7 research outputs found
Mn incorporation in as-grown and annealed (Ga,Mn)As layers studied by x-ray diffraction and standing-wave uorescence
A combination of high-resolution x-ray diffraction and a new technique of
x-ray standing wave uorescence at grazing incidence is employed to study the
structure of (Ga,Mn)As diluted magnetic semiconductor and its changes during
post-growth annealing steps. We find that the film is formed by a uniform,
single crystallographic phase epilayer covered by a thin surface layer with
enhanced Mn concentration due to Mn atoms at random non-crystallographic
positions. In the epilayer, Mn incorporated at interstitial position has a
dominant effect on lattice expansion as compared to substitutional Mn. The
expansion coeffcient of interstitial Mn estimated from our data is consistent
with theory predictions. The concentration of interstitial Mn and the
corresponding lattice expansion of the epilayer are reduced by annealing,
accompanied by an increase of the density of randomly distributed Mn atoms in
the disordered surface layer. Substitutional Mn atoms remain stable during the
low-temperature annealing.Comment: 9 pages, 9 figure
Antiferrodistortive phase transition in EuTiO3
X-ray diffraction, dynamical mechanical analysis and infrared reflectivity
studies revealed an antiferrodistortive phase transition in EuTiO3 ceramics.
Near 300K the perovskite structure changes from cubic Pm-3m to tetragonal
I4/mcm due to antiphase tilting of oxygen octahedra along the c axis (a0a0c- in
Glazer notation). The phase transition is analogous to SrTiO3. However, some
ceramics as well as single crystals of EuTiO3 show different infrared
reflectivity spectra bringing evidence of a different crystal structure. In
such samples electron diffraction revealed an incommensurate tetragonal
structure with modulation wavevector q ~ 0.38 a*. Extra phonons in samples with
modulated structure are activated in the IR spectra due to folding of the
Brillouin zone. We propose that defects like Eu3+ and oxygen vacancies strongly
influence the temperature of the phase transition to antiferrodistortive phase
as well as the tendency to incommensurate modulation in EuTiO3.Comment: PRB, in pres