Application of a high density ratio lattice-Boltzmann model for the droplet impingement on flat and spherical surfaces

In the current study, a 3-dimensional lattice Boltzmann model which can tolerate high density ratios is employed to simulate the impingement of a liquid droplet onto a flat and a spherical target. The four phases of droplet impact on a flat surface, namely, the kinematic, spreading, relaxation and equilibrium phase, have been obtained for a range of Weber and Reynolds numbers. The predicted maximum spread factor is in good agreement with experimental data published in the literature. For the impact of the liquid droplet onto a spherical target, the temporal variation of the film thickness on the target surface is investigated. The three different temporal phases of the film dynamics, namely, the initial drop deformation phase, the inertia dominated phase and the viscosity dominated phase are reproduced and studied. The effect of the droplet Reynolds number and the target-to-drop size ratio on the film flow dynamics is investigated

A numerical model for the fractional condensation of pyrolysis vapours

Experimentation on the fast pyrolysis process has been primarily focused on the pyrolysis reactor itself, with less emphasis given to the liquid collection system (LCS). More importantly, the physics behind the vapour condensation process in LCSs has not been thoroughly researched mainly due to the complexity of the phenomena involved. The present work focusses on providing detailed information of the condensation process within the LCS, which consists of a water cooled indirect contact condenser. In an effort to understand the mass transfer phenomena within the LCS, a numerical simulation was performed using the Eulerian approach. A multiphase multi-component model, with the condensable vapours and non-condensable gases as the gaseous phase and the condensed bio-oil as the liquid phase, has been created. Species transport modelling has been used to capture the detailed physical phenomena of 11 major compounds present in the pyrolysis vapours. The development of the condensation model relies on the saturation pressures of the individual compounds based on the corresponding states correlations and assuming that the pyrolysis vapours form an ideal mixture. After the numerical analysis, results showed that different species condense at different times and at different rates. In this simulation, acidic components like acetic acid and formic acids were not condensed as it was also evident in experimental works, were the pH value of the condensed oil is higher than subsequent stages. In the future, the current computational model can provide significant aid in the design and optimization of different types of LCSs

Effect of air turbulence on gas transport in soil; comparison of approaches

Geophysical Research Abstracts (GRA) is the conference series publishing the abstracts accepted for the General Assemblies of the European Geosciences Union (EGU). It links the annual conference programmes listing programme groups, included sessions, and their contributions. The abstracts underwent an access review by the session conveners.Xi'an Jiaotong-Liverpool Universit

CFD modelling of particle shrinkage in a fluidized bed for biomass fast pyrolysis with quadrature method of moment

An Eulerian-Eulerian multi-phase CFD model was set up to simulate a lab-scale fluidized bed reactor for the fast pyrolysis of biomass. Biomass particles and the bed material (sand) were considered to be particulate phases and modelled using the kinetic theory of granular flow. A global, multi-stage chemical kinetic mechanism was integrated into the main framework of the CFD model and employed to account for the process of biomass devolatilization. A 3-parameter shrinkage model was used to describe the variation in particle size due to biomass decomposition. This particle shrinkage model was then used in combination with a quadrature method of moment (QMOM) to solve the particle population balance equation (PBE). The evolution of biomass particle size in the fluidized bed was obtained for several different patterns of particle shrinkage, which were represented by different values of shrinkage factors. In addition, pore formation inside the biomass particle was simulated for these shrinkage patterns, and thus, the density variation of biomass particles is taken into account

The Recent High State of the BL Lacertae Object AO 0235 and Cross-Correlations Between Optical and Radio Bands

We present new optical (B, V , R, I) and radio (at 14.5, 8.5, and 4.8 GHz) observations of the γ-ray- loud blazar AO 0235+164 obtained during the high state of 1997 December-1998 January. The data were combined with historical light curves from the literature to study correlated optical and radio variations over a time span of more than 20 years. Flux variability with large and energy-dependent amplitude is observed at both wave bands, with the source varying over all timescales sampled (years-months- days), in agreement with previous reports. We have performed a cross-correlation analysis of optical and radio light curves applying various detailed statistical methods. The principal results of our analysis can be summarized as follows : (1) we find that the optical and radio variations exhibit correlated flux changes at their average level , stressing the conclusion that the same emission mechanism is responsible for the radiation in the two bands (i.e., synchrotron emission from shocked plasma in the jet). However, as previously reported, a few strong flares at optical do not have obvious counterparts at longer wavelengths, possibly indicating that an additional component is present in the optical (e.g., microlensing), or, alternatively, rapid cooling of the synchrotron particles in a radiative shock. (2) Periodic variations are observed at radio frequencies (14.5 and 8.0 GHz) with a pattern repeating every ~5.8 years, as indicated by the Lomb-Scargle periodogram. This is the first report for periodicity at radio wavelengths for this source; future continuous monitoring is needed to confirm this result. (3) Through the analysis of B-V and R-I slopes, we observe large spectral variations, with a bimodal behavior. In the first state, the emission is consistent with a variable power law all across the sampled optical region (from R to V bands); in the second state, the R-I slope is constant while the B-V slope varies, i.e., the continuum has various degrees of curvature at the shorter wavelengths. In general, the power-law slope is not correlated with the f;ux of the source. However, there is an indication that when the source is in the first state, the spectrum becomes softer as the source brightens

Decarbonisation of olefin processes using biomass pyrolysis oil

An imperative step toward decarbonisation of current industrial processes is to substitute their petroleum-derived feedstocks with biomass and biomass-derived feedstocks. For decarbonisation of the petrochemical industry, integrated catalytic processing of biomass pyrolysis oil (also known as bio-oil) is an enabling technology. This is because, under certain conditions, the reaction products form a mixture consisting of olefins and aromatics, which are very similar to the products of naphtha hydro-cracking in the conventional olefin processes. These synergies suggest that the catalytic bio-oil upgrading reactors can be seamlessly integrated to the subsequent separation network with minimal retrofitting costs. In addition, the integrated catalytic processing provides a high degree of flexibility for optimization of different products in response to market fluctuations. With the aim of assessing the techno-economic viability of this pathway, five scenarios in which different fractions of bio-oil (water soluble/water insoluble) were processed with different degrees of hydrogenation were studied in the present research. The results showed that such a retrofit is not only economically viable, but also provides a high degree of flexibility to the process, and contributes to decarbonisation of olefin infrastructures. Up to 44% reductions in greenhouse gas emissions were observed in several scenarios. In addition, it was shown that hydrogen prices lower than 6 $/kg will result in bio-based chemicals which are cheaper than equivalent petrochemicals. Alternatively, for higher hydrogen prices, it is possible to reform the water insoluble phase of bio-oil and produce bio-based chemicals, cheaper than petrochemical equivalents

Quantitative insights into the fast pyrolysis of extracted cellulose, hemicelluloses and lignin

The transformation of lignocellulosic biomass into bio-based commodity chemicals is technically possible. Among thermochemical processes, fast pyrolysis, a relatively mature technology that has now reached the commercial level, produces a high yield of an organic-rich liquid stream. Despite the recent efforts in elucidating the degradation paths of biomass pyrolysis, the selectivity and recovery rates of bio-compounds remain low. In an attempt to clarify the general degradation scheme of biomass fast pyrolysis and provide a quantitative insight, this study has combined the use of fast pyrolysis micro-reactors, spectrometric techniques and mixtures of unlabelled and Carbon-13 enriched materials. The first stage of the work reported aimed at selecting the type of reactor to ensure control of the pyrolysis regime. The comparison of chemical fragmentation patterns of 'primary' fast pyrolysis volatiles detectable by GC-MS between two small scale micro-reactors has shown the inevitable presence of secondary reactions. In a second stage, liquid fractions also made of 'primary' fast pyrolysis condensables have been analysed by quantitative liquid-state 13C-NMR providing a quantitative distribution of functional groups. The compilation of those results into a map that displays the distribution of functional groups according to the individual and main constituents of biomass confirmed the origin of individual chemicals within fast pyrolysis liquids