Contrasting mechanisms and timescales of subduction and exhumation as recorded by Paleoproterozoic and late Paleozoic high-pressure granulites in the North China Craton

The North China Craton records multiple metamorphic events related to supercontinent assembly during the Paleoproterozoic, forming Columbia, and again during the late Paleozoic, forming Pangea. Here we show that the Paleoproterozoic high-pressure granulites (HPGs) formed from enriched mid-ocean ridge basalt protoliths and record a clockwise pressure-temperature-time (P–T–t) path with prograde metamorphism at 7.8–10.0 kbar and 780–820 °C, peak granulite-facies metamorphism at 12–12.3 kbar and ∼860–880 °C, and retrograde metamorphism at 8.7–9.1 kbar and 850–855 °C. Subduction initiated prior to 1.90 Ga, with final collision and orogeny at 1.88 Ga, followed by post-collision/exhumation at 1.80 Ga, defining a prolonged exhumation period (∼90 m.y.) that occurred at a slow velocity of ∼0.16 ± 0.08 mm/y. Late Paleozoic HPGs are normal mid-ocean ridge basalt type and record a near clockwise P–T–t path, with peak/post-peak amphibolitefacies metamorphism at 11.0–12.5 kbar and 860–890 °C, isothermal decompression to 7.2–7.5 kbar and 810–820 °C, and retrogression to 5.5–7.2 kbar and 805–850 °C. Subduction initiated earlier than ca. 340 Ma, exhumation and uplift initiated at 335–309 Ma and continued to 297–287 Ma. The exhumation was short-lived (∼50 m.y.) and relatively fast (0.38 ± 0.14 mm/y). When compared to granulite-facies metamorphism documented in many Paleoproterozoic HPGs, late Paleozoic HPGs appear to commonly form with an initial period of steep subduction leading to eclogite-facies metamorphism, with subsequent exhumation to middle/lower levels of the crust. Our results further reveal that the exhumation velocity for supercontinent collision was facilitated and duration shortened through time, and that the exhumation mechanism might have been controlled by subduction angle, compression pressure, and temperature

Low dimensional ordering and fluctuations in methanol-β\beta-hydroquinone-clathrate studied by X-ray and neutron diffraction

Methanol-$\beta$-hydroquinone-clathrate has been established as a model system for dielectric ordering and fluctuations and is conceptually close to magnetic spin systems. In X-ray and neutron diffraction experiments, we investigated the ordered structure, the one-dimensional (1D) and the three-dimensional (3D) critical scattering in the paraelectric phase, and the temperature dependence of the lattice constants. Our results can be explained by microscopic models of the methanol pseudospin in the hydroquinone cage network, in consistency with previous dielectric investigations

A computational study of order-disorder phenomena in Mg2TiO4 spinel (qandilite)

We have used a combination of classical and quantum-mechanical atomistic calculations, together with Monte Carlo simulations, to study order-disorder phenomena in the spinel mineral qandilite, Mg2TiO4. Using an interatomic potential model akin to those previously used for 2-3 spinels yielded a general increase in energy E as a function of inversion parameter x, and thus incorrectly predicted a normal-spinel ground state, whereas the E(x) behavior as modeled by density-functional theory exhibited a maximum at an intermediate degree of inversion and correctly predicted an inverse-spinel ground state. We therefore used the quantum-mechanical simulations to derive pair interaction parameters (for nearest-neighbor tetrahedral-tetrahedral, octahedral-octahedral, and tetrahedral-octahedral interactions) and chemical potential to use in Monte Carlo simulations of order-disorder in qandilite. The simulated cation distributions compared favorably with those obtained experimentally, although the long-range ordering transition to the tetragonal P4122 phase was not observed when using only nearest-neighbor interactions. However, this transition could be observed following the addition of two extra parameters to the model. The simulations were used to calculate the effect of short- and long-range cation order on the configurational entropy of qandilite as a function of temperature. The calculated entropy of the high-temperature cubic phase was in very good agreement with the experimental value recently determined, supporting the suggestion that there is considerable short-range order in qandilite

Cenozoic temporal variation of crustal thickness in the Urumieh-Dokhtar and Alborz magmatic belts, Iran

We present regional variations of whole-rock Sr/Y and (La/Yb)N ratios of magmatic rocks along the Cenozoic Urumieh-Dokhtar and Alborz magmatic belts, Iran. Both the magmatic belts are located at the north of the main Zagros Neo-Tethyan suture. The Urumieh-Dokhtar magmatic belt (UDMB), which trends NW-SE for 1000 km across Iran, was characterized by the intensive volcanism and plutonism, and defined the magmatic front (MF) of the Zagros orogenic belt. The Alborz magmatic belt (AMB) is situated to the north, and characterized by less intense magmatic activity. The Alborz magmatic belt was formed behind it in the rear-arc (RA) domain. A striking feature of the both magmatic belts is the transition from normal calc-alkaline arc magmatism during the Eocene–Oligocene to adakite-like calc-alkaline magmatism during the Middle to Late Miocene–Pliocene. The late-Cenozoic magmatism of the UDMB and AMB shows higher Sr/Y and (La/Yb)N. However, it should be noted that crustal thickening event is intensive in the UDMB than AMB during Late Cenozoic. Using the composition of the Lale-Zar zircons from the SE UDMB we determined the oxygen fugacity (fO2) during zircon crystallization to be between FMQ (fayalite–magnetite–quartz buffer) -0.69 to +2.41, whereas those of the Hashroud-Teckmdash-Gormolla zircons from NW AMB range from −1.22 to +5.99. The fO2 estimates suggest relatively more oxidized conditions for the Late Cenozoic igneous rocks of the AMB. Compiled data from the UDMB and AMB intrusions show an increase in average zircon crystallization temperatures with decreasing age. These outcomes have been interpreted in terms of variation of the crustal thickness, from 30 to 35 km during Eocene-Oligocene to 40–55 km during the middle-late Miocene. We propose the increase in crustal thickness is associated with the collision between the Arabian plate and Iran and subsequent convergence during the middle-late Miocene

Crustal architecture studies in the Iranian Cadomian arc: insights into source, timing and metallogeny

The Jalal Abad magmatic rocks, situated at the southern edge of the Saghand-Bafgh-Zarand district, include a thick pile of Cadomian extrusive and pyroclastic units intruded by younger granitoid stocks. New zircon U–Pb ages show eruptions at ∼552 Ma, followed by emplacement of granodiorite at ∼537 Ma. The Jalal Abad magmatic rocks have typical high-K and shoshonitic signatures, and are characterized by enrichment in large-ion lithophile elements (LILEs) and depletion in high-field-strength elements (HFSE). Zircon ɛHf(t) from the Jalal Abad magmatic rocks ranges from +3.9 to −3.9 for volcanic rocks and −1.2 to +8.1 for granodiorite. Zircon δ18O values for the Jalal Abad are variable from +5.1 to +8.8‰, progressively higher than those of mantle-derived melts. The whole-rock ɛNd(t) values range between −7.7 to −7.4 for granodiorite, −4.6 to −3 for volcanic rocks and −6.2 to −8.2 for ignimbrites/tuff. The whole-rock Nd and zircon Hf crustal model ages (TDMC) for the Jalal Abad magmatic rocks range between 0.8 and 2.3 Ga. All of the Jalal Abad magmatic rocks have quite similar trace element patterns, and slightly different whole-rock Nd and zircon Hf isotopic composition, indicating the involvement of the thick continental crust during the formation of these rocks. Modeling of zircon Hf–O data, bulk-rock trace elements, and Sr–Nd isotopes suggest the magmas were generated by interaction of mantle–derived melts with thick continental crust through assimilation/fractional crystallization (AFC) processes. However, crustal architecture studies in the Iranian Cadomian arcs show that AFC processes were more important during the Mesoarchean–Early Neoproterozoic (3000–1000 Ma), whereas juvenile magmas became increasingly important to the Cadomian (600–500 Ma) magmatism. Early Cambrian intrusive magmas seemingly intruded sedimentary sequences in the study region and provided magmatic constituents and a heat source for hydrothermal processes and mineralization

Quantifying geological uncertainty in metamorphic phase equilibria modelling; a Monte Carlo assessment and implications for tectonic interpretations

Pseudosection modelling is rapidly becoming an essential part of a petrologist’s toolkit and often forms the basis of interpreting the tectonothermal evolution of a rock sample, outcrop, or geological region. Of the several factors that can affect the accuracy and precision of such calculated phase diagrams, “geological” uncertainty related to natural petrographic variation at the hand sample- and/or thin section-scale is rarely considered. Such uncertainty influences the sample’s bulk composition, which is the primary control on its equilibrium phase relationships and thus the interpreted pressure–temperature (P–T) conditions of formation. Two case study examples—a garnet–cordierite granofels and a garnet–staurolite–kyanite schist—are used to compare the relative importance that geological uncertainty has on bulk compositions determined via (1) X-ray fluorescence (XRF) or (2) point counting techniques. We show that only minor mineralogical variation at the thin-section scale propagates through the phase equilibria modelling procedure and affects the absolute P–T conditions at which key assemblages are stable. Absolute displacements of equilibria can approach ±1 kbar for only a moderate degree of modal proportion uncertainty, thus being essentially similar to the magnitudes reported for analytical uncertainties in conventional thermobarometry. Bulk compositions determined from multiple thin sections of a heterogeneous garnet–staurolite–kyanite schist show a wide range in major-element oxides, owing to notable variation in mineral proportions. Pseudosections constructed for individual point count-derived bulks accurately reproduce this variability on a case-by-case basis, though averaged proportions do not correlate with those calculated at equivalent peak P–T conditions for a whole-rock XRF-derived bulk composition. The main discrepancies relate to varying proportions of matrix phases (primarily mica) relative to porphyroblasts (primarily staurolite and kyanite), indicating that point counting preserves small-scale petrographic features that are otherwise averaged out in XRF analysis of a larger sample. Careful consideration of the size of the equilibration volume, the constituents that comprise the effective bulk composition, and the best technique to employ for its determination based on rock type and petrographic character, offer the best chance to produce trustworthy data from pseudosection analysis.RMP acknowledges a NERC postgraduate grant (reference number NE/H524781/1) for funding analytical work performed at the University of Oxford, UK

Metasomatism of the continental crust and its impact on surface uplift: Insights from reactive‐transport modelling

High-elevation, low-relief continental plateaus are major topographic features and profoundly influence atmospheric circulation, sediment transport and storage, and biodiversity. Although orogenic surface-uplift mechanisms for modern continental plateaus near known plate margins like Tibet are well-characterized, they cannot account for examples in intracontinental settings like the Colorado Plateau. In contrast to canonical plate-tectonic uplift mechanisms, broad-scale hydration-induced metasomatism of the lower crust has been suggested to reduce its density and increase its buoyancy sufficiently to contribute to isostatic uplift. However, the relationships between key petrophysical properties in these environments are not fully quantified, which limits application of this model. Here, we develop a series of petrological models that describe the petrological and topographic effects of fluid–rock interaction in non-deforming continental crust of varying composition. We apply an open-system petrological modelling framework that utilizes reactive-transport calculations to determine the spatial and temporal scales over which mineralogic transformations take place compared with the magnitude of infiltration of aqueous fluids derived from devolatilization of subducting oceanic lithosphere. The buoyancy effect of hydration-induced de-densification is most significant for metabasic lower crust, intermediate for metapelitic crust, and minimal for granodioritic crust. We apply these results to a case study of the ~2 km-high Colorado Plateau and demonstrate that under ideal conditions, hydration of its lower–middle crust by infiltrating aqueous fluids released by the Farallon slab during Cenozoic low-angle subduction could have uplifted the plateau surface by a maximum of ~1 km over 16 Myr. However, realistically, although hydration likely has a measurable effect on surface tectonics, the uplift of orogenic plateaus is likely dominantly controlled by other factors, such as lithospheric delamination

The power of light – From dental materials processing to diagnostics and therapeutics

Harnessing the power of light and its photonic energy is a powerful tool in biomedical applications. Its use ranges from biomaterials processing and fabrication of polymers to diagnostics and therapeutics. Dental light curable materials have evolved over several decades and now offer very fast (≤ 10 s) and reliable polymerization through depth (4–6 mm thick). This has been achieved by developments on two fronts: (1) chemistries with more efficient light absorption characteristics (camphorquinone [CQ], ~30 L mol-1 cm1[ʎmax 470 nm]; monoacylphosphine oxides [MAPO], ~800 L mol-1 cm-1 [ʎmax 385 nm]; bisacylphosphine oxide [BAPO], ~1,000 L mol-1 cm-1 [ʎmax 385 nm]) as well mechanistically efficient and prolonged radical generation processes during and after light irradiation, and; (2) introducing light curing technologies (light emitting diodes [LEDs] and less common lasers) with higher powers (≤ 2 W), better spectral range using multiple diodes (short: 390–405 nm; intermediate: 410–450 nm; and long: 450–480 nm), and better spatial power distribution (i.e. homogenous irradiance). However, adequate cure of materials falls short for several reasons, including improper selection of materials and lights, limitations in the chemistry of the materials, and limitations in delivering light through depth. Photonic energy has further applications in dentistry which include transillumination for diagnostics, and therapeutic applications that include photodynamic therapy, photobiomodulation, and photodisinfection. Light interactions with materials and biological tis-sues are complex and it is important to understand the advantages and limitations of these interactions for successful treatment outcomes. This article highlights the advent of photonic technologies in dentistry, its applications, the advantages and limitations, and possible future developments

Temperature and its effects on some maritime plants in Britain

The physiological ecology of five coastal species has been examined with respect to temperature and its effect on survival and distribution. The aims of the study have been to establish whether any direct correlation exists between distribution and the responses of the plants to temperature at different stages in the life cycle. The species Tinder consideration were the northern Ligusticum scoticum and Mertensia maritima and the southern Crithmum maritimum, Limonium binervosum and Glaucium flavum. Highest germination percentages for each species were found at temperatures close to those associated with the season favourable for germination in the natural habitat. Northern species had higher temperature requirements than the southern, corresponding to spring/ summer and autumn or spring germination respectively. Root respiration, measured as oxygen uptake, was found to be twice as great in the northern Ligusticum and Mertensia as in the southern Crithmum and Limonium over a range of experimental temperatures. This varied to some extent with time and temperature of pretreatment. The single experiment on the southern Glauci.um showed rates similar to those of the northern species. Arrhenius plots' of respiration data for the northern species showed a break in gradient at the upper end of the experimental temperature range which correlated well with apparently limiting July mean temperatures from the distribution maps. The southern Crithmum showed a break at lower temperature range close to the limiting January mean temperature. The response of Limonium to experimental temperature depended on the pretreatment; upper range breaks were shown after low pretreatment temperatures, and lower range breaks after higher pretreatment temperatures. The single experiment on Glaucium gave a straight line Arrhenius plot. Carbohydrate analyses of the same pretreated plants yielded additional information relevant to the survival and thus to the distribution in relation to temperature. The southern Crithmum had the highest starch content at all temperatures while the northern Ligusticum and Mertensia had less. Ratios of soluble sugar to starch were greatest in the northern species, possibly reflecting displacement of the equilibrium from starch to soluble sugar at lower temperatures. Overall a connection has been demonstrated between the direct effects of temperature on the plants and the limitation of distribution by temperature. This is clearest for the two northern species, Ligusticum scoticum and Mertensia maritima, less definite for the southern Crithmum maritimiim, and only suggested for Limonium binervosum with its apparently less simple temperature responses. Glaucium flavum appears anomalous and requires further study

Proposing new standards for testing solubility of pulp preservation materials

OBJECTIVES: Quality control testing of dental materials requires a standard to enable the generation of reproducible and comparable data. Currently there are no standards for testing materials used for vital pulp therapy. The aim of this study was to develop a new standard to evaluate solubility of pulp preservation materials.METHODS: The solubility of three materials used for vital pulp therapy: Biodentine, TheraCal and Activa was evaluated using two international standards for dental materials ISO 4049:2019 (S1) and ISO 6876:2012 (S2). For both standards, a modified methodology was evaluated. This included changing the volume of the solution used (S1M, S2M), using Dulbecco's modified eagle medium (DMEM) as an alternative to water (S1D, S2D) and periodic solution change for the ISO 4049 method (S1P, S1MP). Materials were characterised before and after completion of solubility test using scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis.RESULTS: The test materials exhibited different solubility values depending on the methodology used. Biodentine exhibited significantly lower solubility when lower volumes of solution were used when tested using both ISO methods (p ≤ 0.05). TheraCal and Activa showed negative solubility values after desiccation when tested using ISO 4049:2019. The Biodentine exhibited changes in its microstructure which was dependent on the method used to test solubility.CONCLUSIONS: The solubility values obtained were dependent on the method used. It is thus important to use methods that replicate the clinical environment for meaningful evaluations.</p