Transformation of polarons to bipolarons in disordered matter

The polaron to bipolaron transition in disordered media under the influence of a broadband ac electric field is suggested: ac conductivity vs. frequency measurements in disordered media with inhomogeneous disorder induce spatio-temporal fluctuations of the density of polarons yielding polaron to bipolaron transformation. The external field results in the transition, alternatively to an increasing doping level. The assertion is confirmed by performing successive complex impedance measurements in disordered media. A systematic increase of the real part of the ac conductivity in the frequency domain, followed by mutual reduction of the magnetic inductivity of conducting polypyrrole, are explained.Comment: 8 pages plus 3 figures. Accepted for publication in Applied Physics Letter

Electricity storage requirements to support the transition towards high renewable penetration levels: Application to the Greek power system

This paper investigates the electricity storage requirements to support the transition towards a high renewable energy source (RES) penetration in a cost-optimal manner. The achieved reduction of renewable energy curtailments and the decrease in the total generation cost of the system are quantified against a counterfactual scenario without storage. A methodology is presented to determine the optimum mix of short- and medium-duration storage needed to support system operation at increased RES penetration levels, using the mixed integer linear programming mathematical optimization. The Greek power system serves as a realistic study case, in its planned development for the year 2030, with a targeted annual RES energy penetration in the order of 60%. Li-ion batteries and pumped-hydro are selected as the representative technologies to include in the storage mix, assuming energy-to-power ratios of up to 6 hours for the former and 10 hours for the latter. It is shown that the introduction of a suitable mixture of storage facilities may improve renewable energy integration and, at the same time, reduce system cost to the extent that entirely compensates for the full cost of storage, thus allowing for a net economic benefit for the system. The optimum storage portfolio for the study case system and the targeted RES penetration level combines 2-h batteries and 6-h pumped-hydro stations, with an aggregate capacity of new facilities between 1250 MW and 1750 MW, on top of the existing 700 MW of open-loop pumped hydro plants. The optimum storage requirements vary with the targeted RES penetration and with the balance of RES technologies in the generation mix, particularly the level of PV integration.Comment: 28 pages, 19 figure

A comprehensive review of electricity storage applications in island systems

Electricity storage is crucial for power systems to achieve higher levels of renewable energy penetration. This is especially significant for non-interconnected island (NII) systems, which are electrically isolated and vulnerable to the fluctuations of intermittent renewable generation. This paper comprehensively reviews existing literature on electricity storage in island systems, documenting relevant storage applications worldwide and emphasizing the role of storage in transitioning NII towards a fossil-fuel-independent electricity sector. On this topic, the literature review indicates that the implementation of storage is a prerequisite for attaining renewable penetration rates of over 50% due to the amplified requirements for system flexibility and renewable energy arbitrage. The analysis also identifies potential storage services and classifies applicable storage architectures for islands. Amongst the available storage designs, two have emerged as particularly important for further investigation; standalone, centrally managed storage stations and storage combined with renewables to form a hybrid plant that operates indivisibly in the market. For each design, the operating principles, remuneration schemes, investment feasibility, and applications discussed in the literature are presented in-depth, while possible implementation barriers are acknowledged. The literature on hybrid power plants mainly focuses on wind-powered pumped-hydro stations. However, recently, PV-powered battery-based hybrid plants have gained momentum due to the decreasing cost of Li-ion technology. On the other hand, standalone storage establishments rely heavily on battery technology and are mainly used to provide flexibility to the island grid. Nevertheless, these investments often suffer from insufficient remunerating frameworks, making it challenging for storage projects to be financially secure.Comment: 55 pages, 10 figure

Effect of composition on the dielectric relaxation of zeolite-conducting polyaniline blends

The complex permittivity of conducting polyaniline and zeolite - polyaniline blends was measured in the frequency range 0.01 to 2000000 Hz from room temperature to liquid nitrogen temperature. A loss peak is detected for 25, 35 and 50 wt % zeolite blends. Its position in the frequency domain, activation energy and intensity is a function of composition. The experimental results are interpreted through the competing multiple role of zeolite: as being less conducting than polyaniline, it impedes the electric charge flow by dividing large conducting polyaniline regions into smaller pieces, subsequently provides short-range pathways and, moreover, enriches the blend in interfaces separating zeolite from polyaniline.Comment: Accepted for publication in J. Appl. Phy