self-reported pain severity is associated with a history of coronary heart disease

This study was funded by Arthritis Research UK (grant number: 17292).Peer reviewedPublisher PD

Strike Three: Umpires' Demand for Discrimination

We explore how umpires' racial/ethnic preferences are expressed in their evaluation of Major League Baseball pitchers. Controlling for umpire, pitcher, batter and catcher fixed effects and many other factors, strikes are more likely to be called if the umpire and pitcher match race/ethnicity. This effect only exists where there is little scrutiny of umpires' behavior – in ballparks without computerized systems monitoring umpires' calls, at poorly attended games, and when the called pitch cannot determine the outcome of the at-bat. If a pitcher shares the home-plate umpire's race/ethnicity, he gives up fewer hits, strikes out more batters, and improves his team's chance of winning. The general implication is that standard measures of salary discrimination that adjust for measured productivity may be flawed. We derive the magnitude of the bias generally and apply it to several examples.strategic interactions, worker evaluation, wage equations, economics of sports

A J-band detection of the donor star in the dwarf nova OY Carinae, and an optical detection of its `iron curtain'

Purely photometric models can be used to determine the binary parameters of eclipsing cataclysmic variables with a high degree of precision. However, the photometric method relies on a number of assumptions, and to date there have been very few independent checks of this method in the literature. We present time-resolved spectroscopy of the P=90.9 min eclipsing cataclysmic variable OY Carinae obtained with X-shooter on the VLT, in which we detect the donor star from K I lines in the J-band. We measure the radial velocity amplitude of the donor star K2 = 470.0 +/- 2.7 km/s, consistent with predictions based upon the photometric method (470 +/- 7 km/s). Additionally, the spectra obtained in the UVB arm of X-shooter show a series of Fe I and Fe II lines with a phase and velocity consistent with an origin in the accretion disc. This is the first unambiguous detection at optical wavelengths of the `iron curtain' of disc material which has been previously reported to veil the white dwarf in this system. The velocities of these lines do not track the white dwarf, reflecting a distortion of the outer disc that we see also in Doppler images. This is evidence for considerable radial motion in the outer disk, at up to 90 km/s towards and away from the white dwarf.Comment: MNRAS accepted. 11 pages with 10 figures and 2 table